isopropyl 2,3,4,5,6-pentabromobenzyl ether | 497107-08-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: isopropyl 2,3,4,5,6-pentabromobenzyl ether
• 英文别名: 1,2,3,4,5-Pentabromo-6-{[(propan-2-yl)oxy]methyl}benzene；1,2,3,4,5-pentabromo-6-(propan-2-yloxymethyl)benzene
• CAS: 497107-08-1
• 化学式: C₁₀H₉Br₅O
• 分子量: 544.701
• InChiKey: NNSBCOLNALHIIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  溴化2,3,4,5,6,-五溴苄酯 、 异丙醇 反应 60.0h， 以98%的产率得到isopropyl 2,3,4,5,6-pentabromobenzyl ether
  参考文献：
  名称：

  多溴芳族化合物：XI。2,3,4,5,6-五溴苄基溴化物与醇和碱金属醇盐的反应

  摘要：

  2,3,4,5,6-Pentabromobenzyl bromide reacts with primary and secondary alcohols and also with alkali metal alkoxides derived from primary alcohols to form the corresponding pentabromobenzy] ethers in high yields. In the reactions with secondary alkoxides, considerable amounts of bis(2,3,4,5,6-pentabromobenzy]) ether are formed.

  DOI：

  10.1023/a:1019667223708

文献信息

• ——
  作者：V. N. Shishkin、S. S. Vakaeva、K. P. Butin

  DOI：10.1023/a:1019667223708

  日期：——

  2,3,4,5,6-Pentabromobenzyl bromide reacts with primary and secondary alcohols and also with alkali metal alkoxides derived from primary alcohols to form the corresponding pentabromobenzy] ethers in high yields. In the reactions with secondary alkoxides, considerable amounts of bis(2,3,4,5,6-pentabromobenzy]) ether are formed.