2-aminoperfluorophenazine | 1185759-50-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 2-aminoperfluorophenazine
• 英文别名: 1,3,4,6,7,8,9-Heptafluorophenazin-2-amine；1,3,4,6,7,8,9-heptafluorophenazin-2-amine
• CAS: 1185759-50-5
• 化学式: C₁₂H₂F₇N₃
• 分子量: 321.157
• InChiKey: YTASSYBLKVTUKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.8
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2,3,4,5,7,8,9,10-octafluorophenazine 在 氨 、 三乙胺 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以88%的产率得到2-aminoperfluorophenazine
  参考文献：
  名称：

  Red solid-state fluorescent aminoperfluorophenazines

  摘要：

  The solid-state fluorescence of 2-amino-, 2-ethylamino, 2-diethylamino-, and 2.7-bis(diethylamino)perfluorophenazines was examined. They showed their fluorescence maxima in the range of 584-637 nm. The solid-state fluorescence quantum yield of 2-diethylamino derivative was highest among these derivatives, there being 0.22. X-ray crystallographic analysis suggests that the 2-diethylamino derivative has no strong intermolecular interactions among adjacent molecules to show intense fluorescence, whereas the other derivatives have network NH/F hydrogen, pi-pi, and CH/F interactions to reduce solid-state fluorescence intensity. (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2009.06.095

文献信息

• Red solid-state fluorescent aminoperfluorophenazines
  作者：Masaki Matsui、Rie Ikeda、Yasuhiro Kubota、Kazumasa Funabiki

  DOI：10.1016/j.tetlet.2009.06.095

  日期：2009.9

  The solid-state fluorescence of 2-amino-, 2-ethylamino, 2-diethylamino-, and 2.7-bis(diethylamino)perfluorophenazines was examined. They showed their fluorescence maxima in the range of 584-637 nm. The solid-state fluorescence quantum yield of 2-diethylamino derivative was highest among these derivatives, there being 0.22. X-ray crystallographic analysis suggests that the 2-diethylamino derivative has no strong intermolecular interactions among adjacent molecules to show intense fluorescence, whereas the other derivatives have network NH/F hydrogen, pi-pi, and CH/F interactions to reduce solid-state fluorescence intensity. (C) 2009 Published by Elsevier Ltd.