[Cu(II)-1,2-cyclohexanediamino-N,N'-bis(5-(4-azopyridyl)salicylidene)] | 1577222-96-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Cu(II)-1,2-cyclohexanediamino-N,N'-bis(5-(4-azopyridyl)salicylidene)]
• CAS: 1577222-96-8
• 化学式: C₃₀H₂₆CuN₈O₂
• 分子量: 594.135
• InChiKey: ZSJDRQZEHMPJJM-QZWCGGILSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-氨基吡啶 在 硫酸 、 sodium nitrite 作用下， 以 乙醇 、 水 为溶剂， 反应 5.02h， 生成 [Cu(II)-1,2-cyclohexanediamino-N,N'-bis(5-(4-azopyridyl)salicylidene)]
  参考文献：
  名称：

  Synthesis and Characterize of Multifunctional Schiff Base and Cu(II) Complex: An Optical Property Investigation

  摘要：

  A new mononuclear complex was successfully synthesized on the basis of a Schiff-base ligand L = 1, 2-cyclohexanediamino-N,N-bis(5-(4- azopyridyl) salicylidene) and CuCl2. Its structure was characterized by single-crystal X-ray diffraction, IR spectroscopy, and powder X-ray diffraction. The complex showed optical property, a fluorescence quantum yield at 405nm and 510nm, and sends a purple light at 405nm and blue-green light at 510nm when using a 300nm excitation light to stimulate the samples. The remarkable fluorescence quenching in emission upon the copper(II) is attributed to the intermolecular charge transfer after the formation of a coordinate complex. However, this application from the lighting angle can provide a beautiful series, energy conservation, safety of creative products.

  DOI：

  10.1080/15533174.2013.768644