Porphyrins with Exocyclic Rings. 16.<sup>1</sup> Synthesis and Spectroscopic Characterization of Fluoranthoporphyrins, a New Class of Highly Conjugated Porphyrin Chromophores
作者:Timothy D. Lash、Tonya M. Werner、Michelle L. Thompson、Jerad M. Manley
DOI:10.1021/jo010066s
日期:2001.5.1
Porphyrins with fused aromatic rings are under detailed investigation due to their unique spectroscopic properties. To gain more insights into the effects due to ring annealation on the porphyrin chromophore, a series of fluoranthoporphyrins have been synthesized. Reaction of 3-nitrofluoranthene with isocyanoacetate esters in the presence of a phosphazene base afforded good yields of the fluorantho[2