NSC 162535 | 13617-83-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: NSC 162535
• 英文别名: 7-amino-4,4'-dihydroxy-3,7'-azo-bis-naphthalene-2-sulfonic acid；7-Amino-4,4'-dihydroxy-3,7'-azo-bis-naphthalin-2-sulfonsaeure；6-Amino-1.5'-dihydroxy-[2.2']azonaphthalin-disulfonsaeure-(3.7')；7-Amino-4-Hydroxy-3-[(E)-(5-Hydroxy-7-Sulfonaphthalen-2-Yl)diazenyl]naphthalene-2-Sulfonic Acid；7-amino-4-hydroxy-3-[(5-hydroxy-7-sulfonaphthalen-2-yl)diazenyl]naphthalene-2-sulfonic acid
• CAS: 13617-83-9
• 化学式: C₂₀H₁₅N₃O₈S₂
• 分子量: 489.486
• InChiKey: ZSHNSNDVNDUHIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  217
• 氢给体数：
  5
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  NSC 162535 、 4-氨基苯乙酮 在 盐酸 、 sodium carbonate 、 sodium nitrite 作用下， 以 水 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  Dichroic and spectral properties of anthraquinone-based azo dyes for PVA polarizing film

  摘要：

  Dichroic dyes with broad absorption bands are advantageous for the production of neutral gray polarizing films. For this purpose, anthraquinone-based azo dyes were synthesized to have a conjugated bichromophore design and this was applied to PVA polarizing films. The spectral and dichroic properties of the polarizing films were examined and compared to the films produced with a general disazo dichroic dye. The polarizing films with anthraquinone-based azo dyes had wider absorption bands, but lower dichroic ratios compared to the films with a general disazo dichroic dye. It was found that the alignment between the transition moments of the anthraquinone and azo chromophores is an important factor for the dichroic properties of anthraquinone-based azo dyes. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.06.024
• 作为产物：
  描述：

  7-氨基-4-羟基-2-萘磺酸 在 盐酸 、 sodium carbonate 、 sodium nitrite 作用下， 以 水 为溶剂， 反应 3.0h， 生成 NSC 162535
  参考文献：
  名称：

  Dichroic and spectral properties of anthraquinone-based azo dyes for PVA polarizing film

  摘要：

  Dichroic dyes with broad absorption bands are advantageous for the production of neutral gray polarizing films. For this purpose, anthraquinone-based azo dyes were synthesized to have a conjugated bichromophore design and this was applied to PVA polarizing films. The spectral and dichroic properties of the polarizing films were examined and compared to the films produced with a general disazo dichroic dye. The polarizing films with anthraquinone-based azo dyes had wider absorption bands, but lower dichroic ratios compared to the films with a general disazo dichroic dye. It was found that the alignment between the transition moments of the anthraquinone and azo chromophores is an important factor for the dichroic properties of anthraquinone-based azo dyes. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.06.024

文献信息

• Konstitution und Dispersitätsgrad von Azofarbstoffen. (5. Mitteilung). über Azofarbstoffe und ihre Zwischenprodukte
  作者：Paul Rugggli、Arthur Zimmermann

  DOI：10.1002/hlca.19310140110

  日期：——
• METHOD OF INHIBITING THE GROWTH OF HELICOBACTER PYLORI
  申请人：WANG WEN-CHING

  公开号：US20100305152A1

  公开（公告）日：2010-12-02

  The shikimate pathway links metabolism of carbohydrates to biosynthesis of aromatic compounds, which is an attractive target for the rational drug and herbicide design because it is essential in algae, higher plants, bacteria, and fungi, but absent from mammals. Thus, the present invention provides a method of inhibiting the growth of bacteria or fungi, especially Helicobacter pylori, through inhibiting enzymes in the shikimate pathway.
• US8175860B2
  申请人：——

  公开号：US8175860B2

  公开（公告）日：2012-05-08
• Dichroic and spectral properties of anthraquinone-based azo dyes for PVA polarizing film
  作者：Jae Bok Chang、Sim Bum Yuk、Jong S. Park、Jae Pil Kim

  DOI：10.1016/j.dyepig.2011.06.024

  日期：2012.1

  Dichroic dyes with broad absorption bands are advantageous for the production of neutral gray polarizing films. For this purpose, anthraquinone-based azo dyes were synthesized to have a conjugated bichromophore design and this was applied to PVA polarizing films. The spectral and dichroic properties of the polarizing films were examined and compared to the films produced with a general disazo dichroic dye. The polarizing films with anthraquinone-based azo dyes had wider absorption bands, but lower dichroic ratios compared to the films with a general disazo dichroic dye. It was found that the alignment between the transition moments of the anthraquinone and azo chromophores is an important factor for the dichroic properties of anthraquinone-based azo dyes. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.