9-(4-trifluoromethylphenyl)fluoren-9-ol | 123613-84-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9-(4-trifluoromethylphenyl)fluoren-9-ol
• 英文别名: 9-(4-(trifluoromethyl)phenyl)-9H-fluoren-9-ol；9-[4-(Trifluoromethyl)phenyl]-9H-fluorene-9-ol；9-[4-(trifluoromethyl)phenyl]fluoren-9-ol
• CAS: 123613-84-3
• 化学式: C₂₀H₁₃F₃O
• 分子量: 326.318
• InChiKey: ZOKKNNHFEOQVPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  24
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  9-(4-trifluoromethylphenyl)fluoren-9-ol 在 sodium azide 、 三氟乙酸 作用下， 反应 6.0h， 以77%的产率得到6-(4-(trifluoromethyl)phenyl)phenanthridine
  参考文献：
  名称：

  Ring-Expansion Strategy for α-Aryl Azahelicene Construction: Building Blocks for Optoelectronic Materials

  摘要：

  DOI：

  10.1021/acs.orglett.1c03070
• 作为产物：
  描述：

  9-[4-(Trifluoromethyl)phenyl]fluoren-9-ylium 以 水 、 乙腈 为溶剂， 生成 9-(4-trifluoromethylphenyl)fluoren-9-ol
  参考文献：
  名称：

  Cozens, Frances L.; Mathivanan, N.; McClelland, Robert A., Journal of the Chemical Society. Perkin transactions II, 1992, # 12, p. 2083 - 2090

  摘要：

  DOI：

文献信息

• The Construction of H-shaped Fluorescent Materials Based on Building Blocks Consisting of Triphenylamine and Fluorene
  作者：Cheng Zhang、Yu-jian Zhang、Wen-qin Xiang、Bin Hu、Mi Ouyang、Yi Xu、Chun-an Ma

  DOI：10.1246/cl.2010.520

  日期：2010.5.5

  A class of complicated 9,9-diarylfluorenes as nonplanar building blocks were synthesized and utilized to prepare a novel H-shaped oligofluorene. High glass transition temperatures and excellent solubility of the obtained oligomers indicated the 9,9-diarylfluorenes would be promising building blocks for the construction of H-shaped optoelectronic materials.

  合成了一类复杂的9,9-二芳基芴作为非平面构建块，并利用其制备了一种新型的H形寡芴。所得寡聚物的高玻璃转变温度和优良的溶解性表明，9,9-二芳基芴将是构建H形光电材料的有前景的构建块。
• Structures, Lewis Acidities, Electrophilicities, and Protecting Group Abilities of Phenylfluorenylium and Tritylium Ions
  作者：Elsa Follet、Peter Mayer、Guillaume Berionni

  DOI：10.1002/chem.201603963

  日期：2017.1.12

  groups and how their tuning is possible. Determination of the equilibrium constants of the Lewis adducts formation between pyridines of calibrated Lewis basicities and phenylfluorenylium and tritylium ions allowed the determination of their Lewis acidities and to showcase the potential of these carbon‐centered Lewis acids in catalysis.

  报告了芴基离子及其路易斯氮原子和磷中心的路易斯碱的分离，表征和第一个X射线结构。一系列芴基离子与各种大小和亲核性的π，σ和n亲核体的反应动力学，可以阐明这些平面化叔碳离子的亲电子性的电子和结构参数之间的相互作用。描述了结构反应性的相关性以及它们与二芳基和三芳基碳鎓离子的反应性的广泛比较。芴鎓离子电性的定量测定揭示了它们在多大程度上与作为保护基团的三苯甲基离子互补，以及如何进行调节。
• Rhodium- and Iridium-Catalyzed Dehydrogenative Cyclization through Double C–H Bond Cleavages To Produce Fluorene Derivatives
  作者：Masaki Itoh、Koji Hirano、Tetsuya Satoh、Yu Shibata、Ken Tanaka、Masahiro Miura

  DOI：10.1021/jo4000465

  日期：2013.2.15

  The rhodium-catalyzed cyclization of a series of 2,2-diarylalkanoic acids in the presence of copper acetate as an oxidant smoothly proceeded through double C-H bond cleavages and subsequent decarboxylation to produce the corresponding fluorene derivatives. The direct cyclization of triarylmethanols also took place efficiently by using an iridium catalyst in place of the rhodium, while the hydroxy function was still intact.
• Taljaard, Benjamin; Goosen, Andre; McCleland, Cedric W., Journal of the Chemical Society. Perkin transactions I, 1989, p. 931 - 934
  作者：Taljaard, Benjamin、Goosen, Andre、McCleland, Cedric W.

  DOI：——

  日期：——
• TALIAARD, BENJAMIN;GOOSEN, ANDRE;MCCLELAND, CEDRIC W., J. CHEM. SOC. PERKIN TRANS. PT 1,(1989) N, C. 931-934
  作者：TALIAARD, BENJAMIN、GOOSEN, ANDRE、MCCLELAND, CEDRIC W.

  DOI：——

  日期：——