2-tris[bis(trimethylsilyl)methyl]phenyl-2-(2,4,6-triisopropylphenyl)-4-phenylimino-1,3,2-dithiastannetane | 147424-56-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-tris[bis(trimethylsilyl)methyl]phenyl-2-(2,4,6-triisopropylphenyl)-4-phenylimino-1,3,2-dithiastannetane
• 英文别名: 2-(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)-2-(2,4,6-triisopropylphenyl)-4-(phenylimino)-1,3,2-dithiastannetane；N-phenyl-2-[2,4,6-tri(propan-2-yl)phenyl]-2-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-1,3,2-dithiastannetan-4-imine
• CAS: 147424-56-4
• 化学式: C₄₉H₈₇NS₂Si₆Sn
• 分子量: 1041.59
• InChiKey: KCJLXWDWHOVAMA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  16.3
• 重原子数：
  59
• 可旋转键数：
  15
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  63
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-triisopropylphenyl)SnS 、 硫代异氰酸苯酯 以17%的产率得到2-tris[bis(trimethylsilyl)methyl]phenyl-2-(2,4,6-triisopropylphenyl)-4-phenylimino-1,3,2-dithiastannetane
  参考文献：
  名称：

  Okazaki, Renji; Tokitoh, Norihiro; Ishii, Akihiko, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 67, # 1-4, p. 49 - 66

  摘要：

  DOI：

文献信息

• Synthesis and Reactions of a Stannanethione Derived from a Kinetically Stabilized Diarylstannylene
  作者：Masaichi Saito、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1021/om960449u

  日期：1996.10.15

  Stannanethione Tbt(Tip)SnS (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Tip = 2,4,6-triisopropylphenyl), containing a novel tin−sulfur double bond, was synthesized by the reactions of the corresponding kinetically stabilized diarylstannylene Tbt(Tip)Sn:  with styrene episulfide or elemental sulfur. An absorption maximum due to the n−π* transition of the tin−sulfur double bond appeared at 473

  锡烷锡酮Tbt（Tip）Sn S（Tbt = 2,4,6-三[双（三甲基甲硅烷基）甲基]苯基; Tip = 2,4,6-三异丙基苯基）通过新的方法合成动力学稳定的二芳基亚锡基Tbt（Tip）Sn：与苯乙烯环硫或元素硫的化学反应。在己烷中，由于锡-硫双键的n-π*跃迁而引起的最大吸收出现在473 nm处。它与诸如二硫化碳和异硫氰酸苯酯之类的硫代枯烯反应，并与氧化苯乙烯和均三甲苯氧化物反应，得到相应的环加合物。通过X-射线结构分析确定了锡萘那酮与二硫化碳的[2 + 2]环加合物的结构。与Tbt（Tip）Sn S相比，受阻较弱的锡烷内酯Tbt（Mes）SnS（Mes =均三甲苯基）在室温下二聚，得到相应的1,3,2,4-二硫代二金刚烷。
• Tokitoh, Norihiro; Saito, Masaichi; Okazaki, Renji, Journal of the American Chemical Society, 1993, vol. 115, p. 2065 - 2066
  作者：Tokitoh, Norihiro、Saito, Masaichi、Okazaki, Renji

  DOI：——

  日期：——
• Synthesis and reactions of stanneneselone
  作者：Masaichi Saito、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1016/0022-328x(95)00334-m

  日期：1995.9

  Stannaneselone Tbt(Tip)Sn=Se (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phe Tip = 2,4,6-triisopropylphenyl), a novel compound containing a tin-selenium double bond was synthesized by the reaction of the corresponding stannylene Tbt(Tip)Sn with elemental selenium. It reacted with phenyl isothiocyanate, mesitonitrile oxide and styrene oxide to afford cycloadducts. In the reaction with phenyl isothiocyanate, 1,3,2-dithia- and diselenastannetanes were obtained instead of the expected 1,3,2-thiaselenastannetane. Another approach to the stannaneselone by deselenation of the corresponding 1,2,3,4,5-tetraselenastannolane with triphenylphosphine is also described.
• Okazaki, Renji; Matsuhashi, Yasusuke; Matsumoto, Tsuyoshi, Phosphorus, Sulfur and Silicon and the Related Elements, 1993, vol. 74, # 1-4, p. 397 - 398
  作者：Okazaki, Renji、Matsuhashi, Yasusuke、Matsumoto, Tsuyoshi、Saito, Masaichi、Manmaru, Kyoko、Tokitoh, Norihiro

  DOI：——

  日期：——