2,9-diformyl-1,10-phenanthrolinebis(2,4,6-trimethylanil) | 478813-38-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2,9-diformyl-1,10-phenanthrolinebis(2,4,6-trimethylanil)
• 英文别名: N-(2,4,6-trimethylphenyl)-1-[9-[(2,4,6-trimethylphenyl)iminomethyl]-1,10-phenanthrolin-2-yl]methanimine
• CAS: 478813-38-6
• 化学式: C₃₂H₃₀N₄
• 分子量: 470.617
• InChiKey: FBBGHQPKOQBATP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  36
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  50.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  iron(II) chloride tetrahydrate 、 2,9-diformyl-1,10-phenanthrolinebis(2,4,6-trimethylanil) 以 四氢呋喃 为溶剂， 以91%的产率得到dichloro[2,9-diformyl-1,10-phenanthrolinebis(2,4,6-trimethylanil)]iron(II) monohydrate
  参考文献：
  名称：

  Late transition metal complexes bearing 2,9-bis(imino)-1,10-phenanthrolinyl ligands: synthesis, characterization and their ethylene activity

  摘要：

  A series of iron, cobalt and nickel halide complexes, LMX2 (M = Fe, X = Cl; M = Co, X = Cl, M = N-1, X = Br) bearing 2,9-bis(imino)-1,10-phenanthrolinyl ligands [L = 2,9-(ArNCH)(2)C12H6N2] were synthesized. The solid-state structures of 4 and 7 have been determined by single-crystal X-ray diffraction study. Treatment of the complexes LMX2 with methylaluminoxane (MAO) leaded to activate ethylene as oligomerization catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01623-6
• 作为产物：
  描述：

  1,10-菲啰啉-2,9-二甲醛 、 2,4,6-三甲基苯胺 以 乙醇 为溶剂， 反应 5.0h， 以77%的产率得到2,9-diformyl-1,10-phenanthrolinebis(2,4,6-trimethylanil)
  参考文献：
  名称：

  Late transition metal complexes bearing 2,9-bis(imino)-1,10-phenanthrolinyl ligands: synthesis, characterization and their ethylene activity

  摘要：

  A series of iron, cobalt and nickel halide complexes, LMX2 (M = Fe, X = Cl; M = Co, X = Cl, M = N-1, X = Br) bearing 2,9-bis(imino)-1,10-phenanthrolinyl ligands [L = 2,9-(ArNCH)(2)C12H6N2] were synthesized. The solid-state structures of 4 and 7 have been determined by single-crystal X-ray diffraction study. Treatment of the complexes LMX2 with methylaluminoxane (MAO) leaded to activate ethylene as oligomerization catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01623-6

文献信息

• Late transition metal complexes bearing 2,9-bis(imino)-1,10-phenanthrolinyl ligands: synthesis, characterization and their ethylene activity
  作者：Leyong Wang、Wen-Hua Sun、Lingqin Han、Haijian Yang、Youliang Hu、Xianglin Jin

  DOI：10.1016/s0022-328x(02)01623-6

  日期：2002.9

  A series of iron, cobalt and nickel halide complexes, LMX2 (M = Fe, X = Cl; M = Co, X = Cl, M = N-1, X = Br) bearing 2,9-bis(imino)-1,10-phenanthrolinyl ligands [L = 2,9-(ArNCH)(2)C12H6N2] were synthesized. The solid-state structures of 4 and 7 have been determined by single-crystal X-ray diffraction study. Treatment of the complexes LMX2 with methylaluminoxane (MAO) leaded to activate ethylene as oligomerization catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.