(2,9-diformylphenanthroline)bis(benzoyl)hydrazone | 339108-69-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: (2,9-diformylphenanthroline)bis(benzoyl)hydrazone
• 英文别名: N-[[9-[(benzoylhydrazinylidene)methyl]-1,10-phenanthrolin-2-yl]methylideneamino]benzamide
• CAS: 339108-69-9
• 化学式: C₂₈H₂₀N₆O₂
• 分子量: 472.506
• InChiKey: DXMXZRKTUBCQLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  (2,9-diformylphenanthroline)bis(benzoyl)hydrazone 、 二苯基氯化铅 以 甲醇 为溶剂， 生成 Ph2Pb((2,9-diformylphenanthroline)bis(benzoyl)hydrazone)
  参考文献：
  名称：

  The crystal structures of two organometallic complexes of a new 2,9-diformylphenanthroline bis-acylhydrazone hexadentate ligand

  摘要：

  The new potentially hexadentate ligand (2,9-diformylphenanthroline) bis(benzoyl)hydrazone (H2L) is synthesised and spectroscopically characterised. It reacts with dibutyltin diacetate and diphenyllead dichloride giving the complexes [(C4H9)(2)SnL] and [(C6H5)(2)PbL], respectively; their X-ray structure and spectroscopic characterization are reported. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00247-0
• 作为产物：
  描述：

  1,10-菲啰啉-2,9-二甲醛 、 苯甲酰肼 以 甲醇 为溶剂， 反应 6.0h， 以75%的产率得到(2,9-diformylphenanthroline)bis(benzoyl)hydrazone
  参考文献：
  名称：

  A simple strategy for the visual detection and discrimination of Hg²⁺ and CH₃Hg⁺ species using fluorescent nanoaggregates

  摘要：

  基于苯并啉类两性探针的荧光纳米聚集体已被用于在水介质中检测和区分Hg²⁺（LOD约4 ppb）和CH₃Hg⁺（LOD约18 ppb）。

  DOI：

  10.1039/d1dt01455b

文献信息

• Synthesis and characterization of new lanthanide complexes with hexadentate hydrazonic ligands
  作者：M. Carcelli、S. Ianelli、P. Pelagatti、G. Pelizzi、D. Rogolino、C. Solinas、M. Tegoni

  DOI：10.1016/j.ica.2004.10.003

  日期：2005.3

  In this paper, we report the synthesis and the characterization of a novel series of lanthanide (III) complexes with two potentially hexadentate ligands. The ligands contain a rigid phenanthroline moiety and two flexible hydrazonic arms with different donor atom sets (NNN'N'OO and NNN'N'N"N", respectively for H2L1 (2,9-diformylphenanthroline)bis(benzoyl)hydrazone and H2L2 (2,9-diformylphenanthroline)bis(2-pyridyl)hydrazone). Both nitrate and acetate complexes of H2L1 with La, Eu, Gd, and Tb were prepared and fully characterized, and the X-ray crystal structure of the complex [Eu(HL1)(CH3COO)(2)] (.) 5H(2)O is presented. The stability constants of the equilibria Ln(3+) + H2L1 = [Ln(H2L1)](3+) and Ln(3+) + (L-1)(2-) = [Ln(Li)](+) (Ln = La(III), Eu(III), Gd(III), and Tb(III)) are determined by UV spectrophotometric titrations in DMSO at t = 25 degrees C. The nitrate complexes of H2L2 with La, Eu, Gd and Tb were also synthesized, and the X-ray crystal structures of [La(H2L2)(NO3)(2)(H2O)](NO3), [Eu(H2L2)(NO3)(2)](NO3) and [Tb(H-2 L-2)(NO3)(2)](NO3) are discussed. (c) 2004 Elsevier B.V. All rights reserved.