Ni[bis(2,5-dihydroxysalicylidene)ethylenediaminato]*EtOH | 514221-05-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: Ni[bis(2,5-dihydroxysalicylidene)ethylenediaminato]*EtOH
• CAS: 514221-05-7
• 化学式: C₂H₆O*C₁₆H₁₄N₂NiO₄
• 分子量: 403.057
• InChiKey: CWAOQYZKQJPDQP-CKNTWHFTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N-双(5-羟基水杨基)乙二胺 、 乙醇 、 nickel(II) acetate tetrahydrate 以 乙醇 为溶剂， 生成 Ni[bis(2,5-dihydroxysalicylidene)ethylenediaminato]*EtOH
  参考文献：
  名称：

  Synthesis and crystal structure of [Ni{bis(2,5-dihydroxysalicylidene)ethylenediaminato}]: a hydrogen bonded assembly of Ni(II)–salen complex

  摘要：

  The hydrogen bonded assembly of salen type complexes was studied. The nickel(II) complex with N,N'-bis(2,5-dihydroxysalicylidene)ethylenediaminato was synthesized, and structurally characterized. The compound has two hydroxy groups at the both terminals of the tetradentate ligand. One of the two hydroxy groups of the nickel(II) complex forms a hydrogen bond with a coordinating oxygen donor of the adjacent molecule to yield a hydrogen bonded one-dimensional chain. These chains are also associated by pi-pi interactions with interlocking fashion to produce a two-dimensional structure. The guest ethanol molecules are incorporated between the two-dimensional layers. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(02)00708-6