n-butyllithium-diaminobicyclo[2.2.2]octane | 859046-48-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: n-butyllithium-diaminobicyclo[2.2.2]octane
• CAS: 859046-48-3
• 化学式: C₄H₉Li*C₆H₁₂N₂
• 分子量: 176.231
• InChiKey: YTIZRCGGTMXGPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.99
• 重原子数：
  13.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  dimethyl sulfide borane 、 n-butyllithium-diaminobicyclo[2.2.2]octane 生成 Lithium-tetra-n-butylboranat
  参考文献：
  名称：

  BIFFAR W.;NOETH H.;SEDLAK D., ORGANOMETALLICS, 1983, 2, NO 5, 579-585

  摘要：

  DOI：

文献信息

• Nematicidal pyrazoles
  申请人：——

  公开号：US20030028034A1

  公开（公告）日：2003-02-06

  Novel pyrazoles of formula (I) wherein R 1 represents halogen, C 1-6 alkyl, C 1-5 haloalkyl, C 2-6 alkoxy, C 1-4 alkylthio, C 2-5 alkenyloxy, C 3-5 alkynyloxy, C 2-6 (total carbon number) alkoxyalkyl, C 2-6 (total carbon number) alkylthioalkyl, C 1-5 haloalkoxy, C 2-6 (total carbon number) alkoxyalkoxy, hydroxy or optionally substituted phenyl, R 2 represents hydrogen, halogen, C 1-5 alkyl, C 2-6 (total carbon number) alkoxyalkyl, C 2-6 (total carbon number) alkylthioalkyl, C 2-6 (total carbon number) alkylsulfinylalkyl, C 2-6 (total carbon number) alkylsulfonylalkyl or C 1-5 haloalkyl, R 3 represents hydrogen, C 1-5 alkyl, —COR 4 , COOR 5 , CH(OR 6 ) 2 or CH 2 (Si(R 7 ) 3 , R 4 represents C 1-10 alkyl, C 1-6 haloalkyl, C 2-6 alkenyl, optionally substituted C 3-6 cycloalkyl, C 2-6 (total carbon number) alkoxyalkyl, C 2-6 (total carbon number) alkylthioalkyl, optionally substituted phenyl, C 1-6 haloalkyl, alkylamino, di-(C 1-6 alkyl)amino or optionally substituted phenylamino, R 5 represents C 1-7 alkyl, R 6 and R 7 represent C 1-6 alkyl, and n is 1, 2 or 3, and when n is 2 or 3, the corresponding number (n) of R 1 radicals may be the same or different, processes for preparing these compounds and their use as nematicides and anthelmintics.

  式（I）的新型吡唑类化合物，其中R1代表卤素、C1-6烷基、C1-5卤代烷基、C2-6烷氧基、C1-4烷基硫醚、C2-5烯基氧基、C3-5炔基氧基、C2-6（总碳数）烷氧基烷基、C2-6（总碳数）烷基硫醚烷基、C1-5卤代烷氧基、C2-6（总碳数）烷氧基烷氧基、羟基或可选取代的苯基；R2代表氢、卤素、C1-5烷基、C2-6（总碳数）烷氧基烷基、C2-6（总碳数）烷基硫醚烷基、C2-6（总碳数）烷基亚磺酰基烷基、C2-6（总碳数）烷基磺酰基烷基或C1-5卤代烷基；R3代表氢、C1-5烷基、—COR4、COOR5、CH（OR6）2或CH2（Si（R7）3、R4代表C1-10烷基、C1-6卤代烷基、C2-6烯基、可选取代的C3-6环烷基、C2-6（总碳数）烷氧基烷基、C2-6（总碳数）烷基硫醚烷基、可选取代的苯基、C1-6卤代烷基、烷基氨基、二（C1-6烷基）氨基或可选取代的苯基氨基；R5代表C1-7烷基；R6和R7代表C1-6烷基；n为1、2或3，当n为2或3时，相应数量（n）的R1基团可以相同或不同，制备这些化合物的方法以及它们作为杀线虫剂和驱虫剂的用途。
• Pyrimidinyloxy/triazinyloxy alkanol derivatives and their use as herbicides
  申请人：NIHON BAYER AGROCHEM K.K.

  公开号：EP0611759A1

  公开（公告）日：1994-08-24

  The invention relates to novel pyrimidinyloxy/triazinyloxy alkanol derivatives of the formula (I) wherein R₁, R₂, R₃, R₄ and A have the meanings as described in the specification, and processes for their preparation and to their use as herbicides, as well as to novel intermediates for their preparation and to processes for their preparation.

  本发明涉及一种新型嘧啶氧基/三嗪氧基烷基衍生物，其化学式为（I），其中R₁，R₂，R₃，R₄和A的意义如说明书中所述，以及它们的制备方法和用作除草剂的用途，还涉及用于它们制备的新型中间体和制备它们的方法。
• Pyrimidinylthioalkane herbicides
  申请人：NIHON BAYER AGROCHEM K.K.

  公开号：EP0593998A1

  公开（公告）日：1994-04-27

  Novel pyrimidinylthioalkane derivatives of the formula (I) wherein R¹, R², R³ and R⁴ have the meanings as defined in the specification and the use of the new compounds as herbicides.

  式 (I) 的新型嘧啶硫代烷烃衍生物 其中 R¹、R²、R³ 和 R⁴ 的含义如说明书和新化合物作为除草剂的用途中所定义。
• Pyrimidine derivatives
  申请人：NIHON BAYER AGROCHEM K.K.

  公开号：EP0630890A2

  公开（公告）日：1994-12-28

  [Object]    Novel cyano-containing pyrimidine derivatives, processes for the production thereof, and use thereof as herbicidal agents. [Composition of the Invention]    Cyano-containing pyrimidine derivatives represented by the general formula: wherein X represents oxygen atom or sulfur atom, R¹ represents halogen atom, C₁₋₄ alkyl, C₁₋₄ alkoxy, halogeno-C₁₋₄ alkyl or halogeno-C₁₋₄ alkoxy, R² represents halogen atom, C₁₋₄ alkoxy, halogeno-C₁₋₄ alkyl or halogeno-C₁₋₄ alkoxy, R³ represents C₁₋₄ alkyl or C₃₋₇ cycloalkyl substitutable with C₁₋₄ alkyl, and R⁴ represents hydroxy, amino or oxo group, as well as the use thereof as herbicidal agents. [Effect]    The compounds according to the present invention exhibit an excellent herbicidal activity.

  对象 新型含氰基嘧啶衍生物、其生产工艺及其作为除草剂的用途。 [发明内容］ 由通式表示的含氰嘧啶衍生物： 其中 X 代表氧原子或硫原子、 R¹ 代表卤素原子、C₁₋₄ 烷基、C₁₋₄ 烷氧基、卤素-C₁₋₄ 烷基或卤素-C₁₋₄ 烷氧基、 R² 代表卤素原子、C₁₋₄烷氧基、卤代-C₁₋₄烷基或卤代-C₁₋₄烷氧基、 R³ 代表 C₁₋₄ 烷基或可被 C₁₋₄ 烷基取代的 C₃₋₇ 环烷基，以及 R⁴ 代表羟基、氨基或氧代基团、 以及将其用作除草剂。 效果 本发明的化合物具有优异的除草活性。
• 1-pyridyltetrazolinone derivatives
  申请人：NIHON BAYER AGROCHEM K.K.

  公开号：EP0692482A2

  公开（公告）日：1996-01-17

  Summary of the invention Novel tetrazolinone derivatives of the formula: wherein    R¹ represents alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl which may be substituted,    R² represents alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl which may be substituted,    R¹ and R² may form, together with the nitrogen atom to which R¹ and R² are bonded, a 5- or 6-membered heterocyclic ring, said heterocyclic ring may be benzofused and may be substituted by one or more C₁₋₄ alkyl,    R³ represents nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or phenoxy, and    n represents an integer of 0, 1, 2 or 3, and when n represents 2 or 3, then R³ may be same or different, and their use as herbicides.

  发明概述 式中的新型四唑啉酮衍生物： 其中 R¹ 代表可被取代的烷基、卤代烷基、环烷基、烯基、卤代烯基、炔基或苯基、 R² 代表可被取代的烷基、卤代烷基、环烷基、烯基、卤代烯基、炔基或苯基、 R¹ 和 R² 可与 R¹ 和 R² 键合的氮原子一起形成 5 或 6 元杂环，所述杂环可为苯并杂环，并可被一个或多个 C₁₋₄烷基取代、 R³ 代表硝基、卤素、烷基、卤代烷基、烷氧基、卤代烷氧基、烷硫基或苯氧基、 和 n 代表 0、1、2 或 3 的整数，当 n 代表 2 或 3 时，R³ 可以相同或不同、 以及它们作为除草剂的用途。