癸-9-烯基二甲基胺 | 27397-10-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 癸-9-烯基二甲基胺
• 英文名称: N,N-dimethyl-9-decenamine
• 英文别名: N,N-dimethyl-10-amino-1-decene；10-Dimethylaminodecen；dec-9-enyl-dimethyl-amine；10-Dimethylamino-decen-(1)；N,N-dimethyldec-9-en-1-amine
• CAS: 27397-10-0
• 化学式: C₁₂H₂₅N
• mdl: MFCD00837311
• 分子量: 183.337
• InChiKey: NOGJTIYPIIDDAP-UHFFFAOYSA-N

物化性质

• 沸点：
  138-139 °C(Press: 50 Torr)
• 密度：
  0.800±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.833
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  癸-9-烯基二甲基胺 在 乙酸乙酯 、 铂 作用下， 生成 癸叔胺
  参考文献：
  名称：

  Many-membered Carbon Rings. XX. Azacyclohendecane via Reduction of Cyclodecanone Oxime^1,2

  摘要：

  DOI：

  10.1021/ja01512a043
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 生成 癸-9-烯基二甲基胺
  参考文献：
  名称：

  Many-membered Carbon Rings. XX. Azacyclohendecane via Reduction of Cyclodecanone Oxime^1,2

  摘要：

  DOI：

  10.1021/ja01512a043

文献信息

• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition contaning the copolymer, and uses thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1186619A2

  公开（公告）日：2002-03-13

  The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an α-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

  本发明旨在提供一种对金属或极性树脂具有极佳粘附性和相容性的含极性基团的烯烃共聚物、制备该共聚物的工艺、含有该共聚物的热塑性树脂组合物及其用途。含极性基团的烯烃共聚物包括一个由 2 至 20 个碳原子的 α-烯烃衍生的组成单元和一个由直链、支链或环状含极性基团单体衍生的组成单元，直链、支链或环状含极性基团单体的末端具有极性基团，如羟基或环氧基，和/或一个由大单体衍生的组成单元，大单体的末端具有通过阴离子聚合、开环聚合或缩聚反应获得的聚合物段。含极性基团的烯烃共聚物可通过在茂金属催化剂存在下使α-烯烃与含极性基团的单体和/或大单体聚合来制备。含极性基团的烯烃共聚物和含有该共聚物的热塑性树脂组合物可用于薄膜、板材、改性剂、建筑/土木工程材料、汽车外饰、电气/电子零件、涂层基料、相容剂等。
• Aqueous hard surface cleaners based on terpenes and fatty acid derivatives
  申请人：STEPAN COMPANY

  公开号：US10233412B2

  公开（公告）日：2019-03-19

  Aqueous hard surface cleaner compositions useful for removing permanent ink are disclosed. The compositions comprise 75 to 99 wt. % of water; 0.1 to 5 wt. % of a monoterpene; 0.1 to 5 wt. % of a C10-C17 fatty acid derivative; and 0.1 to 5 wt. % of one or more surfactants. The fatty acid derivative is selected from N,N-dialkyl amides, N,N-dialkyl esteramines, and N,N-dialkyl amidoamines. Preferably, a base such as sodium carbonate or monoethanolamine is also included. The invention includes concentrates comprising the non-aqueous components recited above, as well as other applications for the cleaners and concentrates such as graffiti removers and permanent ink erasers. The combination of a monoterpene and certain fatty acid derivatives, especially fatty N,N-dialkyl amides, unexpectedly enables even dilute aqueous compositions to rapidly decolorize black permanent marker from hard, non-porous surfaces.

  本发明公开了可用于去除永久性墨水的水性硬表面清洁剂组合物。该组合物包括 75 至 99 重量百分比的水；0.1 至 5 重量百分比的单萜；0.1 至 5 重量百分比的 C10-C17 脂肪酸衍生物；以及 0.1 至 5 重量百分比的一种或多种表面活性剂。脂肪酸衍生物选自 N,N-二烷基酰胺、N,N-二烷基酯胺和 N,N-二烷基氨基胺。最好还包括碱，如碳酸钠或单乙醇胺。本发明包括由上述非水性成分组成的浓缩物，以及清洁剂和浓缩物的其他应用，如涂鸦清除剂和永久性墨水擦除剂。单萜烯和某些脂肪酸衍生物，特别是脂肪 N,N-二烷基酰胺的组合，出人意料地使稀释的水性组合物也能迅速使黑色永久性记号笔从坚硬的无孔表面脱色。
• Synergistic surfactant blends
  申请人：STEPAN COMPANY

  公开号：US10982174B2

  公开（公告）日：2021-04-20

  Synergistic surfactant blends are disclosed. In one aspect, the blend comprises an anionic surfactant and a metathesis-based cationic surfactant comprising a quaternized derivative. The quaternized derivative is a quaternized fatty amine, quaternized fatty amidoamine, imidazoline quat, or esteramine quat made from a metathesis-derived C10-C17 monounsaturated acid or its ester derivative. Also disclosed are synergistic surfactant blends comprising a cationic surfactant and a metathesis-based anionic surfactant comprising a sulfonated derivative. The sulfonated derivative is a fatty ester sulfonate, fatty acid sulfonate, sulfoestolide, fatty amide sulfonate, sulfonated fatty ester alkoxylate, imidazoline quat sulfonate, sulfonated amidoamine oxide, or sulfonated amidoamine betaine. The synergistic blends have a negative β value or a reduced interfacial tension (IFT) when compared with an expected IFT value calculated from the individual surfactant components. Blends of the invention also exhibit surprisingly favorable solubility profiles. The surfactant blends are useful for laundry detergents, dish detergents, household or industrial cleaners, personal care products, agricultural products, building materials, oil recovery compositions, emulsion polymers, and other practical applications.

  本发明公开了增效表面活性剂混合物。在一个方面，混合物包括阴离子表面活性剂和由季化合物衍生物组成的元化合物阳离子表面活性剂。季铵化衍生物是一种季铵化脂肪胺、季铵化脂肪氨基胺、咪唑啉季铵或酯胺季铵，由元合成衍生的 C10-C17 单不饱和酸或其酯衍生物制成。还公开了协同表面活性剂混合物，包括阳离子表面活性剂和由磺化衍生物组成的偏合成阴离子表面活性剂。磺化衍生物是脂肪酯磺酸盐、脂肪酸磺酸盐、磺内酯、脂肪酰胺磺酸盐、磺化脂肪酯烷氧基化物、咪唑啉季磺酸盐、磺化氨基胺氧化物或磺化氨基胺甜菜碱。与根据单个表面活性剂成分计算出的预期界面张力（IFT）值相比，增效混合物的 β 值为负值或界面张力（IFT）降低。本发明的混合物还表现出令人惊讶的良好溶解度曲线。这种表面活性剂混合物可用于洗衣粉、餐具洗涤剂、家用或工业清洁剂、个人护理产品、农用产品、建筑材料、采油组合物、乳液聚合物和其他实际应用。
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof
  申请人：——

  公开号：US20020156207A1

  公开（公告）日：2002-10-24

  The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an &agr;-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the &agr;-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

  本发明旨在提供一种对金属或极性树脂具有极佳粘附性能和极佳相容性的含极性基团的烯烃共聚物、制备该共聚物的工艺、含有该共聚物的热塑性树脂组合物及其用途。含极性基团的烯烃共聚物包括一个由 2 至 20 个碳原子的&agr;-烯烃衍生的组成单元，以及一个由直链、支链或环状含极性基团单体衍生的组成单元，该单体末端具有极性基团，如羟基或环氧基，和/或一个由大单体衍生的组成单元，该大单体末端具有通过阴离子聚合、开环聚合或缩聚反应获得的聚合物段。含极性基团的烯烃共聚物可通过在茂金属催化剂存在下，将&agr;-烯烃与含极性基团的单体和/或大单体进行聚合来制备。含极性基团的烯烃共聚物和含有该共聚物的热塑性树脂组合物可用于薄膜、板材、改性剂、建筑/土木工程材料、汽车外饰、电气/电子零件、涂层基料、相容剂等。
• Structural and mechanistic effects on the rates of ring-opening reactions in the 5-16-membered-ring region
  作者：Giorgio Cerichelli、Gabriello Illuminati、Claudio Lillocci

  DOI：10.1021/jo01308a002

  日期：1980.9