3,3'-diaminotriphenylamine | 401604-20-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,3'-diaminotriphenylamine
• 英文别名: 3-N-(3-aminophenyl)-3-N-phenylbenzene-1,3-diamine
• CAS: 401604-20-4
• 化学式: C₁₈H₁₇N₃
• 分子量: 275.353
• InChiKey: NGWBMCXODKZCFX-UHFFFAOYSA-N

物化性质

• 沸点：
  508.4±35.0 °C(Predicted)
• 密度：
  1.222±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  55.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,3'-diaminotriphenylamine 在 copper(l) iodide 、 benzyltrimethylammonium tribromide 、 18-冠醚-6 、 potassium carbonate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 88.0h， 生成 4,4',4'',6,6'-pentabromo-3,3'-bis[bis(4-bromophenyl)amino]triphenylamine
  参考文献：
  名称：

  Facile Synthesis, Crystal Structures, and High-Spin Cationic States of All-para-Brominated Oligo(N-phenyl-m-aniline)s

  摘要：

  Syntheses of both the dimer (3) and the trimer (4) of all-para-brominated poly(N-phenyl-m-aniline)s (2c) were achieved in a one-pot procedure from the parent nonbrominated oligomers and benzyltrimethylammonium tribromide [(BTMA)Br-3]. An X-ray crystallographic analysis revealed that 4 has a U-shaped structure, suggesting that 2c easily adopts helical structures. Furthermore, the redox properties were investigated by the UV-vis and EPR measurements. It was confirmed that the both 3 and 4 can be oxidized into the dications 3(2+) and 4(2+) with triplet spin-multiplicity.

  DOI：

  10.1021/jo0160571
• 作为产物：
  描述：

  3,3'-dinitrotriphenylamine 在 盐酸 、 tin(ll) chloride 作用下， 以 乙腈 为溶剂， 反应 1.0h， 以89%的产率得到3,3'-diaminotriphenylamine
  参考文献：
  名称：

  Facile Synthesis, Crystal Structures, and High-Spin Cationic States of All-para-Brominated Oligo(N-phenyl-m-aniline)s

  摘要：

  Syntheses of both the dimer (3) and the trimer (4) of all-para-brominated poly(N-phenyl-m-aniline)s (2c) were achieved in a one-pot procedure from the parent nonbrominated oligomers and benzyltrimethylammonium tribromide [(BTMA)Br-3]. An X-ray crystallographic analysis revealed that 4 has a U-shaped structure, suggesting that 2c easily adopts helical structures. Furthermore, the redox properties were investigated by the UV-vis and EPR measurements. It was confirmed that the both 3 and 4 can be oxidized into the dications 3(2+) and 4(2+) with triplet spin-multiplicity.

  DOI：

  10.1021/jo0160571

文献信息

• Thin film electroluminescence device and process for production thereof
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0449125A2

  公开（公告）日：1991-10-02

  A thin film electroluminescence device and a process for production thereof. This device is characterized in that as a light emitting layer material or charge injection layer material, a polymer film having at least one of a light emitting layer function, a charge transport function and a charge injection function, and having a film thickness of not more than 0.5 µm is prepared by the vacuum evaporation method and used.

  一种薄膜电致发光装置及其生产工艺。该装置的特征在于，作为发光层材料或电荷注入层材料，使用真空蒸发法制备并使用具有发光层功能、电荷传输功能和电荷注入功能中至少一种功能且薄膜厚度不超过 0.5 µm 的聚合物薄膜。
• US5443921A
  申请人：——

  公开号：US5443921A

  公开（公告）日：1995-08-22
• US5705284A
  申请人：——

  公开号：US5705284A

  公开（公告）日：1998-01-06
• Facile Synthesis, Crystal Structures, and High-Spin Cationic States of All-<i>p</i><i>ara</i>-Brominated Oligo(<i>N</i>-phenyl-<i>m</i>-aniline)s
  作者：Akihiro Ito、Haruhiro Ino、Kazuyoshi Tanaka、Katsuichi Kanemoto、Tatsuhisa Kato

  DOI：10.1021/jo0160571

  日期：2002.1.1

  Syntheses of both the dimer (3) and the trimer (4) of all-para-brominated poly(N-phenyl-m-aniline)s (2c) were achieved in a one-pot procedure from the parent nonbrominated oligomers and benzyltrimethylammonium tribromide [(BTMA)Br-3]. An X-ray crystallographic analysis revealed that 4 has a U-shaped structure, suggesting that 2c easily adopts helical structures. Furthermore, the redox properties were investigated by the UV-vis and EPR measurements. It was confirmed that the both 3 and 4 can be oxidized into the dications 3(2+) and 4(2+) with triplet spin-multiplicity.