2-methoxy-3-(2-propenyl)phenol | 1941-12-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-methoxy-3-(2-propenyl)phenol
• 英文别名: phenol, 2-methoxy-3-(2-propenyl)-；3-allylguaiacol；3-allyl-2-methoxyphenol；2-methoxy-3-allylphenol；Phenol, 2-methoxy(2-propenyl)-；2-methoxy-3-prop-2-enylphenol
• CAS: 1941-12-4
• 化学式: C₁₀H₁₂O₂
• mdl: MFCD24392709
• 分子量: 164.204
• InChiKey: HKHVWTUGAJEQNP-UHFFFAOYSA-N

物化性质

• 熔点：
  92-93 °C
• 沸点：
  119-120 °C(Press: 12 Torr)
• 密度：
  1.0762 g/cm3(Temp: 16 °C)
• 保留指数：
  1362;1392

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methoxy-3-(2-propenyl)phenol 、 N,N-二乙基氯乙胺 生成 diethyl-[2-(3-allyl-2-methoxy-phenoxy)-ethyl]-amine
  参考文献：
  名称：

  Pal'gi, Zhurnal Obshchei Khimii, 1958, vol. 28, p. 2239,2241; engl. Ausg. S. 2275, 2277

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 水 作用下， 生成 2-methoxy-3-(2-propenyl)phenol
  参考文献：
  名称：

  Pal'gi, Zhurnal Obshchei Khimii, 1958, vol. 28, p. 2239,2241; engl. Ausg. S. 2275, 2277

  摘要：

  DOI：

文献信息

• Photoinduced Copper‐Catalyzed Coupling of Terminal Alkynes and Alkyl Iodides
  作者：Avijit Hazra、Mitchell T. Lee、Justin F. Chiu、Gojko Lalic

  DOI：10.1002/anie.201801085

  日期：2018.5.4

  We have developed a photoinduced copper‐catalyzed alkylation of terminal alkynes with primary, secondary, or tertiary alkyl iodides as electrophiles. The reaction has a broad substrate scope and can be successfully performed in the presence of ester, nitrile, aryl halide, ketone, sulfonamide, epoxide, alcohol, and amide functional groups. The alkylation is promoted by blue light (λ≈450 nm) and proceeds

  我们已经开发出了以伯，仲或叔烷基碘为亲电试剂的末端炔烃的光诱导铜催化烷基化反应。该反应具有广泛的底物范围，并且可以在酯，腈，卤代芳基，酮，磺酰胺，环氧化物，醇和酰胺官能团的存在下成功进行。该烷基化是由蓝色光促进（λ ≈450nm）与在没有任何附加的金属催化剂的室温下进行。联吡啶配体的使用对于反应的成功至关重要，而且可以防止光诱导的铜催化原料的聚合。
• Method for producing alkoxy-hydroxybenzaldehyde that is substantially free of alkyl-alkoxy-hydroxybenzaldehyde
  申请人：RHODIA OPERATIONS

  公开号：US20150203428A1

  公开（公告）日：2015-07-23

  The invention relates to a method for producing at least one alkoxy-hydroxybenzaldehyde (AHBA) from at least one hydroxyphenol (HP), said method being characterised in that it comprises the formation of at least one alkoxyphenol (AP) and alkyl-alkoxyphenol (AAP) and the separation (S) of AP from AAP, said separation (S) being carried out prior to obtaining AHBA.

  该发明涉及一种从至少一种羟基苯酚（HP）生产至少一种烷氧基-羟基苯甲醛（AHBA）的方法，其特征在于包括形成至少一种烷氧基苯酚（AP）和烷基烷氧基苯酚（AAP），并将AP与AAP分离（S），所述分离（S）在获得AHBA之前进行。
• [EN] CATALYTIC CONVERSION OF BIOMASS TO BIOPHENOL<br/>[FR] CONVERSION CATALYTIQUE DE BIOMASSE EN BIOPHÉNOL
  申请人：UNIV EINDHOVEN TECH

  公开号：WO2019177458A1

  公开（公告）日：2019-09-19

  The invention relates to a demethoxylation process for demethoxylating alkylmethoxyphenols using an aromatic solvent to produce alkylphenols. The invention also relates to dealkylation process for dealkylating alkylphenols using an aromatic solvent to produce phenol. The invention further relates to a tandem demethoxylation and dealkylation process, which can be performed in a single reactor. The process is useful in the conversion of lignin derived alkylmethoxyphenols into biophenol.

  该发明涉及一种利用芳香溶剂进行去甲基化的去甲氧基烷基甲氧基苯酚的方法，以产生烷基苯酚。该发明还涉及一种利用芳香溶剂进行去烷基化的去烷基烷基苯酚的方法，以产生酚。该发明还涉及一种串联去甲基化和去烷基化的方法，可以在单个反应器中进行。该过程对于将木质素衍生的烷基甲氧基苯酚转化为生物酚具有用处。
• [EN] APPLICATION OF NATURAL AND SYNTHETIC EUGENOL AND ESSENTIAL OILS FROM CLOVES, PIMENTOS AND CINNAMON LEAVES FOR THE PREVENTION AND TREATMENT OF ANIMAL DISEASES CAUSED BY BACTERIA, FUNGI AND PARASITES<br/>[FR] UTILISATION D'EUGENOL NATUREL OU SYNTHETIQUE ET D'HUILES ESSENTIELLES, DE CLOUS DE GIROFLE, DE PIMENTS ET DE FEUILLES DE CANNELLE POUR LA PREVENTION ET LE TRAITEMENT DE MALADIES ANIMALES PROVOQUEES PAR DES BACTERIES, DES CHAMPIGNONS OU DES PARASITES
  申请人：GLIGOVIC VOJIN

  公开号：WO2005074965A1

  公开（公告）日：2005-08-18

  Patent registration refers to applications of natural and synthetic eugenol, essential oils from plants containing eugenol: cloves (Eugenia caryophyllata), pimentos (Pimenta officinalis)and cinnamon leaves (Cinnamomum zeylanicum) in the prevention and treatment of animal diseases caused by bacteria, fungi and parasites. The technical problem of improvement of properties of veterinary preparations has been resolved so that natural and synthetic eugenol and eugenol from plant essential oils (cloves, pimentos and cinnamon leaves) have been added to them. This considerably prevents growth of bacteria, fungi and parasites or destroys them resulting in preventive effects or treatment of animals affected by some of the above disease causes. By applying eugenol in veterinary preparations in one of the above mentioned forms, negative effects and counter indications have been avoided and use of preparations has been made possible during the entire cycle of animal breeding.

  专利注册指的是将天然和合成丁香酚、植物精油中含有丁香酚的植物（丁香、肉豆蔻和肉桂叶）应用于预防和治疗由细菌、真菌和寄生虫引起的动物疾病的申请。改进兽药制剂性能的技术问题已得到解决，使得天然和合成丁香酚以及来自植物精油（丁香、肉豆蔻和肉桂叶）的丁香酚被添加到其中。这显著地防止了细菌、真菌和寄生虫的生长或摧毁它们，从而产生预防作用或治疗受到上述疾病原因影响的动物。通过在兽药制剂中应用上述任一形式的丁香酚，避免了负面影响和禁忌症，并使得在整个动物繁殖周期中使用制剂成为可能。
• Antibacterial antiplaque mouthwash composition
  申请人：Colgate-Palmolive Company

  公开号：EP0579383A1

  公开（公告）日：1994-01-19

  An oral composition mouthwash or liquid dentifrice containing an aqueous vehicle acceptable vehicle including an alcohol, a substantially water-insoluble noncationic antibacterial antiplaque agent, such as 2,4,4'-trichloro-2'-hydroxy-diphenyl ether (triclosan) wherein the antiplaque agent is entirely dissolved in the solvent and the weight ratio of water to alcohol is in excess of about 10:1.

  一种口腔组合物漱口水或液体牙膏，含有可接受的水性载体，包括酒精、基本不溶于水的非阳离子抗菌消泡剂，如 2,4,4'-三氯-2'-羟基二苯醚（三氯生），其中消泡剂完全溶解在溶剂中，水与酒精的重量比超过约 10:1。