3',3'-dimethyl-6-nitro-1'-(2-propenyl)spiro<2H-1-benzopyran-2,2'-indoline>

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 3',3'-dimethyl-6-nitro-1'-(2-propenyl)spiro<2H-1-benzopyran-2,2'-indoline>
• 英文别名: 1-Allyl-3,3-dimethyl-6'-nitrospiro(indoline-2,2'-[2h]chromene)；3',3'-dimethyl-6-nitro-1'-prop-2-enylspiro[chromene-2,2'-indole]
• 化学式: C₂₁H₂₀N₂O₃
• 分子量: 348.401
• InChiKey: BOINAJVQPVNFJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  58.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  三乙氧基硅烷 、 3',3'-dimethyl-6-nitro-1'-(2-propenyl)spiro<2H-1-benzopyran-2,2'-indoline> 在 dihydrogen hexachloroplatinate 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 生成 1'-(3-triethoxysilanylpropyl)-3',3'-dimethyl-6-nitrospiro[2H-1]benzopyran-2,2'-indoline
  参考文献：
  名称：

  一种光致变色硅烷偶联剂及其制备方法和应用

  摘要：

  本发明公开了一种光致变色硅烷偶联剂及其制备方法和应用，由带有双键侧链的螺吡喃和三烷氧基硅氢在催化剂作用下通过硅氢加成反应生成。本发明硅烷偶联剂通过在硅原子上增加螺吡喃分子，从而实现在改性的同时具有光致变色的作用，可作为纳米粉体或橡胶的改性剂和变色剂，反应操作简单，且与纳米粉体或橡胶的相容性好，不会降低纳米粉体或橡胶的自身性能，是一种十分理想的硅烷偶联剂。

  公开号：

  CN113773341B
• 作为产物：
  描述：

  2,3,3-三甲基-3H-吲哚 以 甲醇 为溶剂， 反应 92.75h， 生成 3',3'-dimethyl-6-nitro-1'-(2-propenyl)spiro<2H-1-benzopyran-2,2'-indoline>
  参考文献：
  名称：

  Synthesis and characterisation of polymerisable photochromic spiropyrans: towards photomechanical biomaterials

  摘要：

  A methodology for the synthesis of novel polymerisable spiropyrans with photomechanical properties suitable for subsequent copolymerisation with either vinyl or acrylate-based biomaterials is described. UV-vis spectroscopic characterisation of photoisomerism shows that photochromic behaviour with respect to related non-polymerisable compounds is retained and is solvent dependent. In acetone, conventional spiropyran-merocyanine photochromism is observed for nitro-spiropyran derivatives, whereas in dichloromethane both nitro-spiropyrans and spiropyrans isomerise to merocyanines which rapidly form H-aggregates. The monomers were designed such that an alkyl spacer of variable length, both electronically and sterically, separates the polymerisable moiety from the photochromic core and allows steric aspects of the resulting photomechanical behaviour to be explored. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.11.110

文献信息

• Duerr, Heinz; Ma, Yinmin; Cortellaro, Giorgio, Synthesis, 1995, p. 294 - 298
  作者：Duerr, Heinz、Ma, Yinmin、Cortellaro, Giorgio

  DOI：——

  日期：——
• Reversibly Switchable Surfactants and Methods of Use
  申请人：WARNER BABCOCK INSTITUTE FOR GREEN CHEMISTRY, LLC

  公开号：US20190152993A1

  公开（公告）日：2019-05-23

  Disclosed herein are reversibly-switchable surfactants and methods of extracting natural products, coating surfaces, cleaning laundry, and osmotic extraction using same.
• Synthesis and characterisation of polymerisable photochromic spiropyrans: towards photomechanical biomaterials
  作者：Colin P. McCoy、Louise Donnelly、David S. Jones、Sean P. Gorman

  DOI：10.1016/j.tetlet.2006.11.110

  日期：2007.1

  A methodology for the synthesis of novel polymerisable spiropyrans with photomechanical properties suitable for subsequent copolymerisation with either vinyl or acrylate-based biomaterials is described. UV-vis spectroscopic characterisation of photoisomerism shows that photochromic behaviour with respect to related non-polymerisable compounds is retained and is solvent dependent. In acetone, conventional spiropyran-merocyanine photochromism is observed for nitro-spiropyran derivatives, whereas in dichloromethane both nitro-spiropyrans and spiropyrans isomerise to merocyanines which rapidly form H-aggregates. The monomers were designed such that an alkyl spacer of variable length, both electronically and sterically, separates the polymerisable moiety from the photochromic core and allows steric aspects of the resulting photomechanical behaviour to be explored. (c) 2006 Elsevier Ltd. All rights reserved.
• 一种光致变色硅烷偶联剂及其制备方法和应用
  申请人：上海橡实化学有限公司

  公开号：CN113773341B

  公开（公告）日：2023-04-25

  本发明公开了一种光致变色硅烷偶联剂及其制备方法和应用，由带有双键侧链的螺吡喃和三烷氧基硅氢在催化剂作用下通过硅氢加成反应生成。本发明硅烷偶联剂通过在硅原子上增加螺吡喃分子，从而实现在改性的同时具有光致变色的作用，可作为纳米粉体或橡胶的改性剂和变色剂，反应操作简单，且与纳米粉体或橡胶的相容性好，不会降低纳米粉体或橡胶的自身性能，是一种十分理想的硅烷偶联剂。