bis[2-hydroxy-N'-(propan-2-ylidene)benzohydrazonato]copper(II) | 113971-31-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: bis[2-hydroxy-N'-(propan-2-ylidene)benzohydrazonato]copper(II)
• 英文别名: copper(II) acetone salicyloylhydrazone；copper;(1Z)-2-hydroxy-N-propan-2-ylidenebenzenecarbohydrazonate
• CAS: 113971-31-6
• 化学式: C₂₀H₂₂CuN₄O₄
• 分子量: 445.965
• InChiKey: FQCRSEFNOSIDME-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.79
• 重原子数：
  29
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  136
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-((salicyclohydrazono)methyl)benzoic acid 以 N,N-二甲基甲酰胺 为溶剂， 反应 337.0h， 生成 bis[2-hydroxy-N'-(propan-2-ylidene)benzohydrazonato]copper(II)
  参考文献：
  名称：

  Synthesis, crystal structures, and selected properties of Cu(II) and Zn(II) complexes with in situ formed 2-hydroxy-N′-(propan-2-ylidene)benzohydrazide

  摘要：

  Cu(C10H11O2N2)2 (1) and [Zn(C10H12O2N2)2(H2O)2](NO3)2 (2) were synthesized and characterized by elemental analysis, FT-IR spectra, UV-Vis absorption spectroscopy, and X-ray single-crystal diffraction. Both complexes show distorted octahedral geometry. In 1, Cu(II) is coordinated by four oxygen atoms from four ligands and two nitrogen atoms from two ligands. In 2, Zn(II) is coordinated by two oxygen atoms and two nitrogen atoms from two ligands, and two water molecules. The crystal structures suggest that original ligand o-carboxybenzaldehyde salicyloylhydrazone (C15H12O4N2) changed into acetone salicyloylhydrazone (C10H12O2N2). The TG-DTG curves of these complexes indicate two different decomposition processes. 1 and 2 display catalytic activities to decomposition of hydrogen peroxide. Interaction between the complexes and DNA studied by UV-Vis titration shows the insert interaction.

  DOI：

  10.1080/00958972.2012.738813

文献信息

• Johari, R. B.; Nagar, Rajesh; Sharma, R. C., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1987, vol. 26, # 11, p. 962 - 963
  作者：Johari, R. B.、Nagar, Rajesh、Sharma, R. C.

  DOI：——

  日期：——