1-perfluoro-n-heptylnaphthtalene | 126358-10-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-perfluoro-n-heptylnaphthtalene
• 英文别名: 1-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,7-pentadecafluoroheptyl)naphthalene
• CAS: 126358-10-9
• 化学式: C₁₇H₇F₁₅
• 分子量: 496.219
• InChiKey: MINBDEQFAONXBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.67
• 重原子数：
  32.0
• 可旋转键数：
  6.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1-perfluoro-n-heptylnaphthtalene 在 氯磺酸 作用下， 以84%的产率得到1-perfluoro-n-heptylnaphthalene-5-sulfonyl chloride
  参考文献：
  名称：

  Perfluoroalkylbenzenesulfonyl chlorides, perfluoroalkylnaphthalenesulfonyl chlorides, and their metal salts

  摘要：

  Meta-perfluoro-n-alkylbenzenesulfonyl chlorides and 1-perfluoro-n-alkylnaphthalene-5-sulfonyl chlorides were synthesized from the corresponding perfluoroalkylaromatics in good yield by the action of chlorosulfonic acid. From the acid chlorides, salts (RSO3M, where M = Li, K, Ba, Zn and Al) were prepared and their TGA curves obtained. With the exception of the aluminum salts, the materials were stable to at least 350-degrees-C. All the salts were essentially insoluble in Cl(CFClCF2)3-4Cl.

  DOI：

  10.1016/s0022-1139(00)80959-8
• 作为产物：
  描述：

  十五氟碘庚烷 、 1-碘萘 在 铜 作用下， 以 二甲基亚砜 为溶剂， 反应 48.0h， 以89%的产率得到1-perfluoro-n-heptylnaphthtalene
  参考文献：
  名称：

  Perfluoroalkylbenzenesulfonyl chlorides, perfluoroalkylnaphthalenesulfonyl chlorides, and their metal salts

  摘要：

  Meta-perfluoro-n-alkylbenzenesulfonyl chlorides and 1-perfluoro-n-alkylnaphthalene-5-sulfonyl chlorides were synthesized from the corresponding perfluoroalkylaromatics in good yield by the action of chlorosulfonic acid. From the acid chlorides, salts (RSO3M, where M = Li, K, Ba, Zn and Al) were prepared and their TGA curves obtained. With the exception of the aluminum salts, the materials were stable to at least 350-degrees-C. All the salts were essentially insoluble in Cl(CFClCF2)3-4Cl.

  DOI：

  10.1016/s0022-1139(00)80959-8

文献信息

• Synthesis of functionalized long-chain perfluoroalkanes from methyl halodifluoroacetates: a process of difluorocarbene insertion intocopper-carbon bonds
  作者：De-Bao Su、Jian-Xing Duan、An-Juan Yu、Qing-Yun Chen

  DOI：10.1016/s0022-1139(00)80465-0

  日期：1993.11

  organic halides in the presence of KF and catalytic amounts of CuI at 80–120 °C for 3–8 h in DMF gave long-chain perfluoroalkylated compounds which are considered to be former by the insertion of CF:2into carbon-copper bonds.

  在KF存在下，用有机卤化物处理XCF 2 CO 2 Me（X = Cl，Br），并在DMF中于80–120°C催化量的CuI处理3–8 h，得到长链全氟烷基化化合物，认为该化合物通过在碳-铜键中插入CF：2来形成前一键。