Bicyclo<2.2.1>hept-2-en-2-carbonitril | 24993-48-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Bicyclo<2.2.1>hept-2-en-2-carbonitril
• 英文别名: 2-Cyanonorbornene；2-Cyan-cicyclo<2.2.1>hepten-(2)；bicyclo[2.2.1]hept-2-ene-2-carbonitrile
• CAS: 24993-48-4
• 化学式: C₈H₉N
• 分子量: 119.166
• InChiKey: PUTPZPOLWBZQHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Bicyclo<2.2.1>hept-2-en-2-carbonitril 生成 1-cyanobicyclo<4.10>hept-2-ene
  参考文献：
  名称：

  AKETAR, I. A.;MCCULLOUGH, J. J.;VAITEKUNAS, S.;FAGGIANI, R.;LOCK, C. J. L+, CAN. J. CHEM., 1982, 60, N 13, 1657-1663

  摘要：

  DOI：
• 作为产物：
  描述：

  降樟脑 在 吡啶 、 盐酸 、 zinc(II) iodide 作用下， 以 二氯甲烷 为溶剂， 反应 9.0h， 生成 Bicyclo<2.2.1>hept-2-en-2-carbonitril
  参考文献：
  名称：

  Geier, Holger; Kautz, Cornelia Brigitte; Kirmse, Wolfgang, Chemische Berichte, 1993, vol. 126, # 3, p. 739 - 746

  摘要：

  DOI：

文献信息

• GENERATION OF ENDO- AND/OR EXO-NORBORNENECARBOXALDEHYDE AS AN INTERMEDIATE TO FUNCTIONALIZED NORBORNENES
  申请人：Bell Andrew

  公开号：US20090118539A1

  公开（公告）日：2009-05-07

  Embodiments in accordance with the present invention provide for forming essentially pure diastereomers of 5/6-substituted norbornene-type monomers. Further, embodiments in accordance with the present invention encompass polymerizing such diastereomers to form addition or ROMP polymers where a desired exo-/endo-ratio of the diastereomers is provided to the polymerization, such ratio designed to provide a desired ratio of endo-/exo-structured repeating units for a resulting polymer to have desired physical or chemical properties.

  根据本发明的实施例，提供形成基本纯的5/6-取代去氢莰烯型单体的异构体。此外，根据本发明的实施例涵盖聚合这种异构体以形成加成或ROMP聚合物，其中所提供给聚合反应的异构体的期望外/内比例设计为提供所得聚合物具有期望的物理或化学性质的外/内结构重复单元的期望比例。
• Process for forming perfluorinated-alkyl sulfonamide substituted norbornene-type monomers
  申请人：Bell Andrew

  公开号：US20080027246A1

  公开（公告）日：2008-01-31

  Embodiments in accordance with the present invention are directed to providing processes for forming fluorinated-alkyl and particularly perfluorinated-alkyl sulfonamide substituted norbornene-type monomers.

  本发明实施例涉及提供用于形成氟化烷基和特别是全氟烷基磺酰胺取代的诺博烯型单体的过程。
• 3-Acetoxy-2-dimethylphosphonoacrylates. New Dienophiles and Their Use for the Synthesis of Carbocyclic C-Nucleoside Precursors by the Aid of RRA Reaction
  作者：Nobuya Katagiri、Mitsuo Yamamoto、Chikara Kaneko

  DOI：10.1246/cl.1990.1855

  日期：1990.10

  3-acetoxy-2-dimethylphosphonoacrylates, have been prepared and their Diels-Alder reactions with cyclopentadiene investigated. The [4 + 2] adducts thus formed were converted to carbocyclic C-nucleoside precursors by means of reductive retrograde aldol (RRA) reaction.

  已经制备了新的亲二烯体，3-乙酰氧基-2-二甲基膦酰基丙烯酸酯，并研究了它们与环戊二烯的 Diels-Alder 反应。如此形成的 [4 + 2] 加合物通过还原逆行醛醇 (RRA) 反应转化为碳环 C-核苷前体。
• Photoresist composition for deep ultraviolet lithography
  申请人：——

  公开号：US20020187419A1

  公开（公告）日：2002-12-12

  The present invention relates to a novel photoresist composition sensitive in the deep ultraviolet region and a method of processing the novel photoresist, where the photoresist comprises a novel copolymer, a photoactive component, and a solvent. The novel copolymer comprises a unit derived from an ethylenically unsaturated compound containing at least one cyano functionality and a unit derived from an unsaturated cyclic non aromatic compound.

  本发明涉及一种新型的光阻组合物，对深紫外区域敏感，并提供一种处理新型光阻的方法，其中光阻包括一种新型共聚物、一种光活性组分和一种溶剂。所述新型共聚物包括从至少含有一个氰基官能团的乙烯基不饱和化合物和一个不饱和环状非芳香化合物中导出的单元。
• NOVEL POLYMER SUITABLE FOR PHOTORESIST COMPOSITIONS
  申请人：——

  公开号：US20030013831A1

  公开（公告）日：2003-01-16

  The present invention relates to a novel polymer comprising at least one unit derived from an ethylenically unsaturated compound containing at least one cyano functionality and at least one nonaromatic cyclic unit. The novel polymer is particularly useful when used in a photoresist composition sensitive in the deep ultraviolet region.

  本发明涉及一种新型聚合物，包括至少一个由含有至少一个氰基功能和至少一个非芳香环状单元的乙烯基不饱和化合物导出的单元。当用于深紫外区域敏感的光阻组合物时，该新型聚合物特别有用。