2,2'-bis[(2-hydroxyphenyl)methylene]carbonimidic dihydrazide | 91379-47-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2,2'-bis[(2-hydroxyphenyl)methylene]carbonimidic dihydrazide
• 英文别名: 1,3-bis(2-hydroxyphenylmethylideneamino)guanidine；NSC69411；1,2-Bis[(2-hydroxyphenyl)methylideneamino]guanidine；1,2-bis[(2-hydroxyphenyl)methylideneamino]guanidine
• CAS: 91379-47-4
• 化学式: C₁₅H₁₅N₅O₂
• 分子量: 297.316
• InChiKey: HSTUAUQOBCWZDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  116
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-氯甲基苯并咪唑 、 2,2'-bis[(2-hydroxyphenyl)methylene]carbonimidic dihydrazide 在 三乙胺 作用下， 以 甲醇 为溶剂， 以83 %的产率得到
  参考文献：
  名称：

  聚合物负载的氮桥对称双核二氧化钼(VI)配合物及其均相类似物作为高效合成2-氨基-3-氰基-4H-色烯/吡喃的潜在催化剂

  摘要：

  聚合物负载的非均相和均相氮桥对称双核二氧化钼(VI)配合物已被合成、表征并用作生物重要的2-氨基-3-氰基-4 H-色烯/吡喃的多组分一锅合成的潜在催化剂。

  DOI：

  10.1002/chem.202400631
• 作为产物：
  描述：

  1,3-二氨基胍盐酸盐 、 水杨醛 在 氢氧化钾 作用下， 以 乙醇 为溶剂， 反应 3.0h， 以55%的产率得到2,2'-bis[(2-hydroxyphenyl)methylene]carbonimidic dihydrazide
  参考文献：
  名称：

  Physicochemical study on bis-hydrazone derived from 1,3-diaminoguanidine and salicylaldehyde and its complexes with transition metals

  摘要：

  The reaction of 1,3-diaminoguanidine with salicylaldehyde gave the corresponding bis-hydrazone, and complexes of the latter with copper(II), vanadyl(II), nickel(II), and manganese(II) of the composition LM2X (L is triply deprotonated hydrazone, X = CH3COO- or pyrazole) were synthesized. Their structure was determined on the basis of elemental analyses, IR, H-1 NMR, and UV spectra, and low-temperature magnetochemical data.

  DOI：

  10.1134/s1070363208110182

文献信息

• Polymer Supported Nitrogen‐Bridged Symmetrical Binuclear Dioxidomolybdenum(VI) Complexes and Their Homogeneous Analogues as Potential Catalysts for Efficient Synthesis of 2‐Amino‐3‐Cyano‐4<i>H</i>‐Chromenes/Pyrans
  作者：Mannar R. Maurya、Monojit Nandi、Naveen Kumar、Fernando Avecilla

  DOI：10.1002/chem.202400631

  日期：——

  Polymer supported heterogeneous as well as homogeneous nitrogen-bridged symmetrical binuclear dioxidomolybdenum(VI) complexes have been synthesised, characterised and used as potential catalysts for the multicomponent one pot synthesis of biologically important 2-amino-3-cyano-4H-chromenes/pyrans.

  聚合物负载的非均相和均相氮桥对称双核二氧化钼(VI)配合物已被合成、表征并用作生物重要的2-氨基-3-氰基-4 H-色烯/吡喃的多组分一锅合成的潜在催化剂。
• Physicochemical study on bis-hydrazone derived from 1,3-diaminoguanidine and salicylaldehyde and its complexes with transition metals
  作者：L. D. Popov、Yu. P. Tupolova、V. V. Lukov、I. N. Shcherbakov、V. A. Kogan、A. V. Mishchenko

  DOI：10.1134/s1070363208110182

  日期：2008.11

  The reaction of 1,3-diaminoguanidine with salicylaldehyde gave the corresponding bis-hydrazone, and complexes of the latter with copper(II), vanadyl(II), nickel(II), and manganese(II) of the composition LM2X (L is triply deprotonated hydrazone, X = CH3COO- or pyrazole) were synthesized. Their structure was determined on the basis of elemental analyses, IR, H-1 NMR, and UV spectra, and low-temperature magnetochemical data.