bis[3-(N,N-dimethylamino)propyl]diselenide | 45139-29-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis[3-(N,N-dimethylamino)propyl]diselenide
• 英文别名: Bis-<3-dimethylamino-propyl>-diselenid；Di(3-dimethylaminopropyl)-diselenid；3-[3-(dimethylamino)propyldiselanyl]-N,N-dimethylpropan-1-amine
• CAS: 45139-29-5
• 化学式: C₁₀H₂₄N₂Se₂
• 分子量: 330.234
• InChiKey: YVFLXERXNSPMQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.05
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis[3-(N,N-dimethylamino)propyl]diselenide 以 甲醇 、 丙酮 、 甲苯 为溶剂， 生成 [Pd(OAc)(SeCH2CH2CH2NMe2)]2*H2O
  参考文献：
  名称：

  3-Dimethylaminopropyl chalcogenolate complexes of palladium(II): Syntheses and characterization, including the crystal structures of [Pd(OAc)(ECH2CH2CH2NMe2)]2·H2O (E=S, Se) and [PdCl(TeCH2CH2CH2NMe2)]2

  摘要：

  The reactions of the sodium salts of 3-dimethylamino-l-propylchalcogenolates, prepared by sodium borohydride reduction of (Me2NCH2CH2CH2E)(2) in methanol, with Na2PdCl4 yielded homoleptic [Pd(ECH2CH2CH2NMe2)(2)](6) (1) (E=S (1a); Se (1b); Te (1c)). When treated with [Pd(OAc)(2)](3) or Na2PdCl4, compounds 1 readily gave binuclear redistribution products [PdX(ECH2CH2CH2NMe2))(2) where X = OAc (2) (E = S (2a); Se (2b); or Cl (3)) (E = S (3a); Se (3b); Te (3c)), respectively. The terminal acetate/chloride ligands in 2b/3b can be substituted by other ionic ligands like PhSe-. The complexes were characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy. The structures of 2a, 2b and 3c were established by X-ray crystallography. Each molecule has a dimeric structure in which there are two chalcogenolate bridges from the chelating 3-dimethylamino-l-propylchalcogenolate ligands. On pyrolysis, compound 2b affords Pd17Se15. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.019

文献信息

• Synthesis and characterization of 3-dimethylaminopropyl selenolate complexes of palladium(II) and platinum(II)
  作者：Sandip Dey、Vimal K Jain、Axel Knoedler、Wolfgang Kaim

  DOI：10.1016/s0020-1693(03)00080-x

  日期：2003.6

  complexes of palladium and platinum of the formulae [M(SeCH2CH2CH2NMe2)Cl]2, [M(SeCH2CH2CH2NMe2)2] (M=Pd or Pt), [Pd(OAc)(SeCH2CH2CH2NMe2)], [PtCl(SeCH2CH2CH2NMe2)(PR3)]2 (PR3=PMePh2 or PPr3), [Pt(SeCH2CH2CH2NMe2)2(PP)] (PP=dppm, dppe or 2PPh3) have been synthesized by using either the diselenide or its reduction product from the reaction with NaBH4. All complexes have been characterized by elemental

  摘要Na2Se2与Me2NCH2CH2CH2Cl反应制得双（3-二甲基氨基丙基）二硒化物。式[M（SeCH2CH2CH2NMe2）Cl] 2，[M（SeCH2CH2CH2NMe2）2]（M = Pd或Pt），[Pd（OAc）（SeCH2CH2CH2NMe2）]，[PtCl（SeCH2CH2） （PR3）] 2（PR3 = PMePh2或PPr3），[Pt（SeCH2CH2CH2NMe2）2（PP）]（PP= dppm，dppe或2PPh3）已通过使用与NaBH4反应。所有配合物均已通过元素分析，IR和NMR（1H，13C，31P，77Se，195Pt）光谱进行了表征。这些配合物的立体化学已经从NMR光谱数据中推导出来。通过单晶X射线衍射分析确定了[Pd（SeCH2CH2CH2NMe2）Cl] 2的结构。
• Multiple coordination modes of hemilabile 3-dimethylaminopropyl chalcogenolates in platinum(II) complexes: Synthesis, spectroscopy and structures
  作者：Sandip Dey、Vimal K. Jain、Ray J. Butcher

  DOI：10.1016/j.ica.2007.01.002

  日期：2007.5

  N-dimethylaminopropyl chalcogenolates with platinum(II) compounds have been carried out and complexes of the types [PtCl(ECH2CH2CH2NMe2)]2 (1) (E = S (1a) and Se (1b)), [Pt(ECH2CH2CH2NMe2)2]n (2) (E = S (2a) and Se (2b)), [(PtCl2)2(Me2NCH2CH2CH2E)2}]n (3), [PtX(SeCH2CH2CH2NMe2)]2 (4) (X = SePh (4a) and OAc (4b)) and [PtCl(ECH2CH2CH2NMe2)(PR3)]n (5) (E = S, Se, Te) have been isolated. These complexes have been

  摘要进行了N，N-二甲基氨基丙基硫属元素化物与铂（II）化合物的反应，并形成了[PtCl（ECH2CH2CH2NMe2）] 2（1）（E = S（1a）和Se（1b））型络合物，[ Pt（ECH2CH2CH2NMe2）2] n（2）（E = S（2a）和Se（2b）），[（PtCl2）2 （Me2NCH2CH2CH2E）2}] n（3），[PtX（SeCH2CH2CH2NMe2）] 2（4 ）（X = SePh（4a）和OAc（4b））和[PtCl（ECH2CH2CH2NMe2）（PR3）] n（5）（E = S，Se，Te）已分离。这些络合物已通过元素分析，IR，UV-Vis，NMR（1H，13C，31P，77Se，195Pt）光谱和FAB质谱数据进行了表征。[PtCl（SeCH2CH2CH2NMe2）] 2（1b）和[PtCl（SCH2CH2CH2NMe2）（PPr3）] 2（5a）
• Coordination Polymers of Palladium Bridged by Carboxylate and Dimethylaminoalkylselenolate Ligands
  作者：Dilip K. Paluru、Sandip Dey、Amey P. Wadawale、Nattamai Bhuvanesh、Anita Grupp、Wolfgang Kaim、Vimal K. Jain

  DOI：10.1002/asia.201501087

  日期：2016.2

  Coordination polymers of palladium stabilized by dimethylaminoalkylselenolate and carboxylate ligands are reported. The reaction of [PdCl(SeCH2CH2NMe2)]3 with AgOTf followed by treatment with sodium acetate afforded [Pd0PdII4(SeCH2CH2NMe2)3(OAc)3](OTf)2 (1) in which one of the Pd atoms is in the zero oxidation state. In the absence of NaOAc, a tetranuclear complex, [PdII4(SeCH2CH2NMe2)4(OTf)](OTf)3

  报道了通过二甲基氨基烷基硒烯酸酯和羧酸酯配体稳定的钯的配位聚合物。[PdCl（SeCH 2 CH 2 NMe 2）] 3与AgOTf的反应，然后用乙酸钠处理，得到[Pd 0 Pd II 4（SeCH 2 CH 2 NMe 2）3（OAc）3 ]（OTf）2（1），其中Pd原子之一处于零氧化态。在没有NaOAc的情况下，四核复合物[Pd II 4（SeCH 2 CH 2 NMe 2从同一反应中分离出）4（OTf）]（OTf）3（2）。随后用NaO 2 CR处理得到[Pd 4（SeCH 2 CH 2 NMe 2）4（O 2 CR）4 ]（R ＝t Bu（3）和Ph（4））。[PdCl（SeCH 2 CH 2 CH 2 NMe 2）] 2与AgOTf和NaOAc的反应产生离子双核络合物，[Pd II 2（SeCH 2 CH 2CH 2 NMe 2）2（OAc）]（OTf）（5）。这些配合物的特征
• 3-Dimethylaminopropyl chalcogenolate complexes of palladium(II): Syntheses and characterization, including the crystal structures of [Pd(OAc)(ECH2CH2CH2NMe2)]2·H2O (E=S, Se) and [PdCl(TeCH2CH2CH2NMe2)]2
  作者：Sandip Dey、Vimal K. Jain、Babu Varghese、Thilo Schurr、Mark Niemeyer、Wolfgang Kaim、Ray J. Butcher

  DOI：10.1016/j.ica.2005.09.019

  日期：2006.3

  The reactions of the sodium salts of 3-dimethylamino-l-propylchalcogenolates, prepared by sodium borohydride reduction of (Me2NCH2CH2CH2E)(2) in methanol, with Na2PdCl4 yielded homoleptic [Pd(ECH2CH2CH2NMe2)(2)](6) (1) (E=S (1a); Se (1b); Te (1c)). When treated with [Pd(OAc)(2)](3) or Na2PdCl4, compounds 1 readily gave binuclear redistribution products [PdX(ECH2CH2CH2NMe2))(2) where X = OAc (2) (E = S (2a); Se (2b); or Cl (3)) (E = S (3a); Se (3b); Te (3c)), respectively. The terminal acetate/chloride ligands in 2b/3b can be substituted by other ionic ligands like PhSe-. The complexes were characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy. The structures of 2a, 2b and 3c were established by X-ray crystallography. Each molecule has a dimeric structure in which there are two chalcogenolate bridges from the chelating 3-dimethylamino-l-propylchalcogenolate ligands. On pyrolysis, compound 2b affords Pd17Se15. (c) 2005 Elsevier B.V. All rights reserved.