trans-[PtCl2(As(n-C4H9)3)2] | 21481-30-1

• 分子结构分类: 有机化合物 - 有机金属化合物
• 英文名称: trans-[PtCl2(As(n-C4H9)3)2]
• 英文别名: {Pt<(As(C4H9)3)2>Cl2}；Dichloroplatinum;tributylarsane
• CAS: 21481-30-1；141317-03-5
• 化学式: C₂₄H₅₄As₂Cl₂Pt
• 分子量: 758.522
• InChiKey: QQDIGAMGGKFJLM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  11.14
• 重原子数：
  29.0
• 可旋转键数：
  20.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  trans-[PtCl2(As(n-C4H9)3)2] 、 1,3,5-三乙炔苯 在 copper(l) iodide 作用下， 以 二乙胺 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Khan, M. S.; Schwartz, D. J.; Pasha, N. A., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 三丁基砷 以 水 为溶剂， 生成 trans-[PtCl2(As(n-C4H9)3)2]
  参考文献：
  名称：

  Jensen, K. A., Zeitschrift fur anorganische Chemie, 1936, vol. 229, p. 225 - 251

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pt: MVol.D, 161, page 354 - 356
  作者：

  DOI：——

  日期：——
• Synthesis of monomeric, oligomeric and polymeric σ-acetylide complexes of platinum, palladium, nickel and rhodium
  作者：Muhammad S. Khan、Simon J. Davies、Ashok K. Kakkar、David Schwartz、Bing Lin、Brian F.G. Johnson、Jack Lewis

  DOI：10.1016/0022-328x(92)85011-k

  日期：1992.2

  Reaction of equimolar quantities of Me3SnC = CRC = CSnMe3 [R = p-C6H4; p-C6H2(CH3)2; p-C6H4-p-C6H4] with the group 10 metal dihalide complexes, [M(XnBu3)2Cl2] (M = Pt, Pd, Ni; X = P, As; Bu = butyl) affords the polymeric species trans-[-M(XnBu3)2(-C = CRC = C -)]n in excellent yields. By varying the stoichiometry of these reactions, complexes of the type trans-[M(XnBu3)2(-C = CRC = CSnMe3)2] and trans-[ClM(XnBu3)2 C = CRC = CM(XnBu3)2Cl], which are precursors to higher oligomers, can be prepared. Treatment of the former with an excess of trans-[M(XnBu3)2Cl2] affords the trimetallic compound trans-[ClM(XnBu3)2(-C = CRC = C-)M(XnBu3)2(-C = CRC = C-)M(XnBu3)2-Cl], while reaction of the latter with two equivalents of Me3SnC = CRC = CSnMe3 followed by two equivalents of trans-[M(XnBu3)2Cl2] gives the complex trans-[ClM(XnBu3)2(-C = CRC = C-)M-(XnBu3)2(-C = CRC = C-)M(XnBu3)2(-C = CRC = C-)M(XnBu3)2Cl]. Treatment of the complex [Rh(PPh3)3Cl] (Ph = Phenyl) with one equivalent of Me3SnC = CRC = CSnMe3 [R = p-C6H4-p-C6H4] gives the polymeric species [-Rh(PPh3)2(SnMe3)(-C = CRC = C-)]n. Model compounds for other rhodium-containing sigma-acetylide complexes have been obtained from the reaction between the complex [Rh(PMe3)4Cl] (Me = CH3) and Me3SnC = CC6H5, which yields the compound mer,trans-[Rh(PMe3)3-(SnMe3)(-C = CC6H5)2] via the intermediate [Rh(PMe3)4(-C = CC6H5)]. Reaction of [Rh(PMe3)4Cl] with one equivalent of Me3SnC = CRC = CSnMe3 [R = p-C6H4-p-C6H4] yields the polymer mer,trans-[-Rh(PMe3)3(SnMe3)(-C = CRC = C-)]n.
• Synthesis, Electrochemistry, and Spectroscopy of Blue Platinum(II) Polyynes and Diynes
  作者：Muhammed Younus、Anna Köhler、Stephane Cron、Nazia Chawdhury、Muna R. A. Al-Mandhary、Muhammad S. Khan、Jack Lewis、Nicholas J. Long、Richard H. Friend、Paul R. Raithby

  DOI：10.1002/(sici)1521-3773(19981116)37:21<3036::aid-anie3036>3.0.co;2-r

  日期：1998.11.16

  The smallest band gap observed so far (1.77 eV) for an organometallic polymer is exhibited by the blue, rigid-rod polymer 2, which is prepared by the reaction of trans-[PtCl2 (PnBu3 )2 ] with one equivalent of 1.