N,N,N'-trimethyl-N'-(2,4-dihydroxyphenylmethyl)ethanediamine | 934218-90-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N,N,N'-trimethyl-N'-(2,4-dihydroxyphenylmethyl)ethanediamine
• 英文别名: 4-[[2-(Dimethylamino)ethyl-methylamino]methyl]benzene-1,3-diol；4-[[2-(dimethylamino)ethyl-methylamino]methyl]benzene-1,3-diol
• CAS: 934218-90-3
• 化学式: C₁₂H₂₀N₂O₂
• 分子量: 224.303
• InChiKey: ZCLPBWLGIOTZOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  46.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N,N'-trimethyl-N'-(2,4-dihydroxyphenylmethyl)ethanediamine 、 copper(ll) bromide 以 甲醇 为溶剂， 生成 dicopper(II)bis(2-O-4-OH-5-Br-C6H2-CH2NMeC2H4NMe2)(copper(I)tribromide)
  参考文献：
  名称：

  Copper(I) tribromide dianion as a weakly-bridging, axial ligand: Synthesis of an unusual mixed-valent Cu(II)2Cu(I) trimer

  摘要：

  Copper complexes of a new resorcinol-substituted trimethylethylenediamine ligand have been isolated and characterised. The results reveal limitations to the use chiral ligands with hydrogen bond donor groups located for intermolecular hydrogen bonding for the self-assembly of helical coordination polymers and include the X-ray crystal structure of an unusual mixed-valent Cu(II)(2)Cu(I) trimer in which CuBr32- anion acts as a bridging ligand between the two Cu(II) centres. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.05.028

文献信息

• Copper(I) tribromide dianion as a weakly-bridging, axial ligand: Synthesis of an unusual mixed-valent Cu(II)2Cu(I) trimer
  作者：David G. Lonnon、Donald C. Craig、Stephen B. Colbran

  DOI：10.1016/j.inoche.2006.05.028

  日期：2006.9

  Copper complexes of a new resorcinol-substituted trimethylethylenediamine ligand have been isolated and characterised. The results reveal limitations to the use chiral ligands with hydrogen bond donor groups located for intermolecular hydrogen bonding for the self-assembly of helical coordination polymers and include the X-ray crystal structure of an unusual mixed-valent Cu(II)(2)Cu(I) trimer in which CuBr32- anion acts as a bridging ligand between the two Cu(II) centres. (C) 2006 Elsevier B.V. All rights reserved.