4-bromo-N-(4-bromophenyl)-N-(2,4-dimethylphenyl)benzenamine | 157913-52-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-bromo-N-(4-bromophenyl)-N-(2,4-dimethylphenyl)benzenamine
• 英文别名: N,N-Bis(4-bromophenyl)-2,4-dimethylaniline
• CAS: 157913-52-5
• 化学式: C₂₀H₁₇Br₂N
• 分子量: 431.17
• InChiKey: FULWMMKSEOZHND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  异丙醇频哪醇硼酸酯 、 4-bromo-N-(4-bromophenyl)-N-(2,4-dimethylphenyl)benzenamine 在 正丁基锂 作用下， 以 四氢呋喃 、 hexanes 为溶剂， 以62%的产率得到N-(4-bromophenyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-N-(2,4-dimethylphenyl)benzenamine
  参考文献：
  名称：

  Systematic Improvement in Charge Carrier Mobility of Air Stable Triarylamine Copolymers

  摘要：

  The electrical performance of organic semiconducting polymers in field-effect transistor devices is now sufficient for initial low complexity circuit applications. To achieve high performance, either operation in an inert atmosphere or a hydrophobic surface treatment and annealing step is typically required. In this communication we report a strategy to prepare fully air stable, amorphous semiconducting polymers which can achieve charge carrier mobilities in the range of 0.04 cm(2)/(V s), remaining over a period of over 3 months in ambient conditions

  DOI：

  10.1021/ja9034818

文献信息

• ORGANIC SEMICONDUCTOR COMPOSITIONS
  申请人：SMARTKEM LIMITED

  公开号：US20150028262A1

  公开（公告）日：2015-01-29

  The present invention relates to organic copolymers and organic semiconducting compositions comprising these materials, including layers and devices comprising such organic semiconductor compositions. The invention is also concerned with methods of preparing such organic semiconductor compositions and layers and uses thereof. The invention has application in the field of printed electronics and is particularly useful as a semiconducting material for use in formulations for organic thin film transistor (OTFT) backplanes for displays, integrated circuits, organic light emitting diodes (OLEDs), photodetectors, organic photovoltaic (OPV) cells, sensors, memory elements and logic circuits.

  本发明涉及有机共聚物和包括这些材料的有机半导体组合物，包括包含这种有机半导体组合物的层和器件。本发明还涉及制备这种有机半导体组合物和层的方法及其用途。本发明在印刷电子领域具有应用，并且作为用于有机薄膜晶体管（OTFT）背板的半导体材料特别有用，用于显示器、集成电路、有机发光二极管（OLED）、光电探测器、有机光伏（OPV）电池、传感器、存储元件和逻辑电路的配方。
• Transistors and methods for making them
  申请人：Wuhan Xinqu Chuangrou Optoelectronics Technology Co., Ltd.

  公开号：US10121970B2

  公开（公告）日：2018-11-06

  A semiconductor composition which comprises a soluble polyacene semiconductor and a polymeric semiconducting binder the binder having a permittivity greater than 3.4 at 000 Hz. The charge mobility of the semiconducting binder when measured in a pure state is greater than 10−7 cm2/Vs and more preferably greater than 10−6 cm2/Vs. Organic thin film transistors in which the source and drain electrodes are bridged by the semiconductor composition have desirable properties of reproducibility and charge mobility. The organic semiconducting composition can be applied by solution coating.

  一种半导体组合物，它包括一种可溶性多烯半导体和一种聚合物半导体粘结剂，粘结剂在 000 Hz 时的介电常数大于 3.4。在纯净状态下测量半导体粘合剂的电荷迁移率大于 10-7 cm2/Vs，更优选大于 10-6 cm2/Vs。源极和漏极由半导体粘合剂桥接的有机薄膜晶体管具有理想的再现性和电荷迁移率。有机半导体组合物可以通过溶液涂覆的方式使用。
• Organic semiconductor compositions
  申请人：SMARTKEM LIMITED

  公开号：US10580989B2

  公开（公告）日：2020-03-03

  The present invention relates to organic copolymers and organic semiconducting compositions comprising these materials, including layers and devices comprising such organic semiconductor compositions. The invention is also concerned with methods of preparing such organic semiconductor compositions and layers and uses thereof. The invention has application in the field of printed electronics and is particularly useful as the semiconducting material for use in formulations for organic thin film transistor (OFET) backplanes for displays, integrated circuits, organic light emitting diodes (OLEDs), photodetectors, organic photovoltaic (OPV) cells, sensors, memory elements and logic circuits.

  本发明涉及有机共聚物和包含这些材料的有机半导体组合物，包括包含这种有机半导体组合物的层和器件。 本发明还涉及制备这种有机半导体组合物和层的方法及其用途。 本发明可应用于印刷电子领域，特别是作为半导体材料用于显示器有机薄膜晶体管（OFET）背板、集成电路、有机发光二极管（OLED）、光电探测器、有机光伏（OPV）电池、传感器、存储元件和逻辑电路的配方中。
• SEMICONDUCTOR COMPOSITIONS FOR ORGANIC TRANSISTORS
  申请人：NEUDRIVE LIMITED

  公开号：EP2715820B1

  公开（公告）日：2018-02-14
• SEMICONDUCTOR COMPOUNDS
  申请人：NEUDRIVE LIMITED

  公开号：EP2715819B1

  公开（公告）日：2018-03-21