N-phenyl-N-[4-(5-phenylthiophen-2-yl)phenyl]-4-[4-(N-[4-(5-phenylthiophen-2-yl)phenyl]anilino)phenyl]aniline | 960412-36-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-phenyl-N-[4-(5-phenylthiophen-2-yl)phenyl]-4-[4-(N-[4-(5-phenylthiophen-2-yl)phenyl]anilino)phenyl]aniline
• CAS: 960412-36-6
• 化学式: C₅₆H₄₀N₂S₂
• 分子量: 805.079
• InChiKey: PUIGAFXFSIGZHY-UHFFFAOYSA-N

物化性质

• 密度：
  1.225±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  16
• 重原子数：
  60
• 可旋转键数：
  11
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N,N'-二苯基联苯二胺 、 2-(4-溴苯基)-5-苯基噻吩 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 8.0h， 生成 N-phenyl-N-[4-(5-phenylthiophen-2-yl)phenyl]-4-[4-(N-[4-(5-phenylthiophen-2-yl)phenyl]anilino)phenyl]aniline
  参考文献：
  名称：

  AROMATIC AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME

  摘要：

  本发明提供了一种具有特定结构的新型芳香胺衍生物以及一种有机电致发光器件，其中有机薄膜层包括至少一个发光层的单层或多层，被插入在阴极和阳极之间，上述有机薄膜层中的至少一层，特别是注入孔层中含有上述芳香胺衍生物的单一成分或混合成分。使用上述芳香胺衍生物可以实现一种有机电致发光器件，降低操作电压，使分子不易结晶，并提高有机EL器件的产量，并具有长寿命。

  公开号：

  US20080108832A1

文献信息

• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2224510A1

  公开（公告）日：2010-09-01

  An organic electroluminescence device including: an anode (10), a cathode (70), an emitting layer (40) including an organic compound, which is between the anode (10) and the cathode (70), two or more layers arranged in a hole injection and transport region which is between the anode (10) and the emitting layer (40), and one or more layers arranged in an electron injection and transport region which is between the emitting layer (40) and the cathode (70), wherein a layer in the hole injection and transport region, which is in contact with the emitting layer (40), includes an aromatic amine derivative having a carbazole skeleton, one of the layers other than the layer in contact with the emitting layer (40) in the hole injection and transport region includes one or more materials selected from the group consisting of thiophene derivatives, tricyclic or more cyclic fused aromatic derivatives, amine derivatives excluding the compound represented by the following formula (A), conductive polymers, CFx, CuPc, transition metal oxides, fullerenes and acceptor materials, and a layer in the electron injection and transport region includes a benzimidazole derivative.

  一种有机电致发光装置，包括阳极（10）、阴极（70）、位于阳极（10）和阴极（70）之间的包括有机化合物的发射层（40）、位于阳极（10）和发射层（40）之间的空穴注入和传输区域中的两个或多个层、在发射层（40）和阴极（70）之间的电子注入和传输区域中布置的一层或多层，其中在空穴注入和传输区域中与发射层（40）接触的一层包括具有咔唑骨架的芳香胺衍生物、在空穴注入和传输区域中，与发射层（40）接触的层以外的层之一包括一种或多种选自以下组别的材料：噻吩衍生物、三环或多环融合芳香衍生物、胺衍生物（不包括下式（A）代表的化合物）、导电聚合物、CFx、CuPc、过渡金属氧化物、富勒烯和受体材料；在电子注入和传输区域中的层包括苯并咪唑衍生物。
• Organic electroluminescent device using aryl amine derivative containing heterocycle
  申请人：Kawamura Masahiro

  公开号：US10263192B2

  公开（公告）日：2019-04-16

  An organic electroluminescent device including: an anode, a cathode, an emitting layer formed of an organic compound and interposed between the cathode and the anode, and two or more layers provided in a hole-injecting/hole-transporting region between the anode and the emitting layer; of the layers which are provided in the hole-injecting/hole-transporting region, a layer which is in contact with the emitting layer containing a compound represented by the formula (1); and of the layers which are provided in the hole-injecting/hole-transporting region, a layer which is interposed between the anode and the layer which is in contact with the emitting layer containing an amine derivative represented by the formula (2).

  一种有机电致发光器件，包括一个阳极，一个阴极，一个由有机化合物形成并位于阴极和阳极之间的发光层，以及在阳极和发光层之间的孔注入/孔传输区域中设置的两个或两个以上的层；在孔注入/孔传输区域中设置的层中，一个与发光层接触的层含有式(1)表示的化合物；在孔注入/孔传输区域的层中，阳极和与发射层接触的层之间有一层含有式（2）表示的胺衍生物。
• Mixture, organic electroluminescence device and electronic equipment
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US11069861B2

  公开（公告）日：2021-07-20

  A mixture contains a first compound and a second compound, in which the first compound has at least one of a first cyclic structure represented by a formula (11) below and a second cyclic structure represented by a formula (12) below, and the second compound is a compound represented by a formula (21) or a compound represented by a formula (22) below, and a total mass MT of the first and second compounds and a mass M2 of the second compound in the mixture satisfy a relationship of a numerical formula (Numerical Formula 1) below,

  一种混合物含有第一种化合物和第二种化合物，其中第一种化合物具有以下式（11）表示的第一种环状结构和以下式（12）表示的第二种环状结构中的至少一种，第二种化合物是以下式（21）表示的化合物或以下式（22）表示的化合物，混合物中第一种和第二种化合物的总质量 MT 和第二种化合物的质量 M2 满足以下数值式（数值式 1）的关系、
• ORGANIC ELECTROLUMINESCENT DEVICE USING ARYL AMINE DERIVATIVE CONTAINING HETEROCYCLE
  申请人：Kawamura Masahiro

  公开号：US20080014464A1

  公开（公告）日：2008-01-17

  An organic electroluminescent device including: an anode, a cathode, an emitting layer formed of an organic compound and interposed between the cathode and the anode, and two or more layers provided in a hole-injecting/hole-transporting region between the anode and the emitting layer; of the layers which are provided in the hole-injecting/hole-transporting region, a layer which is in contact with the emitting layer containing a compound represented by the formula (1); and of the layers which are provided in the hole-injecting/hole-transporting region, a layer which is interposed between the anode and the layer which is in contact with the emitting layer containing an amine derivative represented by the formula (2).
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Jinde Yukitoshi

  公开号：US20100301312A1

  公开（公告）日：2010-12-02

  An organic electroluminescence device including: an anode ( 10 ), a cathode ( 70 ), an emitting layer ( 40 ) including an organic compound, which is between the anode ( 10 ) and the cathode ( 70 ), two or more layers arranged in a hole injection and transport region which is between the anode ( 10 ) and the emitting layer ( 40 ), and one or more layers arranged in an electron injection and transport region which is between the emitting layer ( 40 ) and the cathode ( 70 ), wherein a layer in the hole injection and transport region, which is in contact with the emitting layer ( 40 ), includes an aromatic amine derivative having a carbazole skeleton, one of the layers other than the layer in contact with the emitting layer ( 40 ) in the hole injection and transport region includes one or more materials selected from the group consisting of thiophene derivatives, tricyclic or more cyclic fused aromatic derivatives, amine derivatives excluding the compound represented by the following formula (A), conductive polymers, CF x , CuPc, transition metal oxides, fullerenes and acceptor materials, and a layer in the electron injection and transport region includes a benzimidazole derivative.