N-(4-dibenzothiophen-2-ylphenyl)-9,9-dimethyl-N-(4-phenylphenyl)fluoren-2-amine | 1356174-87-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(4-dibenzothiophen-2-ylphenyl)-9,9-dimethyl-N-(4-phenylphenyl)fluoren-2-amine
• CAS: 1356174-87-2
• 化学式: C₄₅H₃₃NS
• 分子量: 619.83
• InChiKey: WVYHPCJLENGQNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  47
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  31.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-氨基联苯 在 palladium diacetate 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 生成 N-(4-dibenzothiophen-2-ylphenyl)-9,9-dimethyl-N-(4-phenylphenyl)fluoren-2-amine
  参考文献：
  名称：

  [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  [FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE À BASE DE CES COMPOSÉS

  摘要：

  提供了新型有机电致发光化合物和使用该化合物的有机电致发光装置。由于使用该有机电致发光化合物作为空穴传输材料或空穴注入材料的有机电致发光装置表现出良好的发光效率和优秀的寿命特性，因此用于制造具有卓越工作寿命且由于提高的功率效率而消耗更少电力的OLED设备。

  公开号：

  WO2012015265A1

文献信息

• AROMATIC AMINE DERIVATIVE AND ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US20140159006A1

  公开（公告）日：2014-06-12

  Provided are a novel aromatic amine derivative having a specific structure and an organic electroluminescence device in which an organic thin layer comprising a single layer or plural layers including a light emitting layer is interposed between a cathode and an anode, wherein at leas one layer of the above organic thin layer contains the aromatic amine derivative described above in the form of a single component or a mixed component. Thus, the organic electroluminescence device is less liable to be crystallized in molecules, improved in a yield in producing the organic electroluminescence device and extended in a lifetime.

  提供了一种具有特定结构的新型芳香胺衍生物和一种有机电致发光器件，其中在阴极和阳极之间夹有包括发光层的单层或多层有机薄层，上述有机薄层的至少一层以单一组分或混合组分的形式包含上述芳香胺衍生物。因此，该有机电致发光器件不易在分子中结晶，提高了器件的产量，并延长了寿命。
• ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE INCLUDING SAME
  申请人：Cheil Industries Inc.

  公开号：EP2940097A1

  公开（公告）日：2015-11-04

  An organic optoelectronic device and a display device including the same are disclosed, and the organic optoelectronic device includes an anode, a cathode and at least one organic layer interposed between the anode and the cathode, wherein the organic thin layer includes an emission layer, a hole transport layer, a hole injection layer, an electron transport layer, an electron injection layer, or a combination thereof, the organic thin layer includes an emission layer and a plurality of a hole transport layer, the hole transport layer contacting the emission layer of the plurality of hole transport layer includes a compound represented by a combination of the following Chemical Formula 1; Chemical Formula 2 or 3; and Chemical Formula 4, and one of the hole transport layers not contacting the emission layer includes a compound represented by the following Chemical Formula B-1.

  本发明公开了一种有机光电器件和包括该器件的显示器件，该有机光电器件包括阳极、阴极和至少一个穿插在阳极和阴极之间的有机薄层，其中有机薄层包括发射层、空穴传输层、空穴注入层、电子传输层、电子注入层或其组合，有机薄层包括发射层和多个空穴传输层，空穴传输层与多个空穴传输层中的发射层接触、电子传输层、电子注入层或它们的组合，有机薄层包括发射层和多个空穴传输层，与发射层接触的多个空穴传输层包括由以下化学式 1；化学式 2 或 3 和化学式 4 的组合，而不与发射层接触的孔传输层之一包括由以下化学式 B-1 表示的化合物。
• Aromatic amine derivative and electroluminescence device using the same
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10446761B2

  公开（公告）日：2019-10-15

  Provided are a novel aromatic amine derivative having a specific structure and an organic electroluminescence device in which an organic thin layer comprising a single layer or plural layers including a light emitting layer is interposed between a cathode and an anode, wherein at least one layer of the above organic thin layer contains the aromatic amine derivative described above in the form of a single component or a mixed component. Thus, the organic electroluminescence device is less liable to be crystallized in molecules, improved in a yield in producing the organic electroluminescence device and extended in a lifetime.

  本发明提供了一种具有特定结构的新型芳香胺衍生物和一种有机电致发光器件，其中在阴极和阳极之间插入了由单层或包括发光层的多层组成的有机薄层，上述有机薄层中至少有一层以单组分或混合组分的形式含有上述芳香胺衍生物。因此，有机电致发光器件不易在分子中结晶，提高了生产有机电致发光器件的产量，并延长了使用寿命。
• Organic compound, light-emitting element, light-emitting device, display device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10446766B2

  公开（公告）日：2019-10-15

  A novel organic compound that forms an exciplex emitting light with high efficiency is provided. An organic compound with a triarylamine skeleton in which the three aryl groups of the triarylamine skeleton are a p-biphenyl group, a fluoren-2-yl group, and a phenyl group to which a dibenzofuranyl group or a dibenzothiophenyl group is bonded. By the use of the organic compound and an organic compound with an electron-transport property, an exciplex that emits light with extremely high efficiency can be formed.

  本发明提供了一种新型有机化合物，它能形成一种高效发光的复合物。一种有机化合物具有三芳基胺骨架，其中三芳基胺骨架的三个芳基分别是对联苯基、芴-2-基和与二苯并呋喃基或二苯并噻吩基键合的苯基。通过使用该有机化合物和具有电子传输特性的有机化合物，可以形成一种发光效率极高的复合物。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20140084270A1

  公开（公告）日：2014-03-27

  An organic electroluminescence device includes an anode, a cathode, a first organic layer and an emitting layer including a luminescent material, in which the first organic layer and the emitting layer are interposed between the anode and the cathode in this sequence from the anode. The emitting layer contains a first material represented by the following formula (1-1) and a second material. The first organic layer contains a compound represented by the following formula (4).