1-[[2,7-Bis(prop-2-enoxy)naphthalen-1-yl]methyl]-2,7-bis(prop-2-enoxy)naphthalene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-[[2,7-Bis(prop-2-enoxy)naphthalen-1-yl]methyl]-2,7-bis(prop-2-enoxy)naphthalene
• 英文别名: 1-[[2,7-bis(prop-2-enoxy)naphthalen-1-yl]methyl]-2,7-bis(prop-2-enoxy)naphthalene
• 化学式: C₃₃H₃₂O₄
• 分子量: 492.615
• InChiKey: RAHCCDVBBNDQMK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  37
• 可旋转键数：
  14
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-[[2,7-Bis(prop-2-enoxy)naphthalen-1-yl]methyl]-2,7-bis(prop-2-enoxy)naphthalene 在 platinum(IV) oxide 、 双氧水 、 potassium hydrogencarbonate 作用下， 以 甲醇 、 甲苯 、 乙腈 为溶剂， 反应 18.0h， 生成 3-[8-[[2,7-Bis(oxiran-2-ylmethoxy)naphthalen-1-yl]methyl]-7-(oxiran-2-ylmethoxy)naphthalen-2-yl]oxypropyl-triethoxysilane
  参考文献：
  名称：

  EPOXY COMPOUND HAVING ALKOXY SILYL GROUP, COMPOSITION COMPRISING SAME, CURED PRODUCT, USE THEREOF AND METHOD FOR PREPARING EPOXY COMPOUND HAVING ALKOXY SILYL GROUP

  摘要：

  公开号：

  EP2826777B1
• 作为产物：
  描述：

  2,2',7,7'-tetrahydroxydinaphthylmethane 、 3-溴丙烯 在 sodium hydroxide 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 5.0h， 以94%的产率得到1-[[2,7-Bis(prop-2-enoxy)naphthalen-1-yl]methyl]-2,7-bis(prop-2-enoxy)naphthalene
  参考文献：
  名称：

  EPOXY COMPOUND HAVING ALKOXY SILYL GROUP, COMPOSITION COMPRISING SAME, CURED PRODUCT, USE THEREOF AND METHOD FOR PREPARING EPOXY COMPOUND HAVING ALKOXY SILYL GROUP

  摘要：

  公开号：

  EP2826777B1

文献信息

• THERMOSETTING ALKOXYSILYL COMPOUND HAVING TWO OR MORE ALKOXYSILYL GROUPS, COMPOSITION AND CURED PRODUCT COMPRISING SAME, USE THEREOF, AND METHOD FOR PREPARING ALKOXYSILYL COMPOUND
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20180155370A1

  公开（公告）日：2018-06-07

  The present invention relates to: a thermosetting alkoxysilyl compound (hereinafter, referred to as “alkoxysilyl compound”)having two or more alkoxysilyl groups showing excellent heat-resistance characteristics in a composite; a composition and a cured product comprising the same; a use thereof; and a method for preparing an alkoxysilyl compound. The composition of an alkoxysilyl compound, comprising a novel alkoxysilyl compound according to the present invention shows, in a composite, improved heat-resistance characteristics, i.e., an effect of decreasing the CTE of the composition of an alkoxysilyl compound and not showing a glass transition temperature (hereinafter, referred to as “Tg-less”). Further, the cured product comprising an alkoxysilyl compound according to the present invention shows excellent flame retardant properties due to the alkoxysilyl groups.

  本发明涉及一种热固性烷氧基硅基化合物（以下简称“烷氧基硅基化合物”），其具有两个或两个以上的烷氧基硅基团，在复合材料中表现出优异的耐热特性；包括该烷氧基硅基化合物的组合物和固化产物；其用途；以及制备烷氧基硅基化合物的方法。根据本发明的一种烷氧基硅基化合物的组合物显示出改善的耐热特性，即降低烷氧基硅基化合物组合物的CTE并且不显示玻璃转变温度（以下简称“Tg-less”）的效果。此外，根据本发明的一种烷氧基硅基化合物的固化产物由于烷氧基硅基团表现出优异的阻燃性能。
• Thermosetting alkoxysilyl compound having two or more alkoxysilyl groups, composition and cured product comprising same, use thereof, and method for preparing alkoxysilyl compound
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US10428176B2

  公开（公告）日：2019-10-01

  The present invention relates to: a thermosetting alkoxysilyl compound (hereinafter, referred to as “alkoxysilyl compound”) having two or more alkoxysilyl groups showing excellent heat-resistance characteristics in a composite; a composition and a cured product comprising the same; a use thereof; and a method for preparing an alkoxysilyl compound. The composition of an alkoxysilyl compound, comprising a novel alkoxysilyl compound according to the present invention shows, in a composite, improved heat-resistance characteristics, i.e., an effect of decreasing the CTE of the composition of an alkoxysilyl compound and not showing a glass transition temperature (hereinafter, referred to as “Tg-less”). Further, the cured product comprising an alkoxysilyl compound according to the present invention shows excellent flame retardant properties due to the alkoxysilyl groups.

  本发明涉及：一种热固性烷氧基硅烷化合物（以下简称 "烷氧基硅烷化合物"），该化合物具有两个或两个以上的烷氧基硅烷基团，在复合材料中显示出优异的耐热特性；一种包含该化合物的组合物和固化产品；其用途；以及一种制备烷氧基硅烷化合物的方法。根据本发明，由新型烷氧基硅基化合物组成的烷氧基硅基化合物组合物在复合材料中显示出更好的耐热特性，即降低烷氧基硅基化合物组合物的 CTE，并且不显示玻璃化转变温度（以下称为 "无 Tg"）。此外，根据本发明，由烷氧基硅烷化合物组成的固化产品因含有烷氧基硅烷基团而具有优异的阻燃性能。
• US9902803B2
  申请人：——

  公开号：US9902803B2

  公开（公告）日：2018-02-27
• EPOXY COMPOUND HAVING ALKOXY SILYL GROUP, COMPOSITION COMPRISING SAME, CURED PRODUCT, USE THEREOF AND METHOD FOR PREPARING EPOXY COMPOUND HAVING ALKOXY SILYL GROUP
  申请人：Korea Institute of Industrial Technology

  公开号：EP2826777B1

  公开（公告）日：2020-08-05