申请人:ExxonMobil Chemical Patents Inc.
公开号:US10017708B2
公开(公告)日:2018-07-10
This disclosure relates to a composition for use as an additive for fuels and lubricants including a reductive amination product of a vinyl terminated macromonomer (VTM) based aldehyde. Optionally aldehyde is reacted with the amino compound under condensation conditions sufficient to give an imine intermediate, and the imine intermediate is reacted under hydrogenation conditions sufficient to give the composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde. A reductive amination method for making a composition for use as an additive for fuels and lubricants. The method includes reacting a VTM based aldehyde with an amino compound containing at least one —NH— group under condensation conditions sufficient to give an imine intermediate, and reacting the imine intermediate under hydrogenation conditions sufficient to give said composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde.
本公开涉及一种用作燃料和润滑剂添加剂的组合物,包括基于乙烯端基的大分子单体(VTM)为基础的醛的还原胺化产物。可选地,醛与氨基化合物在足以形成亚胺中间体的缩合条件下反应,然后在足以形成该组合物的氢化条件下反应。醛是通过在足以形成醛的羟甲基化条件下反应VTM形成的。一种用于制备用作燃料和润滑剂添加剂的组合物的还原胺化方法。该方法包括在足以形成亚胺中间体的缩合条件下,反应基于VTM的醛与至少含有一个—NH—基团的氨基化合物,并在足以形成所述组合物的氢化条件下反应亚胺中间体。醛是通过在足以形成醛的羟甲基化条件下反应VTM形成的。