cyclopenta-1,3-diene;N,N-dimethyl-1-[5-tri(propan-2-yloxy)silylcyclopenta-1,3-dien-1-yl]methanamine;iron(2+) | 207407-47-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: cyclopenta-1,3-diene;N,N-dimethyl-1-[5-tri(propan-2-yloxy)silylcyclopenta-1,3-dien-1-yl]methanamine;iron(2+)
• CAS: 207407-47-4
• 化学式: C₂₂H₃₇FeNO₃Si
• 分子量: 447.473
• InChiKey: MOEXWEYYWOHFMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 cyclopenta-1,3-diene;N,N-dimethyl-1-[5-tri(propan-2-yloxy)silylcyclopenta-1,3-dien-1-yl]methanamine;iron(2+) 以 正戊烷 为溶剂， 以93%的产率得到cyclopenta-1,3-diene;N,N-dimethyl-1-[5-tri(propan-2-yloxy)silylcyclopenta-1,3-dien-1-yl]methanamine;iron(2+);hydrochloride
  参考文献：
  名称：

  1,2-N,N-dimethylaminomethylferrocenyl as a ligand towards silicon

  摘要：

  The reinvestigation of reactions of [2-(dimethylaminomethyl)ferrocenyl]lithium (1), (FcN)Li, with silicontetrachloride respectively, chlorotrimethylsilane delivers new analytical data for (FcN)SiCl3 (2) and (FcN)SiMe3 (3), especially the structure of 2 has been subjected to X-ray structure analyses. The reaction of 2 with sodiumisopropylate yields the novel (FcN)Si(O-(C3H7)-C-i)(3) (4) which was subjected to X-ray diffraction analysis by its hydrochloride (FcN)Si(O-(C3H7)-C-i)(3) x HCl (5). The reaction of 1 with 1,6-dichlorododecamethylhexasilane yields the novel (FcN)(SiMe2)(6)(FcN) (6). (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00662-1
• 作为产物：
  描述：

  1-dimethylaminomethyl-2-trichlorosilylferrocene 、 sodium isopropylate 以 乙醚 为溶剂， 生成 cyclopenta-1,3-diene;N,N-dimethyl-1-[5-tri(propan-2-yloxy)silylcyclopenta-1,3-dien-1-yl]methanamine;iron(2+)
  参考文献：
  名称：

  1,2-N,N-dimethylaminomethylferrocenyl as a ligand towards silicon

  摘要：

  The reinvestigation of reactions of [2-(dimethylaminomethyl)ferrocenyl]lithium (1), (FcN)Li, with silicontetrachloride respectively, chlorotrimethylsilane delivers new analytical data for (FcN)SiCl3 (2) and (FcN)SiMe3 (3), especially the structure of 2 has been subjected to X-ray structure analyses. The reaction of 2 with sodiumisopropylate yields the novel (FcN)Si(O-(C3H7)-C-i)(3) (4) which was subjected to X-ray diffraction analysis by its hydrochloride (FcN)Si(O-(C3H7)-C-i)(3) x HCl (5). The reaction of 1 with 1,6-dichlorododecamethylhexasilane yields the novel (FcN)(SiMe2)(6)(FcN) (6). (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00662-1