N,N,N-trimethyldecylammonium iodide | 7447-24-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N-trimethyldecylammonium iodide
• 英文别名: decyl trimethylammonium Iodide；N-decyl-N,N,N-trimethylammonium iodide；n-decyltrimethylammonium iodide；Decyl-trimethyl-ammonium; Jodid；1-Decanaminium, N,N,N-trimethyl-, iodide；decyl(trimethyl)azanium;iodide
• CAS: 7447-24-7
• 化学式: C₁₃H₃₀N*I
• 分子量: 327.292
• InChiKey: UHUYXVHRGTYTEM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.84
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  癸-9-烯基二甲基胺 在 乙酸乙酯 、 铂 作用下， 生成 N,N,N-trimethyldecylammonium iodide
  参考文献：
  名称：

  Many-membered Carbon Rings. XX. Azacyclohendecane via Reduction of Cyclodecanone Oxime^1,2

  摘要：

  DOI：

  10.1021/ja01512a043

文献信息

• Micelle Formation in Liquid Ammonia
  作者：Joseph M. Griffin、John H. Atherton、Michael I. Page

  DOI：10.1021/acs.joc.5b00830

  日期：2015.7.17

  Perfluorinated long chain alkyl amides aggregate in liquid ammonia with increasing concentration which reflects micelle-type formation based on changes in 19F NMR chemical shifts. The critical micelle concentrations (cmc) decrease with increasing chain length and give Kleven parameters A = 0.18 and B = 0.19. The micelles catalyze the ammonolysis of esters in liquid ammonia. The corresponding perfluorinated long

  全氟化长链烷基酰胺在液氨中聚集，浓度增加，这反映了基于19 F NMR化学位移的变化而形成的胶束类型。临界胶束浓度（cmc）随着链长的增加而降低，并给出Kleven参数A = 0.18和B = 0.19。胶束催化液氨中酯的氨解。相应的全氟化长链烷基羧酸盐在液氨中形成离子对，但平衡解离常数表明除静电力外，链之间的相互作用也很有利。这些全氟化的羧酸盐在水溶液中形成胶束，并且它们的cmc产生Kleven B值＝ 0.52，而类似的烷基羧酸盐为0.30。讨论了CH 2和CF 2单元在水和液氨中的疏水性差异，以及与液氨中生命形式的可能相关性。
• Degradation kinetics and solvent effects of various long‐chain quaternary ammonium salts
  作者：Roel J. T. Kleijwegt、Wyatt Winkenwerder、Wim Baan、John van der Schaaf

  DOI：10.1002/kin.21537

  日期：2022.1

  Surfactants such as quaternary ammonium salts (QAS) have been in increasing demand, for emerging new applications. Recent attempts at process intensification of their production have disclosed the need for a better understanding of QAS thermal stability. This work aims to determine the degradation kinetics of various QASs and the associated solvent effects. The degradation kinetics of four methyl carbonate

  对于新兴的新应用，诸如季铵盐 (QAS) 之类的表面活性剂的需求不断增加。最近对其生产过程强化的尝试表明需要更好地了解 QAS 热稳定性。这项工作旨在确定各种 QAS 的降解动力学和相关的溶剂效应。在不锈钢间歇式高压釜中，在各种极性溶剂中测定了四种碳酸甲酯 QAS 的降解动力学。H NMR光谱用于反应混合物的离线分析。然后使用动力学参数来比较四种化合物在极性溶剂中的热稳定性。水没有显示出降解，甲醇 (MeOH) 是提供第二好的稳定性的溶剂。水-MeOH 混合物可提供整体最佳效果。此外，更长的长链取代基增加了降解率。热重分析用于获得固态，即无溶剂环境下的热稳定性。等转化分析表明无法确定可靠的动力学参数。尽管如此，这些数据确实允许对 14 种不同 QAS 的热稳定性进行比较。此外，
• Method for the formation of silica film, silica film, insulating film, and semiconductor device
  申请人：JSR Corporation

  公开号：EP1267395A2

  公开（公告）日：2002-12-18

  A method for the formation of a silica film which comprises treating a film in a supercritical medium, the film comprising (A) a siloxane compound and (B) at least one member selected from the group consisting of (B-1) a compound compatible with or dispersible in ingredient (A) and having a boiling or decomposition temperature of from 150 to 500°C and (B-2) a surfactant. The silica film has excellent mechanical strength showing a dielectric constant of generally 2.2 or lower, and hence is useful as a dielectric film in semiconductor devices and the like.

  一种形成二氧化硅薄膜的方法，包括在超临界介质中处理薄膜，该薄膜包括(A)硅氧烷化合物和(B)至少一种选自以下组别的成员：(B-1)与成分(A)相容或可分散在成分(A)中且沸腾或分解温度为 150 至 500°C 的化合物和(B-2)表面活性剂。二氧化硅薄膜具有优异的机械强度，介电常数一般为 2.2 或更低，因此可用作半导体设备等的介电薄膜。
• US6787193B2
  申请人：——

  公开号：US6787193B2

  公开（公告）日：2004-09-07
• [EN] THERMOSETING POLYVINYL ALCOHOLIC BINDER RESIN COMPOSITION, SLURRY OF ELECTRODE MIX, ELECTRODE, NON-AQUEOUS ELECTROLYSIS SOLITION-CONTAINING SECONDARY BATTERY AND THERMOSETTING POLYVINYL ALCOHOLIC BINDER RESIN AS ELECTRODE MATERIAL<br/>[FR] COMPOSITION DE RESINE LIANTE THERMODURCISSABLE D'ALCOOL POLYVINYLIQUE, SUSPENSION EPAISSE DE MELANGE POUR ELECTRODE, ELECTRODE, BATTERIE SECONDAIRE A SOLUTION D'ELECTROLYSE NON AQUEUSE, ET RESINE LIANTE THERMODURCISSABLE D'ALCOOL POLYVINYLIQUE TENANT LIEU DE MATERIAU POUR ELECTRODE
  申请人：HITACHI CHEMICAL CO LTD

  公开号：WO2003018687A2

  公开（公告）日：2003-03-06

  The invention provides a thermosetting binder resin composition comprising: (A) a thermosetting polyvinyl alcoholic binder resin, (B) an acrylic resin plasticizer and (C) a solvent; a thermosetting binder resin composition comprising a thermosetting polyvinyl alcoholic binder resin having thermosetting units represented by the following general formula (III) and a solvent; a slurry of an electrode mix containing the binder resin composition; and an electrode and non-aqueous electrolysis solution-containing secondary battery using the same: (III) wherein one of R3 and R4 represents a hydrogen atom and the other represents an alkenyl group.