7-[(E)-2-(4-Dioctylamino-phenyl)-vinyl]-9,10-dihydro-phenanthrene-2-carbaldehyde | 357219-53-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 7-[(E)-2-(4-Dioctylamino-phenyl)-vinyl]-9,10-dihydro-phenanthrene-2-carbaldehyde
• CAS: 357219-53-5
• 化学式: C₃₉H₅₁NO
• 分子量: 549.84
• InChiKey: CGNNQYWQEHMTBJ-FOCLMDBBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.96
• 重原子数：
  41.0
• 可旋转键数：
  18.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  20.31
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2,7-Bis(diethoxyphosphorylmethyl)-9,10-dihydrophenanthrene 、 7-[(E)-2-(4-Dioctylamino-phenyl)-vinyl]-9,10-dihydro-phenanthrene-2-carbaldehyde 在 18-冠醚-6 、 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 16.0h， 以64%的产率得到4-[(E)-2-[7-[(E)-2-[7-[(E)-2-[7-[(E)-2-[4-(dioctylamino)phenyl]ethenyl]-9,10-dihydrophenanthren-2-yl]ethenyl]-9,10-dihydrophenanthren-2-yl]ethenyl]-9,10-dihydrophenanthren-2-yl]ethenyl]-N,N-dioctylaniline
  参考文献：
  名称：

  Nanoscale Push-Push Dihydrophenanthrene Derivatives as Novel Fluorophores for Two-Photon-Excited Fluorescence

  摘要：

  Outperforming fluorescein by far, elongated fluorophores (e.g. 1) give rise to large two-photon absorption cross-sections σ2 in the visible-red or NIR region and high quantum fluorescence yields Φ (see figure; GM = 10-50 cm4 s photon-1 ). This opens interesting prospects in the field of two-photon microscopy imaging of cell membranes.

  DOI：

  10.1002/1521-3773(20010601)40:11<2098::aid-anie2098>3.0.co;2-0
• 作为产物：
  描述：

  2,7-bis(bromomethyl)-9,10-dihydrophenanthrene 在 碳酸氢钠 、 二甲基亚砜 作用下， 反应 4.0h， 生成 7-[(E)-2-(4-Dioctylamino-phenyl)-vinyl]-9,10-dihydro-phenanthrene-2-carbaldehyde
  参考文献：
  名称：

  Nanoscale Push-Push Dihydrophenanthrene Derivatives as Novel Fluorophores for Two-Photon-Excited Fluorescence

  摘要：

  Outperforming fluorescein by far, elongated fluorophores (e.g. 1) give rise to large two-photon absorption cross-sections σ2 in the visible-red or NIR region and high quantum fluorescence yields Φ (see figure; GM = 10-50 cm4 s photon-1 ). This opens interesting prospects in the field of two-photon microscopy imaging of cell membranes.

  DOI：

  10.1002/1521-3773(20010601)40:11<2098::aid-anie2098>3.0.co;2-0