6,9-Dioxa-3,12,23,26-tetraazatetracyclo<12.8.4.0^17,25.0^20,24>hexacosa-1(23),14(26),15,17,19,21,24-heptaene | 118459-35-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 6,9-Dioxa-3,12,23,26-tetraazatetracyclo<12.8.4.0^17,25.0^20,24>hexacosa-1(23),14(26),15,17,19,21,24-heptaene
• 英文别名: 6,9-dioxa-3,12,23,26-tetraazatetracyclo<12.8.4.0^17,25.0^20,24>hexacosa-1(22),14,16,18,20,23,25-heptaene；6,9-Dioxa-3,12,23,26-tetrazatetracyclo[12.8.4.017,25.020,24]hexacosa-1(23),14(26),15,17(25),18,20(24),21-heptaene
• CAS: 118459-35-1
• 化学式: C₂₀H₂₄N₄O₂
• 分子量: 352.436
• InChiKey: KRGXPVYKUYIDTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  68.3
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  癸基二酰二氯 、 6,9-Dioxa-3,12,23,26-tetraazatetracyclo<12.8.4.0^17,25.0^20,24>hexacosa-1(23),14(26),15,17,19,21,24-heptaene 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以20%的产率得到29,32-dioxa-1,4,11,14-tetraazapentacyclo<12.12.8.2^3,6.2^9,12.0^5,10>octatriaconta-3,5,7,9,11,35,37-heptaene-15,26-dione
  参考文献：
  名称：

  Luening, Ulrich; Mueller, Michael, Liebigs Annalen der Chemie, 1989, p. 367 - 374

  摘要：

  DOI：
• 作为产物：
  描述：

  1,8-二氨基-3,6-二氧杂辛烷 、 1,10-菲啰啉-2,9-二甲醛 生成 6,9-Dioxa-3,12,23,26-tetraazatetracyclo<12.8.4.0^17,25.0^20,24>hexacosa-1(23),14(26),15,17,19,21,24-heptaene
  参考文献：
  名称：

  Luening, Ulrich; Mueller, Michael, Liebigs Annalen der Chemie, 1989, p. 367 - 374

  摘要：

  DOI：

文献信息

• Luening, Ulrich; Baumstark, Roland; Mueller, Michael, Liebigs Annalen der Chemie, 1991, # 10, p. 987 - 998
  作者：Luening, Ulrich、Baumstark, Roland、Mueller, Michael

  DOI：——

  日期：——
• LUNING, ULRICH;MULLER, MICHAEL, LIEBIGS ANN. CHEM.,(1989) N, C. 367-374
  作者：LUNING, ULRICH、MULLER, MICHAEL

  DOI：——

  日期：——
• The synthesis and complexation of a cobaltocenium-based redox-active cryptand containing the phenanthroline unit
  作者：C.Dennis Hall、Natasha Djedovic

  DOI：10.1016/s0022-328x(01)01415-2

  日期：2002.4

  The synthesis and characterization of a cobaltocenium-based redox-active cryptand 3 containing a phenanthroline unit is described. Complex formation (with Ca2+) Was Studied by H-1/C-13-NMR. and the effects of complexation on the redox properties of 3 were monitored by cyclic voltammetry. The fluorescence spectra of the complexes of 3 and its ferrocene analogue (4) with Eu3+ are also reported. and the low intensity of the fluorescence in each case attributed to carbonyl coordination of Eu3+ rather than metallocene quenching. (C) 2002 Elsevier Science B.V. All rights reserved.
• The synthesis and complexation of a ferrocene-based redox-active cryptand containing the phenanthroline unit
  作者：C.Dennis Hall、Thi-Kim-Uyen Truong

  DOI：10.1016/s0022-328x(96)06172-4

  日期：1996.7

  The synthesis and characterisation of a ferrocene-based redox-active cryptand (5) containing a phenanthroline unit is described. Complex formation with a wide range of mono-, di- and trivalent cations was studied by H-1/C-13 nmr and uv-vis spectroscopy and the effects of complexation on the redox properties of (5) were monitored by cyclic voltammetry.