1-(((2′-(methylthio)phenyl)imino)methyl)naphthalen-2-ol | 1379581-40-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-(((2′-(methylthio)phenyl)imino)methyl)naphthalen-2-ol
• 英文别名: 1-[(2-Methylsulfanylphenyl)iminomethyl]naphthalen-2-ol；1-[(2-methylsulfanylphenyl)iminomethyl]naphthalen-2-ol
• CAS: 1379581-40-4
• 化学式: C₁₈H₁₅NOS
• 分子量: 293.389
• InChiKey: BJBUXIVLCJSUKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  57.9
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 1-(((2′-(methylthio)phenyl)imino)methyl)naphthalen-2-ol 以 四氢呋喃 为溶剂， 反应 24.0h， 以65%的产率得到
  参考文献：
  名称：

  苯氧基/萘氧基-亚胺配体负载的双[L（μ2-氯）铜（II）]的合成，分子结构和抗氧化活性。

  摘要：

  一系列新的Cu（II）络合物[双[{（μ 2 -氯）-2-的MeO-PH-CH 2 - （N = CH）-2,4-叔丁基- 2-OC 6 H ^ 2） } Cu（II）]（Cu1）；双[{（μ 2 -氯）-2- MES-PH-CH 2 - （N = CH）-2,4-叔丁基-2-（OC 6 H ^ 2）}的Cu（II）]（铜） ; 双[{（μ 2 -氯）-2-的MeO-PH-CH 2 - （N = CH）-2-（OC 10 H ^ 6）}的Cu（II）]（CU3）; 双[{（μ 2 -氯）-2- MES-PH-CH 2 - （N = CH）-2-（OC 10 H ^ 6）}的Cu（II）]配合物（CU4）; 合成了双[{2-MeS-Ph-CH 2-（N = CH）-2,4-叔丁基-2-（OC 6 H 2）} Cu（II）]（Cu5）]，并进行了表征元素分析，IR，UV-可见和X射线晶体学分析

  DOI：

  10.1016/j.jinorgbio.2020.111130
• 作为产物：
  描述：

  2-氨基茴香硫醚 、 2-羟基-1-萘甲醛 以41.2%的产率得到1-(((2′-(methylthio)phenyl)imino)methyl)naphthalen-2-ol
  参考文献：
  名称：

  水杨基亚胺基钴（II）配合物与侧链供体促进的生物来源月桂烯和甲基丙烯酸甲酯的选择性聚合双催化

  摘要：

  钴配合物（Co1 - Co6）被苯氧基（4,6-二叔丁基-2-苯酚，萘-2-醇）-亚胺配体双螯合，后者含有侧链硬氧（Co1和Co4），软硫（Co2和Co5）或膦供体（Co3和Co6）被报道用于生物来源的月桂烯和甲基丙烯酸甲酯（MMA）的选择性聚合的双重催化。X射线分析表明，该配合物的特征是钴中心与酚酸氧，亚胺氮和侧链供体结合的八面体配位畸变（P代表Co3，S代表Co5）。由MMAO或Al活化在Bu 3中，所有前体不仅能够将月桂烯转化为顺式-1,4-聚Myrence，而且能够聚合MMA，从而形成具有中等间同立构规整度的聚（甲基丙烯酸甲酯）（PMMA）。侧链供体的引入同时提高了活性和稳定性，特别是在60-80°C时两种单体的聚合反应。在月桂烯顺式中观察到增强的活性和选择性含硫和氧的催化剂促进的-1,4聚合反应可能与弱的Co-X（X = O，S）相互作用有关，从而促进了月桂烯的配位。然而，供体对

  DOI：

  10.1021/acs.organomet.8b00708

文献信息

• Boranil dye based “turn-on” fluorescent probes for detection of hydrogen peroxide and their cell imaging application
  作者：Jayabalan Shanmugapriya、Kandasamy Rajaguru、Gandhi Sivaraman、Shanmugam Muthusubramanian、Nattamai Bhuvanesh

  DOI：10.1039/c6ra17863d

  日期：——

  The synthesis of boranil dye fluorescent probes for the detection of hydrogen peroxide has been described. The probes exhibited high selectivity in sensing hydrogen peroxide among other reactive oxygen species, reactive nitrogen species and biologically pertinent species. The probes display good sensitivity and a rapid response time. The sensing mechanism was ascertained by ESI-MS analysis and density

  已经描述了用于检测过氧化氢的硼腈染料荧光探针的合成。这些探针在检测其他活性氧，活性氮和生物学相关物质中的过氧化氢方面表现出很高的选择性。探针显示出良好的灵敏度和快速的响应时间。通过ESI-MS分析和密度泛函理论（DFT）计算确定了传感机制。该探针已成功应用于生理条件下HeLa细胞中H 2 O 2的成像。
• Photoinduced interaction studies on N-(2-methylthiophenyl)-2-hydroxy-1-naphthadiamine with TiO2 nanoparticles: A combined experimental and theoretical (DFT and spectroscopic) approach
  作者：S. Pushpam、S. Gayathri、V. Ramakrishnan

  DOI：10.1016/j.saa.2014.04.167

  日期：2014.12

  Schiff base derivative synthesized by the reaction of 2-(methylthio) aniline and 2-hydroxy-1-naphthaldehyde exhibits keto-amine tautomerism in methanol solvent. The fluorescence quenching of N-(2-methyl thiophenyl)-2-hydroxy-1-naphthadiamine (NMTHN) by TiO2 nanoparticles in methanol has been studied. The excitation and emission peaks have been observed at 439 and 509 nm respectively. The apparent association constant has been deduced from the absorption spectral changes of NMTHN-TiO2 nanoparticles using Bensi-Hildebrand equation. The number of binding sites and the binding constant have been calculated from the relevant fluorescence data. Quenching of fluorescence of NMTHN by TiO2 could be due to a dynamic mode. Density Functional Theory (DFT) calculations also have been performed to study the charge distribution of NMTHN-TiO2 both in ground and excited states. The HOMO-LUMO analysis of NMTHN-TiO2 in the ground state has been made. (C) 2014 Elsevier B.V. All rights reserved.
• [EN] LONG SHELF LIFE STABLE ORGANORUTHENIUM COMPLEXES AS (PRE)CATALYSTS FOR OLEFIN METATHESIS<br/>[FR] COMPLEXES D'ORGANORUTHÉNIUM STABLES À LONGUE DURÉE DE CONSERVATION EN TANT QUE (PRÉ)CATALYSEURS POUR LA MÉTATHÈSE D'OLÉFINES
  申请人：[en]APEIRON SYNTHESIS S.A.

  公开号：WO2022167944A1

  公开（公告）日：2022-08-11

  Embodiments in accordance with the present invention encompass an organorutheniumcompound of the formula I:(I)wherein X, Y, L1, L2, L3, R1and R2are as defined herein. Also disclosed herein are the use of organoruthenium compound of the formula I as (pre)catalysts for the olefin metathesis reactions, as well as to the process for carrying out the olefin metathesis reaction.
• Dual Catalysis of the Selective Polymerization of Biosourced Myrcene and Methyl Methacrylate Promoted by Salicylaldiminato Cobalt(II) Complexes with a Pendant Donor
  作者：Xiaoyu Jia、Wenxin Li、Junyi Zhao、Feiyan Yi、Yunjie Luo、Dirong Gong

  DOI：10.1021/acs.organomet.8b00708

  日期：2019.1.28

  activity and stability particularly at 60–80 °C for polymerizations of both monomers. The enhanced activity and selectivity observed in myrcene cis-1,4 polymerization promoted by the sulfur and oxygen containing catalysts may relate to the weak Co–X (X = O, S) interaction, facilitating myrcene coordination. However, the donor effect on MMA polymerization activity is reversed, with phosphine donated catalyst

  钴配合物（Co1 - Co6）被苯氧基（4,6-二叔丁基-2-苯酚，萘-2-醇）-亚胺配体双螯合，后者含有侧链硬氧（Co1和Co4），软硫（Co2和Co5）或膦供体（Co3和Co6）被报道用于生物来源的月桂烯和甲基丙烯酸甲酯（MMA）的选择性聚合的双重催化。X射线分析表明，该配合物的特征是钴中心与酚酸氧，亚胺氮和侧链供体结合的八面体配位畸变（P代表Co3，S代表Co5）。由MMAO或Al活化在Bu 3中，所有前体不仅能够将月桂烯转化为顺式-1,4-聚Myrence，而且能够聚合MMA，从而形成具有中等间同立构规整度的聚（甲基丙烯酸甲酯）（PMMA）。侧链供体的引入同时提高了活性和稳定性，特别是在60-80°C时两种单体的聚合反应。在月桂烯顺式中观察到增强的活性和选择性含硫和氧的催化剂促进的-1,4聚合反应可能与弱的Co-X（X = O，S）相互作用有关，从而促进了月桂烯的配位。然而，供体对
• Synthesis, molecular structure and antioxidant activity of bis [L(μ2-chloro)copper(II)] supported by phenoxy/naphthoxy–imine ligands
  作者：Tamara Machado dos Santos、Carolina Cristovão Martins、Danielle Tapia Bueno、Ianka Jacondino Nunes、Franciele Faccio Busatto、Roberta Cargnelutti、Cristiane Luchese、Osvaldo de Lazaro Casagrande、Jenifer Saffi、Ethel Antunes Wilhelm、Adriana Castro Pinheiro

  DOI：10.1016/j.jinorgbio.2020.111130

  日期：2020.9

  A new series of Cu(II) complexes [bis[(μ2-chloro)-2-MeO-Ph-CH2-(N=CH)-2,4-tert-butyl-2-OC6H2)}Cu(II)] (Cu1); bis[(μ2-chloro)-2-MeS-Ph-CH2-(N=CH)-2,4-tert-butyl-2-(OC6H2)}Cu(II)] (Cu2); bis[(μ2-chloro)-2-MeO-Ph-CH2-(N=CH)-2-(OC10H6)} Cu(II)] (Cu3); bis[(μ2-chloro)-2-MeS-Ph-CH2-(N=CH)-2-(OC10H6)}Cu(II)] complex (Cu4); bis[2-MeS-Ph-CH2-(N=CH)-2,4-tert-butyl-2-(OC6H2)}Cu(II)] (Cu5)] have been synthesized

  一系列新的Cu（II）络合物[双[（μ 2 -氯）-2-的MeO-PH-CH 2 - （N = CH）-2,4-叔丁基- 2-OC 6 H ^ 2） } Cu（II）]（Cu1）；双[（μ 2 -氯）-2- MES-PH-CH 2 - （N = CH）-2,4-叔丁基-2-（OC 6 H ^ 2）}的Cu（II）]（铜） ; 双[（μ 2 -氯）-2-的MeO-PH-CH 2 - （N = CH）-2-（OC 10 H ^ 6）}的Cu（II）]（CU3）; 双[（μ 2 -氯）-2- MES-PH-CH 2 - （N = CH）-2-（OC 10 H ^ 6）}的Cu（II）]配合物（CU4）; 合成了双[2-MeS-Ph-CH 2-（N = CH）-2,4-叔丁基-2-（OC 6 H 2）} Cu（II）]（Cu5）]，并进行了表征元素分析，IR，UV-可见和X射线晶体学分析