2-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalen-3-ol | 351866-07-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalen-3-ol
• 英文别名: 2-Methyl-4,5-benzoindanol
• CAS: 351866-07-4
• 化学式: C₁₄H₁₄O
• 分子量: 198.265
• InChiKey: RUBFEGSKABOQBU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  萘 在 甲醇 、 aluminum (III) chloride 、 sodium tetrahydroborate 、 硫酸 作用下， 以 二氯甲烷 为溶剂， 反应 7.0h， 生成 2-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalen-3-ol
  参考文献：
  名称：

  전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조 방법

  摘要：

  根据本发明，不仅可以在烯烃聚合反应中表现出高活性，还可以方便地调节合成的烯烃聚合物的特性的过渡金属化合物，包括该过渡金属化合物的催化剂组合物以及可以提供使用该催化剂组合物制备烯烃聚合物的方法。利用上述过渡金属化合物，可以提供具有高催化活性并且在各种分子量范围内具有高表观密度的烯烃聚合物。

  公开号：

  KR20170075529A

文献信息

• Production of bridged metallocene complexes and intermediates therefor
  申请人：Albemarle Corporation

  公开号：US05861522A1

  公开（公告）日：1999-01-19

  Bridged metallocene compounds are produced by a process of promising commercial utility for plant-sized operations. One of the key steps of the process involves converting a deprotonated silicon-, germanium- or tin-containing ligand into the metallocene. Preferably, and in accordance with an embodiment of the invention, this is accomplished to great advantage by adding a diamine adduct of a Group IV, V, or VI metal tetrahalide to a solution or slurry formed from a deprotonated silicon-, germanium- or tin-containing ligand and an organic liquid medium so as to form a metallocene. The overall process of the invention involves the direct conversion of benzoindanones to benzoindanols which, without isolation, are converted to benzoindenes. Thereupon the benzoindenes are bridged by deprotonating the benzoindenes with a strong base such as butyllithium and reacting the resultant deprotonated product with a suitable silicon-, germanium- or tin-containing bridging reactant such as dichlorodimethylsilane. The resultant bridged product is deprotonated with a strong base such as butyllithium and reacted with a suitable Group IV, V, or VI metal-containing reactant such as ZrCl.sub.4 to provide a silicon-, germanium- or tin-bridged Group IV, V, or VI metal complex, such as a dihydrocarbylsilyl-bridged zirconocene complex.

  桥联金属茂化合物是一种具有商业实用价值的工艺过程，适用于大型工厂操作。该过程的关键步骤之一涉及将去质子化的含硅、锗或锡配体转化为茂金属。根据发明实施例，最好的方法是将IV、V或VI族金属四卤化物的二胺加合物添加到由去质子化的含硅、锗或锡配体和有机液体介质形成的溶液或混悬液中，以形成茂金属。该发明的整个过程涉及将苯并茚酮直接转化为苯并茚醇，然后不经过分离，转化为苯并茚烯。然后，通过用强碱（如丁基锂）去质子化苯并茚烯，并用适当的含硅、锗或锡桥联试剂（如二氯二甲基硅烷）反应，将苯并茚烯桥联。所得到的桥联产物用强碱（如丁基锂）去质子化，并与适当的IV、V或VI族金属含有试剂（如ZrCl.sub.4）反应，以提供硅、锗或锡桥联的IV、V或VI族金属配合物，例如双氢碳基硅桥联的二茂锆配合物。
• PROPYLENE POLYMER, MOLDED OBJECT THEREOF, AND PROCESS FOR PRODUCING PROPYLENE POLYMER
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1153944A1

  公开（公告）日：2001-11-14

  The propylene polymer of the invention is transparent and has good low-temperature heat-sealability and scratch resistance, and is favorable to wrapping and packaging films. (1) The polymer has a melting point, Tm (°C), measured through differential scanning calorimetry, of 110 ≤ Tm ≤ 140; (2) its heat of fusion △H (J/g) and melting point Tm (°C) satisfy ΔH ≥ 0.45 × Tm + 22; (3) the half-value width Th (°C) of the peak top of its elution curve obtained in programmed-temperature fractionation is Th ≤ 5; and (4) its intrinsic viscosity [η] (dl/g) measured in a solvent of tetralin at 135°C falls between 0.5 and 5.

  本发明的丙烯聚合物是透明的，具有良好的低温热封性和抗划伤性，有利于包装和包裹薄膜。(1) 通过差示扫描量热法测量，该聚合物的熔点 Tm (℃)为 110 ≤ Tm ≤ 140；(2) 其熔化热 △H (J/g) 和熔点 Tm (℃)满足 △H ≥ 0.45 × Tm + 22；(3) 在程序温度分馏中得到的其洗脱曲线峰顶的半值宽度 Th（℃）为 Th ≤ 5；(4) 在 135℃的四萘溶剂中测得的其固有粘度[η]（dl/g）介于 0.5 和 5 之间。
• PRODUCTION OF BRIDGED METALLOCENE COMPLEXES AND INTERMEDIATES THEREFOR
  申请人：ALBEMARLE CORPORATION

  公开号：EP0854876A2

  公开（公告）日：1998-07-29
• PROPYLENE POLYMER, MOLDED OBJECT THEREOF
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1153944B1

  公开（公告）日：2007-01-31
• METALLOCENE COMPLEX WITH A HETEROATOM-CONTAINING PI-LIGAND AND PREPARATION METHOD THEREFOR, CATALYST SYSTEM CONTAINING THE SAME AND USE THEREOF
  申请人：PetroChina Company Limited

  公开号：US20200062874A1

  公开（公告）日：2020-02-27

  The present invention relates to a metallocene complex with a heteroatom-containing π-ligand, having a chemical structure represented by formula (I) as below: wherein M is a transition metal element from Group 3, Group 4, Group 5 and Group 6 in the periodic table, including lanthanides and actinides; X, being the same as or different from each other, is selected from hydrogen, halogen, an alkyl group R, an alkoxyl group OR, a mercapto group SR, a carboxyl group OCOR, an amino group NR 2 , a phosphino group PR 2 , —OR ∘ O— and OSO 2 CF 3 ; n is an integer from 1 to 4 and is not zero; the charge number resulted from multiplying n by the charge number of X equals to the charge number of the central metal atom M minus 2; Q is a divalent radical; A is a π-ligand; and Z is a π-ligand; the process for producing the same; a catalyst system of the same; and use of the catalyst system.