[copper(II)(κ3N2O-OHC6H3OCH2NMeC2H4NMe2)(methanol)]perchlorate | 934218-86-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: [copper(II)(κ3N2O-OHC6H3OCH2NMeC2H4NMe2)(methanol)]perchlorate
• CAS: 934218-86-7
• 化学式: C₁₃H₂₃CuN₂O₃*ClO₄
• 分子量: 418.334
• InChiKey: DMUIGPAMJKUXIU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 N,N,N'-trimethyl-N'-(2,4-dihydroxyphenylmethyl)ethanediamine 、 copper(II) perchlorate 以 甲醇 为溶剂， 生成 [copper(II)(κ3N2O-OHC6H3OCH2NMeC2H4NMe2)(methanol)]perchlorate
  参考文献：
  名称：

  Copper(I) tribromide dianion as a weakly-bridging, axial ligand: Synthesis of an unusual mixed-valent Cu(II)2Cu(I) trimer

  摘要：

  Copper complexes of a new resorcinol-substituted trimethylethylenediamine ligand have been isolated and characterised. The results reveal limitations to the use chiral ligands with hydrogen bond donor groups located for intermolecular hydrogen bonding for the self-assembly of helical coordination polymers and include the X-ray crystal structure of an unusual mixed-valent Cu(II)(2)Cu(I) trimer in which CuBr32- anion acts as a bridging ligand between the two Cu(II) centres. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.05.028