perfluoro-(3-di-n-propylaminopropionic acid) | 144629-93-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: perfluoro-(3-di-n-propylaminopropionic acid)
• 英文别名: 3-[Bis(1,1,2,2,3,3,3-heptafluoropropyl)amino]-2,2,3,3-tetrafluoropropanoic acid
• CAS: 144629-93-6
• 化学式: C₉HF₁₈NO₂
• 分子量: 497.084
• InChiKey: ZYCOISXZEMDASB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  40.5
• 氢给体数：
  1
• 氢受体数：
  21

反应信息

• 作为产物：
  描述：

  methyl 3-(dipropylamino)propionate 在 氢氟酸 、 水 作用下， 生成 perfluoro-(3-di-n-propylaminopropionic acid)
  参考文献：
  名称：

  含氮羧酸的电化学氟化。3-二烷基氨基丙酸甲酯的氟化

  摘要：

  将3-二烷基氨基取代的丙酸的六种甲酯进行电化学氟化，得到相应的全氟代氟化物。研究了以下二烷基氨基取代基：二乙基氨基，二正丙基氨基，二正丁基氨基，吡咯烷基，吗啉代和哌啶子基。这些以合理收率获得的全氟酸氟化物被认为是制备软质（可降解）含氟化合物的潜在关键前体。这些盐在水溶液中显示出明显降低的表面张力。报告了所获得的所有全氟酸氟化物的物理性质，以及它们的光谱数据（19 F NMR，质谱和IR光谱）。

  DOI：

  10.1016/s0022-1139(00)82821-3

文献信息

• HYDROPHILIC OIL REPELLENT AGENT AND METHOD FOR MANUFACTURING SAME, AND SURFACE COVERING MATERIAL, COATING FILM, RESIN COMPOSITION, OIL-WATER SEPARATION FILTER MEDIUM, AND POROUS BODY
  申请人：Mitsubishi Materials Corporation

  公开号：EP3176237A1

  公开（公告）日：2017-06-07

  The hydrophilic oil repellent includes one or more types of nitrogen-containing fluorine-based compounds. The nitrogen-containing fluorine-based compound includes any one hydrophilicity imparting group selected from the group consisting of anion type hydrophilicity imparting groups, cation type hydrophilicity imparting groups, and amphoteric type hydrophilicity imparting groups in the molecule.

  亲水驱油剂包括一种或多种含氮氟基化合物。含氮氟基化合物分子中包括从阴离子型亲水赋予基团、阳离子型亲水赋予基团和两性型亲水赋予基团组成的组中选出的任意一个亲水赋予基团。
• Hydrophilic oil repellent and production method of same, surface coating material, coating film, resin composition, oil-water separation filter material, and porous body
  申请人：MITSUBISHI MATERIALS CORPORATION

  公开号：US10208210B2

  公开（公告）日：2019-02-19

  The hydrophilic oil repellent includes one or more types of nitrogen-containing fluorine-based compounds. The nitrogen-containing fluorine-based compound includes any one hydrophilicity imparting group selected from the group consisting of anion type hydrophilicity imparting groups, cation type hydrophilicity imparting groups, and amphoteric type hydrophilicity imparting groups in the molecule.

  亲水驱油剂包括一种或多种含氮氟基化合物。含氮氟基化合物分子中包括从阴离子型亲水赋予基团、阳离子型亲水赋予基团和两性型亲水赋予基团组成的组中选出的任意一个亲水赋予基团。
• HYDROPHILIC OIL REPELLENT AND PRODUCTION METHOD OF SAME, SURFACE COATING MATERIAL, COATING FILM, RESIN COMPOSITION, OIL-WATER SEPARATION FILTER MATERIAL, AND POROUS BODY
  申请人：MITSUBISHI MATERIALS CORPORATION

  公开号：US20170210912A1

  公开（公告）日：2017-07-27

  The hydrophilic oil repellent includes one or more types of nitrogen-containing fluorine-based compounds. The nitrogen-containing fluorine-based compound includes any one hydrophilicity imparting group selected from the group consisting of anion type hydrophilicity imparting groups, cation type hydrophilicity imparting groups, and amphoteric type hydrophilicity imparting groups in the molecule.
• The electrochemical fluorination of nitrogen-containing carboxylic acids. Fluorination of methyl esters of 3-dialkylamino propionic acids
  作者：Takashi Abe、Eiji Hayashi、Haruhiko Fukaya、Yoshio Hayakawa、Hajime Baba、Shigeki Ishikawa、Kinya Asahino

  DOI：10.1016/s0022-1139(00)82821-3

  日期：1992.4

  Six methyl esters of 3-dialkylamino-substituted propionic acids were subjected to electrochemical fluorination to give the corresponding perfluoroacid fluorides. The following dialkylamino substituents were investigated: diethylamino, di-n-propyl-amino, di-n-butylamino, pyrrolidino, morpholino and piperidino groups. These perfluoroacid fluorides, which were obtained in fair yields, are considered to

  将3-二烷基氨基取代的丙酸的六种甲酯进行电化学氟化，得到相应的全氟代氟化物。研究了以下二烷基氨基取代基：二乙基氨基，二正丙基氨基，二正丁基氨基，吡咯烷基，吗啉代和哌啶子基。这些以合理收率获得的全氟酸氟化物被认为是制备软质（可降解）含氟化合物的潜在关键前体。这些盐在水溶液中显示出明显降低的表面张力。报告了所获得的所有全氟酸氟化物的物理性质，以及它们的光谱数据（19 F NMR，质谱和IR光谱）。