dimethyl 4,5-epoxycyclohexane-1,2-dicarboxylate | 51349-92-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: dimethyl 4,5-epoxycyclohexane-1,2-dicarboxylate
• 英文别名: 4,5-Epoxy-hexahydrophthalsaeure-dimethylester；4,5-epoxy-cyclohexane-1,2-dicarboxylic acid dimethyl ester；4,5-Epoxy-cyclohexan-1,2-dicarbonsaeure-dimethylester；Dimethyl 7-oxabicyclo[4.1.0]heptane-3,4-dicarboxylate
• CAS: 51349-92-9
• 化学式: C₁₀H₁₄O₅
• 分子量: 214.218
• InChiKey: OBOPQSIGGSCTEL-UHFFFAOYSA-N

物化性质

• 沸点：
  138-140 °C(Press: 3 Torr)
• 密度：
  1.249±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  65.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-环己烯-1-甲酸 、 dimethyl 4,5-epoxycyclohexane-1,2-dicarboxylate 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Batog, A. E.; Stepko, O. P.; Nikonova, L. P., Journal of Organic Chemistry USSR (English Translation), 1980, p. 971 - 975

  摘要：

  DOI：
• 作为产物：
  描述：

  二甲基环己-3-烯-1,6-二羧酸酯 在 过氧乙酸 作用下， 以84%的产率得到dimethyl 4,5-epoxycyclohexane-1,2-dicarboxylate
  参考文献：
  名称：

  Batog, A. E.; Stepko, O. P.; Nikonova, L. P., Journal of Organic Chemistry USSR (English Translation), 1980, p. 971 - 975

  摘要：

  DOI：

文献信息

• Transesterification process for preparation of cycloaliphatic epoxides
  申请人：UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

  公开号：EP0479166A1

  公开（公告）日：1992-04-08

  Transesterification and a particular class of catalysts, namely, one or more salts of one or more weak acids, and mixtures thereof, are used to transesterify epoxide esters and active hydrogen-containing compounds to produce a wide variety of cycloaliphatic epoxide products.

  酯交换反应和一类特殊的催化剂，即一种或多种弱酸的一种或多种盐，以及它们的混合物，可用于酯交换环氧酯和活性含氢化合物，以生产多种环脂族环氧产物。
• POLYURETHANE GEL MATERIAL, POLYURETHANE GEL, PSEUDO-BIOLOGICAL MATERIAL, AND PRODUCTION METHOD FOR POLYURETHANE GEL
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3778689A1

  公开（公告）日：2021-02-17

  A polyurethane gel material includes an aliphatic polyisocyanate (A) having an average functionality of 2.3 or more and 3.2 or less, a polyol (B) having an average functionality of 2.0 or more and 2.3 or less, and a plasticizer (C) having an ester group. The aliphatic polyisocyanate (A) contains an isocyanurate derivative of an aliphatic diisocyanate and/or an alcoholic modified isocyanurate derivative of an aliphatic diisocyanate. The polyol (B) contains a polyoxypropylene polyol and/or a polytetramethylene ether glycol. The polyol (B) has an average hydroxyl value of 73 mgKOH/g or more and 200 mgKOH/g or less. A ratio of the plasticizer (C) per 100 parts by mass of the polyol component (B) is 100 parts by mass or more and 500 parts by mass or less.

  一种聚氨酯凝胶材料包括平均官能度为 2.3 或更高和 3.2 或更低的脂肪族多异氰酸酯 (A)、平均官能度为 2.0 或更高和 2.3 或更低的多元醇 (B) 以及具有酯基的增塑剂 (C)。脂肪族多异氰酸酯（A）包含脂肪族二异氰酸酯的异氰尿酸酯衍生物和/或脂肪族二异氰酸酯的醇改性异氰尿酸酯衍生物。多元醇（B）含有聚氧丙烯多元醇和/或聚四亚甲基醚二醇。多元醇（B）的平均羟值为 73 mgKOH/g 或以上，200 mgKOH/g 或以下。增塑剂（C）与每 100 份（质量）多元醇组分（B）的比例为 100 份（质量）或以上， 500 份（质量）或以下。
• Aromatic polyamide films for solvent resistant flexible substrates
  申请人：Akron Polymer Systems, Inc.

  公开号：US10759940B2

  公开（公告）日：2020-09-01

  Films with optical transmittance of >80% between 400 and 750 nm and with coefficient of thermal expansion less than 20 ppm/° C. are prepared from aromatic polyamides that are soluble in polar organic solvents yet have glass transition temperatures >300° C. The films are cross-linked in the solid state by heating at elevated temperatures for short periods of time in the presence of multifunctional epoxides. Surprisingly, the optical and thermal properties of the films do not change significantly during the curing process. The temperature required for the crosslinking process to take place can be reduced by the presence of a few free, pendant carboxyl groups along the polyamide backbones. The films are useful as flexible substrates for electronic displays and photovoltaic devices.

  薄膜在 400 纳米到 750 纳米之间的光学透射率大于 80%，热膨胀系数小于 20 ppm/°C，由可溶于极性有机溶剂但玻璃化转变温度大于 300°C 的芳香族聚酰胺制备而成。令人惊讶的是，在固化过程中，薄膜的光学和热学特性没有发生明显变化。由于聚酰胺骨架上存在一些游离的悬垂羧基，因此可以降低交联过程所需的温度。这种薄膜可用作电子显示器和光伏设备的柔性基板。
• Thermally stable, low birefringent copolyimide films
  申请人：Sun Limin

  公开号：US11084906B2

  公开（公告）日：2021-08-10

  A class of solvent resistant, flexible copolyimide substrates having high optical transparency (>80% from 400 to 750 nm) that is retained after brief exposure to 300° C., near-zero birefringence (<0.001) and a maximum CTE of approximately 60 ppm/° C. is disclosed. The copolyimides are prepared from alicyclic dianhydrides, aromatic cardo diamines, and aromatic diamines containing free carboxyl groups. The substrates are manufactured from solutions of the copolyimides containing multifunctional epoxides in the form of single layer films, multilayer laminates and glass fiber reinforced composite films. The substrates can be used in the construction of flexible optical displays, and other microelectronic and photovoltaic devices that require their unique combination of properties.

  本发明公开了一类耐溶剂、柔性共聚亚胺基材，其光学透明度高（从 400 纳米到 750 纳米>80%），在短暂暴露于 300° C 后仍能保持，双折射近乎零（<0.001），最大 CTE 约为 60 ppm/°C。共聚亚胺是由脂环族二酐、芳香族辛二胺和含有游离羧基的芳香族二胺制备而成。基材由含有多功能环氧化物的共聚亚胺溶液制成，其形式包括单层膜、多层复合膜和玻璃纤维增强复合膜。这些基材可用于制造柔性光学显示器以及其他需要其独特组合特性的微电子和光伏设备。
• Batog, A. E.; Savenko. T. V.; Batrak, T. A., Journal of applied chemistry of the USSR, 1983, vol. 56, # 10, p. 2145 - 2149
  作者：Batog, A. E.、Savenko. T. V.、Batrak, T. A.

  DOI：——

  日期：——