N-Phenyl-(3-phenyl-1-phenyliminoinden-2-yl)-amine | 42549-15-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: N-Phenyl-(3-phenyl-1-phenyliminoinden-2-yl)-amine
• 英文别名: 1-phenylimino-2-phenylamino-3-phenylindene；(1E)-N,3-Diphenyl-1-(phenylimino)-1H-inden-2-amine；N,1-diphenyl-3-phenyliminoinden-2-amine
• CAS: 42549-15-5
• 化学式: C₂₇H₂₀N₂
• 分子量: 372.469
• InChiKey: IBLMOUNKVHPTQF-UHFFFAOYSA-N

物化性质

• 沸点：
  532.7±50.0 °C(Predicted)
• 密度：
  1.11±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-Phenyl-(3-phenyl-1-phenyliminoinden-2-yl)-amine 在 硫化氢 、 苯胺 作用下， 反应 3.5h， 以86%的产率得到11-Phenylbenzindeno<2,1-e>-1,4-thiazine
  参考文献：
  名称：

  Cyclic meso-ionic heterocycles. Part 24. The reaction of 1,2-dithiolium-4-olates with aniline. The formationof 11-phenylbenz[b]indeno[2,1-e]-1,4-thiazine

  摘要：

  Reaction of the type B meso-ionic heterocycle 3,5-diphenyl-1,2-dithiolium-4-olate (1) with aniline yields N-phenyl-(3-phenyl-1-phenylimino-inden-2-yl)-amine (10) and 11-phenylbenz[b]indeno[2,1-e]-1,4-thiazine (12). Mechanistic investigations establish that the 3-phenylindenylamine (10) is an intermediate in the formation of the tetracyclic 1,4-thiazine (12).

  DOI：

  10.1016/s0040-4020(01)80482-8
• 作为产物：
  描述：

  3,5-diphenyl-1,2-dithiolium-4-olate 、 苯胺 反应 0.17h， 以32%的产率得到N-Phenyl-(3-phenyl-1-phenyliminoinden-2-yl)-amine
  参考文献：
  名称：

  Cyclic meso-ionic heterocycles. Part 24. The reaction of 1,2-dithiolium-4-olates with aniline. The formationof 11-phenylbenz[b]indeno[2,1-e]-1,4-thiazine

  摘要：

  Reaction of the type B meso-ionic heterocycle 3,5-diphenyl-1,2-dithiolium-4-olate (1) with aniline yields N-phenyl-(3-phenyl-1-phenylimino-inden-2-yl)-amine (10) and 11-phenylbenz[b]indeno[2,1-e]-1,4-thiazine (12). Mechanistic investigations establish that the 3-phenylindenylamine (10) is an intermediate in the formation of the tetracyclic 1,4-thiazine (12).

  DOI：

  10.1016/s0040-4020(01)80482-8

文献信息

• McKinnon, David M.; Clark, Peter D.; Martin, Robert O., Canadian Journal of Chemistry, 1987, vol. 65, p. 2830 - 2833
  作者：McKinnon, David M.、Clark, Peter D.、Martin, Robert O.、Delbaere, Louis T.J.、Quail, J.Wilson

  DOI：——

  日期：——
• Cyclic meso-ionic heterocycles. Part 24. The reaction of 1,2-dithiolium-4-olates with aniline. The formationof 11-phenylbenz[b]indeno[2,1-e]-1,4-thiazine
  作者：Christopher G. Newton、W.David Ollis、Graham P. Rowson、Margaret J. Hamor、Thomas A. Hamor

  DOI：10.1016/s0040-4020(01)80482-8

  日期：1992.1

  Reaction of the type B meso-ionic heterocycle 3,5-diphenyl-1,2-dithiolium-4-olate (1) with aniline yields N-phenyl-(3-phenyl-1-phenylimino-inden-2-yl)-amine (10) and 11-phenylbenz[b]indeno[2,1-e]-1,4-thiazine (12). Mechanistic investigations establish that the 3-phenylindenylamine (10) is an intermediate in the formation of the tetracyclic 1,4-thiazine (12).