2-Benzyloxy-1-naphthol | 152335-24-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-Benzyloxy-1-naphthol
• 英文别名: 2-Phenylmethoxynaphthalen-1-ol
• CAS: 152335-24-5
• 化学式: C₁₇H₁₄O₂
• 分子量: 250.297
• InChiKey: DIIHAVLLUAWECU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Benzyloxy-1-naphthol 在 三乙胺 、 silver(l) oxide 作用下， 以 二氯甲烷 为溶剂， 以80%的产率得到2,2'-Dibenzyloxy-4,4'-binaphthylidene-1,1'-dione
  参考文献：
  名称：

  Kral, Andreas; Laatsch, Hartmut, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1993, vol. 48, # 10, p. 1401 - 1407

  摘要：

  DOI：
• 作为产物：
  描述：

  2-苄氧基-1-萘醛 在 过氧乙酸 、 二异丁基氢化铝 作用下， 以 四氢呋喃 、 乙酸乙酯 、 甲苯 为溶剂， 反应 1.0h， 生成 2-Benzyloxy-1-naphthol
  参考文献：
  名称：

  2-Alkoxyarenol-derived orthoquinols in carbon–oxygen, carbon–nitrogen and carbon–carbon bond-forming reactions

  摘要：

  Silylated oxygen- and nitrogen-tethered orthoquinol acetates, generated by phenyliodine(III) diacetoxy-mediated oxidative acetoxylation of 2-alkoxyphenols in CH2Cl2 can be used to furnish regioselectively benzannulated heterocycles. Oxidative activation of 2-alkoxynaphthols with non-nucleophilic phenyliodine(III) bis(trifluoroacetoxy) in the presence of carbon nucleophiles, including oxidation sensitive silyl enol ethers, constitute a potentially valuable route to naturally occurring vicinally oxygenated benz[a]anthracene motifs. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(00)00939-x

文献信息

• 10A-AZALIDE COMPOUND CROSSLINKED AT 10A- AND 12-POSITIONS
  申请人：Sugimoto Tomohiro

  公开号：US20110237784A1

  公开（公告）日：2011-09-29

  A novel 10a-azalide compound crosslinked at the 10a- and 12-positions, which is represented by the following formula, and is effective on even Hemophilus influenzae , or erythromycin resistant bacteria (e.g., resistant pneumococci and streptococci).

  一种新型的10a-azalide化合物，其在10a-和12-位置交联，化学式如下，并且对于Hemophilus influenzae，或者对红霉素产生耐药性的细菌（例如耐药性肺炎球菌和链球菌）具有有效性。
• ACIDIC TREATMENT-SUBJECTED MONOALKYLNAPHTHALENE FORMALDEHYDE RESIN
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC

  公开号：US20150037736A1

  公开（公告）日：2015-02-05

  Provided are a novel resin and a precursor thereof that are excellent in thermal decomposability and solubility in a solvent. The resin is obtained by subjecting, to an acidic treatment, a monoalkylnaphthalene formaldehyde resin that is obtained by reacting a compound represented by the following formula (1), wherein R 1 represents an alkyl group having 1 to 4 carbon atoms, and formaldehyde in the presence of a catalyst.

  提供了一种新型的树脂及其前体，其在热分解性和在溶剂中的溶解性方面表现出色。该树脂是通过对一种单烷基萘甲醛树脂进行酸处理而得到的，该树脂是通过在催化剂存在下将以下公式（1）所代表的化合物（其中R1代表具有1至4个碳原子的烷基）和甲醛反应而得到的。
• NOVEL COMPOUND AND ORGANIC ELECTROLUMINESCENT ELEMENT PRODUCED USING SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20160172604A1

  公开（公告）日：2016-06-16

  A compound represented by the following formula (1): wherein in the formula, L 1 is a single bond or a linking group, A is a group represented by the following formula (A), B is a group represented by the following formula (B), m is an integer of 1 to 3, and n is an integer of 1 to 4.

  以下式子(1)所代表的化合物：其中在式子中，L1是单键或连接基团，A是由以下式子(A)所代表的基团，B是由以下式子(B)所代表的基团，m为1到3的整数，n为1到4的整数。
• EPOXY RESIN, PRODUCTION METHOD THEREOF, EPOXY RESIN COMPOSITION, AND CURED PRODUCT
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US20150322308A1

  公开（公告）日：2015-11-12

  An epoxy resin obtained through the following steps (a) to (d): (a): a step of reacting a compound represented by formula (1) and/or (2) with formaldehyde in the presence of a catalyst to thereby provide an aromatic hydrocarbon-formaldehyde resin; (b): a step of treating the aromatic hydrocarbon-formaldehyde resin obtained in the step (a) with an acidic catalyst and water to thereby provide an acid-treated resin; (c): a step of treating the acid-treated resin obtained in the step (b) with an acidic catalyst and a compound represented by formula (3) to thereby provide a modified resin; and (d): a step of reacting the modified resin obtained in the step (c) with epihalohydrin to thereby provide an epoxy resin.

  通过以下步骤（a）至（d）获得的环氧树脂： （a）：在催化剂的存在下，将式（1）和/或（2）表示的化合物与甲醛反应，从而提供芳香族烃-甲醛树脂； （b）：用酸性催化剂和水处理在步骤（a）中获得的芳香族烃-甲醛树脂，从而提供处理后的树脂； （c）：用酸性催化剂和式（3）表示的化合物处理在步骤（b）中获得的处理后的树脂，从而提供修饰树脂； （d）：用环氧氯丙烷与在步骤（c）中获得的修饰树脂反应，从而提供环氧树脂。
• AROMATIC HYDROCARBON FORMALDEHYDE RESIN, MODIFIED AROMATIC HYDROCARBON FORMALDEHYDE RESIN, AND EPOXY RESIN, AND METHOD FOR PRODUCING THESE
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20160130383A1

  公开（公告）日：2016-05-12

  There is provided an aromatic hydrocarbon formaldehyde resin obtained by reacting an aromatic hydrocarbon compound (A) represented by the following formula (1) with formaldehyde (B) in the presence of an acidic catalyst. wherein R represents an organic group having 1 to 10 carbon atoms; l represents an integer of 0 to 2, and m and n represent integers satisfying 1≦m+n≦10, m≧0 and n≧1.

  提供了一种芳香族烃醛树脂，其通过在酸性催化剂存在下将以下式(1)所代表的芳香族烃化合物(A)与甲醛(B)反应而得到。其中，R代表具有1至10个碳原子的有机基团；l代表0至2的整数，m和n代表满足1≦m+n≦10、m≧0和n≧1的整数。