2,4,6-trimethyl-N-(1-(6-(benzothiazol-2-yl)pyridin-2-yl)ethylidene)benzenamine | 1262395-56-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 2,4,6-trimethyl-N-(1-(6-(benzothiazol-2-yl)pyridin-2-yl)ethylidene)benzenamine
• 英文别名: 2,4,6-trimethyl-N-(1-(6-(benzothiazol-2-yl)pyridin-2-yl)ethylidene)benzeneamine；1-[6-(1,3-benzothiazol-2-yl)pyridin-2-yl]-N-(2,4,6-trimethylphenyl)ethanimine
• CAS: 1262395-56-1
• 化学式: C₂₃H₂₁N₃S
• 分子量: 371.506
• InChiKey: VOXWFRFIUCCPSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  66.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4,6-trimethyl-N-(1-(6-(benzothiazol-2-yl)pyridin-2-yl)ethylidene)benzenamine 、 cobalt(II) chloride 以 乙醇 为溶剂， 以82.4%的产率得到(2,4,6-trimethyl-N-(1-(6-(benzothiazol-2-yl)pyridin-2-yl)ethylidene)benzeneamine)dichlorocobalt(II)
  参考文献：
  名称：

  2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization

  摘要：

  A series of 2-(2-benzothiazolyl)-6-(1-(arylimino)ethyl)pyridines and their metal (Fe or Co) complexes were prepared. All organic compounds were fully characterized by NMR, FT-IR spectra and elemental analysis, and all metal complexes were identified by FT-IR spectroscopic and elemental analysis. The molecular structures of representative metal complexes were confirmed by single-crystal X-ray diffraction and displayed the distorted trigonal bipyramid geometry. Upon activation with modified methylaluminoxane (MMAO), the iron pro-catalysts showed good catalytic activities up to the range of 10(7) g mol(-1)(Fe) h(-1) in ethylene reactivity with the high selectivity for the vinyl-type products of both oligomers and polyethylene waxes; whereas the cobalt pro-catalysts showed moderate activities towards ethylene oligomerization. The correlations between metal complexes and their catalytic activities and products were investigated in detail under various reaction parameters and discussed. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.06.037
• 作为产物：
  描述：

  2-(2-benzothiazole)-6-acetylpyridine 、 2,4,6-三甲基苯胺 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以66%的产率得到2,4,6-trimethyl-N-(1-(6-(benzothiazol-2-yl)pyridin-2-yl)ethylidene)benzenamine
  参考文献：
  名称：

  2-β-Benzothiazolyl-6-iminopyridylmetal dichlorides and the catalytic behavior towards ethylene oligomerization and polymerization

  摘要：

  A series of 2-(2-benzothiazolyl)-6-(1-(arylimino)ethyl)pyridines and their metal (Fe or Co) complexes were prepared. All organic compounds were fully characterized by NMR, FT-IR spectra and elemental analysis, and all metal complexes were identified by FT-IR spectroscopic and elemental analysis. The molecular structures of representative metal complexes were confirmed by single-crystal X-ray diffraction and displayed the distorted trigonal bipyramid geometry. Upon activation with modified methylaluminoxane (MMAO), the iron pro-catalysts showed good catalytic activities up to the range of 10(7) g mol(-1)(Fe) h(-1) in ethylene reactivity with the high selectivity for the vinyl-type products of both oligomers and polyethylene waxes; whereas the cobalt pro-catalysts showed moderate activities towards ethylene oligomerization. The correlations between metal complexes and their catalytic activities and products were investigated in detail under various reaction parameters and discussed. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.06.037