N,N,N-trimethyl-2-adamantylammonium iodide | 40505-99-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N-trimethyl-2-adamantylammonium iodide
• 英文别名: N,N,N-trimethyladamantane-2-aminium iodide；Trimethyl(2-adamantyl)ammonium iodide；2-adamantyl(trimethyl)azanium;iodide
• CAS: 40505-99-5
• 化学式: C₁₃H₂₄N*I
• 分子量: 321.245
• InChiKey: WDUHCXLWYLCTCI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.48
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N,N-trimethyl-2-adamantylammonium iodide 生成 2-Adamantyl(trimethyl)azanium;hydroxide
  参考文献：
  名称：

  ZONES, STACEY I.;INNES, R. A.

  摘要：

  DOI：
• 作为产物：
  描述：

  2-氨基金刚烷 、 碘甲烷 在 碳酸氢钠 作用下， 以 甲醇 为溶剂， 反应 48.0h， 以66%的产率得到N,N,N-trimethyl-2-adamantylammonium iodide
  参考文献：
  名称：

  解开葫芦 [n] urils (n = 7, 8) 和阳离子类金刚石之间的结构-亲和力关系

  摘要：

  我们报告了基于 2,6-二取代的金刚烷、4,9-二取代的金刚烷、1,6-二取代的四个系列客体的葫芦 [n]uril (n = 7, 8) 结合常数 (Ka) 的测量结果通过直接和竞争性 1H NMR 光谱测定金刚石和 1-取代的金刚烷铵离子。与CB[7]·Diam(NMe3)2的亲和力相比，金刚烷二铵离子络合物(如CB[7]·2,6-Ad(NH3)2和CB[7]·2,6-Ad(由于第二个脲基 C=O 入口处的离子-偶极相互作用，NMe3)2) 在实现亲和力潜在提高 1000 倍方面效果较差。CB[7]·Diam(NMe3)2、CB[7]·DiamNMe3 和 CB[7]·1-AdNMe3 的比较晶体学研究表明，优选的几何结构将 +NMe3 基团定位在 C=O 门户上方 ≈0.32 Å ; 观察到的 0。对CB[7]·Diam(NMe3)2 观察到的80 Å 间距反映了CH2...O=C 在

  DOI：

  10.1021/jacs.7b00056

文献信息

• Polyborate Anions Partnered with Large Nonmetal Cations: Triborate(1–), Pentaborate(1–) and Heptaborate(2–) Salts
  作者：Michael A. Beckett、Simon J. Coles、Peter N. Horton、Charlotte L. Jones

  DOI：10.1002/ejic.201700551

  日期：2017.10.25

  [C36H30NP2][B3O3(OH)4]·2.5H2O (8), 4,4′-bipiperidinium heptaborate dihydrate [C10H22N2][B7O9(OH)5]·2H2O (9). All compounds were characterized by thermal (TGA/DSC) and spectroscopic (NMR, IR) analysis. Compounds 3–5 and 9 were characterized by single-crystal XRD studies. The waters of crystallization in 3–6 and the boric acid of crystallization in 3 play important structural roles in expanding the supramolecular

  在甲醇水溶液中，由游离有机碱或[非金属阳离子] [OH]与甲醇制得了含有大量非金属阳离子的新型多硼酸盐：1-金刚烷酸五硼酸铵[C 10 H 18 N] [B 5 O 6（OH） ）4 ]（1），2-金刚烷酸五硼酸二水合物[C 10 H 18 N] [B 5 O 6（OH）4 ] · 2H 2 O（2），N，N-二甲基-1-金刚烷酸五硼酸硼酸一水合物[C 12 H 22N] [B 5 O 6（OH）4 ] · B（OH）3 · H 2 O（3），N，N，N-三甲基-1-金刚烷酸五硼酸三水合物[C 13 H 24 N] [B 5 O 6（OH）4 ] · 3H 2 O（4），N，N，N-三甲基-2-金刚烷酸五硼酸三水合物[C 13 H 24 N] [B 5 O 6（OH）4 ] · 3H 2 O（5），五硼酸二苄基铵倍半水合物[C 14 H 16 N] [B 5 O 6（OH）4 ] · 1.5H
• [EN] METHOD FOR PRODUCING OLEFIN OXIDE<br/>[FR] PROCÉDÉ DE FABRICATION D'UN OXYDE D'OLÉFINE
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2012074118A1

  公开（公告）日：2012-06-07

  Disclosed is a method for producing an olefin oxide, capable of overcoming the disadvantage of the conventional methods that hydrogen peroxide is not completely consumed and thus is left to remain, depending on the reaction conditions. To solve this problem, the method of the present invention comprises the steps of [1] reacting hydrogen peroxide with an olefin in the presence of a titanosilicate and a solvent, and [2] bringing the reaction product obtained in the previous step, into contact with a substance containing at least one element selected from the group consisting of manganese and platinum group elements.

  本发明公开了一种生产烯丙基氧化物的方法，能够克服传统方法的缺点，即根据反应条件，过氧化氢不能完全消耗，从而残留下来。为了解决这个问题，本发明的方法包括以下步骤：[1] 在钛硅酸盐和溶剂的存在下，将过氧化氢与烯烃反应，[2] 将在前一步骤中获得的反应产物与含有锰和铂族元素中至少一种元素的物质接触。
• ZONES, STACEY I.;HOLTERMANN, D. I.;INNES, R. A.;RECORARO, T. A.;ZIEMER, J+
  作者：ZONES, STACEY I.、HOLTERMANN, D. I.、INNES, R. A.、RECORARO, T. A.、ZIEMER, J+

  DOI：——

  日期：——
• METHOD OF CONTROLLING STRUCTURE OF DEFECTS IN CHABAZITE ZEOLITE MEMBRANES THROUGH LOW TEMPERATURE HEAT TREATMENT
  申请人：KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION

  公开号：US20210213393A1

  公开（公告）日：2021-07-15

  The present invention relates to a method of controlling a defect structure in a chabazite (CHA) zeolite membrane, the CHA zeolite membrane having a controlled defect structure by the method and a method of separating CO 2 , H 2 , or He and water from a mixture of water and an organic solvent using the CHA zeolite membrane, and more particularly, to a method of controlling a defect structure in a CHA zeolite membrane that improves the separation performance by reducing the amount and size of defects formed in the CHA membrane structure when removing organic-structure-directing agents in the membrane through calcination at a low temperature using ozone.
• [EN] PRODUCTION METHOD FOR TITANOSILICATE AND PRODUCTION METHOD FOR OLEFIN OXIDE<br/>[FR] PROCÉDÉ DE PRODUCTION DE TITANOSILICATE ET PROCÉDÉ DE PRODUCTION D'OXYDE D'OLÉFINE
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2012096415A1

  公开（公告）日：2012-07-19

  There are demands for a method for producing an olefin oxide, capable of further improving a production activity for an olefin oxide per weight of a titanosilicate, and a method for producing a titanosilicate usable in the method for producing the olefin oxide. The present invention provides, to meet such demands, a method for producing a titanosilicate, which comprises a first step of mixing at least one compound selected from the group consisting of cyclic amines and quaternary ammonium salts, a compound containing an element of Group 13 of the periodic table, a silicon-containing compound, a titanium-containing compound, a fluorine-containing compound and water to obtain a liquid suspension, and separating a solid component from the liquid suspension; and a second step of mixing the solid component obtained in the first step, an aqueous acid solution and a titanium-containing compound to obtain a solid-liquid mixture, and separating a solid from the solid-liquid mixture. The present invention also provides a method for producing an olefin oxide, which comprises a step of reacting an olefin with an oxidizing agent in the presence of the titanosilicate obtained in the above-described method.