1,5-Dibutoxy-4,8-bis[[diethoxy(oxido)phosphaniumyl]methyl]naphthalene | 295806-78-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,5-Dibutoxy-4,8-bis[[diethoxy(oxido)phosphaniumyl]methyl]naphthalene
• 英文别名: 1,5-dibutoxy-4,8-bis[[diethoxy(oxido)phosphaniumyl]methyl]naphthalene
• CAS: 295806-78-9
• 化学式: C₂₈H₄₆O₈P₂
• 分子量: 572.616
• InChiKey: GCOIIOJSGCPATH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  38
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  102
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1-dodecyl-1H-pyrrole-2-carbaldehyde 、 1,5-Dibutoxy-4,8-bis[[diethoxy(oxido)phosphaniumyl]methyl]naphthalene 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以60%的产率得到
  参考文献：
  名称：

  Fluorescent bispyrroles. New building blocks for novel π-conjugated polymers

  摘要：

  Several bispyrroles which are bridged through conjugated aromatic moieties were synthesized by the Wittig-Horner-Emmons reaction. Photophysical and electrochemical data of these highly fluorescent monomers reveal that they are useful building blocks for the design of a wide variety of novel pi-conjugated polymers, which may find application as potential optoelectronic materials. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)01039-x
• 作为产物：
  描述：

  1,5-二丁氧基萘 在 氢溴酸 作用下， 反应 13.5h， 生成 1,5-Dibutoxy-4,8-bis[[diethoxy(oxido)phosphaniumyl]methyl]naphthalene
  参考文献：
  名称：

  Fluorescent bispyrroles. New building blocks for novel π-conjugated polymers

  摘要：

  Several bispyrroles which are bridged through conjugated aromatic moieties were synthesized by the Wittig-Horner-Emmons reaction. Photophysical and electrochemical data of these highly fluorescent monomers reveal that they are useful building blocks for the design of a wide variety of novel pi-conjugated polymers, which may find application as potential optoelectronic materials. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)01039-x