tert-Butyl-[1-methyl-prop-(Z)-ylidene]-amine | 77390-51-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tert-Butyl-[1-methyl-prop-(Z)-ylidene]-amine
• CAS: 77390-51-3
• 化学式: C₈H₁₇N
• 分子量: 127.23
• InChiKey: AIDXSBOJACKUBJ-CLFYSBASSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.66
• 重原子数：
  9.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  tert-Butyl-[1-methyl-prop-(Z)-ylidene]-amine 、 碘甲烷 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 生成 tert-butyl imine of 3-pentanone 、 tert-Butyl-[1,2-dimethyl-prop-(Z)-ylidene]-amine
  参考文献：
  名称：

  Factors controlling regioselectivity in deprotonations of unsymmetrical ketimines

  摘要：

  DOI：

  10.1021/ja00351a045
• 作为产物：
  描述：

  tert-Butyl-[1-methyl-prop-(E)-ylidene]-amine 生成 tert-Butyl-[1-methyl-prop-(Z)-ylidene]-amine
  参考文献：
  名称：

  FRASER, R. R.;CHUAQUI-OFFERMANNS, N., CAN. J. CHEM., 1981, 59, N 20, 3007-3011

  摘要：

  DOI：

文献信息

• ORGANOAMINOSILANES AND METHODS FOR MAKING SAME
  申请人：Air Products and Chemicals, Inc.

  公开号：US20160168169A1

  公开（公告）日：2016-06-16

  Organoaminosilanes, such as without limitation di-iso-propylaminosilane (DIPAS), are precursors for the deposition of silicon containing films such as silicon-oxide and silicon-nitride films. Described herein are methods to make organoaminosilane compounds, or other compounds such as organoaminodisilanes and organoaminocarbosilanes, via the catalytic hydrosilylation of an imine by a silicon source comprising a hydridosilane.

  Organoaminosilanes，例如但不限于二异丙基氨基硅烷（DIPAS），是沉积含硅膜如硅氧化物和硅氮化物膜的前体。本文描述了通过催化氢硅化反应将亚胺与含有氢硅烷的硅源反应制备出有机氨基硅烷化合物，或其他化合物如有机氨基二硅烷和有机氨基碳硅烷的方法。
• Organoaminosilanes and methods for making same
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP2913334A1

  公开（公告）日：2015-09-02

  Organoaminosilanes, such as without limitation di-iso-propylaminosilane (DIPAS), are precursors for the deposition of silicon containing films such as silicon-oxide and silicon-nitride films. Described herein are methods to make organoaminosilane compounds, or other compounds such as organoaminodisilanes and organoaminocarbosilanes, via the catalytic hydrosilylation of an imine by a silicon source comprising a hydridosilane.

  有机氨基硅烷，例如但不限于二异丙氨基硅烷（DIPAS），是沉积氧化硅和氮化硅薄膜等含硅薄膜的前体。本文描述了通过包含氢基硅烷的硅源对亚胺进行催化氢硅烷化来制造有机氨基硅烷化合物或其他化合物如有机氨基二硅烷和有机氨基碳硅烷的方法。
• Fraser, Robert R.; Banville, Jacques; Akiyama, Fuminori, Canadian Journal of Chemistry, 1981, vol. 59, p. 705 - 709
  作者：Fraser, Robert R.、Banville, Jacques、Akiyama, Fuminori、Chuaqui-Offermanns, Noemi

  DOI：——

  日期：——
• Organoaminosilanes and Methods for Making Same
  申请人：Versum Materials US, LLC

  公开号：US20170204120A1

  公开（公告）日：2017-07-20

  Organoaminosilanes, such as without limitation di-iso-propylaminosilane (DIPAS), are precursors for the deposition of silicon containing films such as silicon-oxide and silicon-nitride films. Described herein are methods to make organoaminosilane compounds, or other compounds such as organoaminodisilanes and organoaminocarbosilanes, via the catalytic hydrosilylation of an imine by a silicon source comprising a hydridosilane.
• PYRIDINE RING-SUBSTITUTED PYRIDAZINOL COMPOUNDS AND DERIVATIVES, PREPARATION METHODS, HERBICIDAL COMPOSITIONS AND APPLICATIONS THEREOF
  申请人：Qingdao Kingagroot Chemical Compound Co., Ltd.

  公开号：US20210032229A1

  公开（公告）日：2021-02-04

  The invention belongs to the technical field of agricultural chemicals, and in particular relates to a pyridine ring-substituted pyridazinol compound and a derivatives thereof, preparation method, herbicidal composition and application thereof. The compound is as shown in Formula I: wherein, X is halogen, cyano, alkyl, halogenated alkyl, alkoxy, halogenated alkoxy, R 1 R 2 N—(C═O)—, R 1 R 2 N—, hydroxy, or unsubstituted or substituted aryl; Y is independently selected from hydrogen, halogen, cyano, nitro, R—O—(CH 2 ) n —, and R 1 R 2 R 3 SiO—, etc.; r is an integer from 0 to 4, m is 0 or 1, n and q are independently an integer from 0 to 8, p is an integer from 1 to 8; R is hydrogen, or a halogen-containing or not containing group selected from alkyl, alkenyl, alkynyl, and cycloalkyl, etc.; R 1 , R 2 , R 3 are each independently hydrogen, nitro, or hydroxy, etc. The compound and the derivative, as well as the composition thereof have very high herbicidal activity and good selectivity, and are safe for crops.