2-(2'-pyridylmethylenehydrazonomethyl)phenol | 110484-55-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-(2'-pyridylmethylenehydrazonomethyl)phenol
• 英文别名: pyridine-2-aldehyde salicylaldazine；2-(pyridin-2-ylmethylene-hydrazonomethyl)-phenol；Hsalpahn；2-[(pyridin-2-ylmethylidenehydrazinylidene)methyl]phenol
• CAS: 110484-55-4
• 化学式: C₁₃H₁₁N₃O
• 分子量: 225.25
• InChiKey: MEOOTLKYEQRLJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  57.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  iron perchlorate hexahydrate 、 2-(2'-pyridylmethylenehydrazonomethyl)phenol 在 KOH 作用下， 以 甲醇 为溶剂， 以61%的产率得到iron(III) bis[2-(pyridin-2-ylmethylene-hydrazonomethyl)-phenolate]perchlorate
  参考文献：
  名称：

  Tridentate facial coordination mode of an unsymmetrical tetradentate diazine ligand in an iron(III) complex

  摘要：

  Synthesis, structure and properties of a distorted octahedral iron(III) complex, [Fe(salpahn)(2)]ClO4 (Hsalpahn = 2-(pyridin-2-ylmethylene-hydrazonomethyl)-phenol), are described. The X-ray structure reveals the facial disposition of pyridine-N, imine-N and phenolate-O donor salpahn(-) with the formation of two six-membered chelate rings. The self-assembly pattern via intermolecular hydrogen bonds in the crystal lattice is reported. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.07.003

文献信息

• Tirant, Michael; Smith, Thomas D.; Pilbrow, John R., Journal of the Chemical Society, Dalton Transactions, 1987, p. 1755 - 1762
  作者：Tirant, Michael、Smith, Thomas D.、Pilbrow, John R.、Hanson, Graeme、Sinclair, Geoffrey R.

  DOI：——

  日期：——
• Singh, B.; Singh, U. R., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, <hi>1994</hi>, vol. 24, p. 201 - 216
  作者：Singh, B.、Singh, U. R.

  DOI：——

  日期：——
• Tridentate facial coordination mode of an unsymmetrical tetradentate diazine ligand in an iron(III) complex
  作者：Subramanya Gupta Sreerama、Abhik Mukhopadhyay、Samudranil Pal

  DOI：10.1016/j.inoche.2006.07.003

  日期：2006.11

  Synthesis, structure and properties of a distorted octahedral iron(III) complex, [Fe(salpahn)(2)]ClO4 (Hsalpahn = 2-(pyridin-2-ylmethylene-hydrazonomethyl)-phenol), are described. The X-ray structure reveals the facial disposition of pyridine-N, imine-N and phenolate-O donor salpahn(-) with the formation of two six-membered chelate rings. The self-assembly pattern via intermolecular hydrogen bonds in the crystal lattice is reported. (C) 2006 Elsevier B.V. All rights reserved.