[trans-5,15-di(2-methoxynaphthyl)-10-phenyl-20-(4-(hexadecyloxy)phenyl)porphyrinato]zinc(II) | 1610791-90-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [trans-5,15-di(2-methoxynaphthyl)-10-phenyl-20-(4-(hexadecyloxy)phenyl)porphyrinato]zinc(II)
• CAS: 1610791-90-6
• 化学式: C₇₀H₆₈N₄O₃Zn
• 分子量: 1078.72
• InChiKey: GCCUCKDRSYIGGC-UEHNJFPDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [trans-5,15-di(2-methoxynaphthyl)-10-phenyl-20-(4-(hexadecyloxy)phenyl)porphyrinato]zinc(II) 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 1.5h， 以70.4%的产率得到trans-5,15-bis(2-hydroxynaphthyl)-10-phenyl-20-(4-hydroxyphenyl)porphyrin
  参考文献：
  名称：

  Chiral dinaphthylporphyrin with C2 symmetry: synthesis, resolution, and enantio-discrimination by single-crystal X-ray diffraction analysis

  摘要：

  An intrinsic chiral dinaphthylporphyrin with C-2 symmetry, namely [5,15-trans-bis(2-hydroxynaphthyl)-10-phenyl-20-(4-hydroxyphenyl)porphyrinato]zinc(II) (ZnDNP), has been designed and synthesized. The molecular structure of ZnDNP was determined by single crystal X-ray diffraction analysis. Resolution of the racemic mixture was achieved with chiral HPLC technique. In particular, the stereostructures of the enantiomers and the specific interactions between the chiral meso-dinaphthylporphyrin with L-Phe-OMe were elucidated in the solid state by single-crystal X-ray diffraction analysis. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.04.067
• 作为产物：
  描述：

  [5,15-dibromo-10-phenyl-20-(4-(hexadecyloxy)phenyl)porphyrinato]zinc(II) 、 2-甲氧基-1-萘基硼酸 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 20.0h， 以35%的产率得到[trans-5,15-di(2-methoxynaphthyl)-10-phenyl-20-(4-(hexadecyloxy)phenyl)porphyrinato]zinc(II)
  参考文献：
  名称：

  Chiral dinaphthylporphyrin with C2 symmetry: synthesis, resolution, and enantio-discrimination by single-crystal X-ray diffraction analysis

  摘要：

  An intrinsic chiral dinaphthylporphyrin with C-2 symmetry, namely [5,15-trans-bis(2-hydroxynaphthyl)-10-phenyl-20-(4-hydroxyphenyl)porphyrinato]zinc(II) (ZnDNP), has been designed and synthesized. The molecular structure of ZnDNP was determined by single crystal X-ray diffraction analysis. Resolution of the racemic mixture was achieved with chiral HPLC technique. In particular, the stereostructures of the enantiomers and the specific interactions between the chiral meso-dinaphthylporphyrin with L-Phe-OMe were elucidated in the solid state by single-crystal X-ray diffraction analysis. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.04.067