1-(5-thiophen-2-ylthiophen-2-yl)-N-[(5-thiophen-2-ylthiophen-2-yl)methylideneamino]methanimine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 1-(5-thiophen-2-ylthiophen-2-yl)-N-[(5-thiophen-2-ylthiophen-2-yl)methylideneamino]methanimine
• 化学式: C₁₈H₁₂N₂S₄
• 分子量: 384.571
• InChiKey: ISCLZNKSPYHWMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  138
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,2-联噻吩-5-乙醛 在 sodium hydroxide 、 sulfur 、 一水合肼 作用下， 以82%的产率得到1-(5-thiophen-2-ylthiophen-2-yl)-N-[(5-thiophen-2-ylthiophen-2-yl)methylideneamino]methanimine
  参考文献：
  名称：

  摘要：

  Dissolution of sulfur in the system hydrazine hydrate-alkali leads to strong activation of hydrazine, so that the latter readily reacts at room temperature with aldehydes of the aromatic and thiophene series to give the corresponding aldehyde azines in high yield. The mechanism of activating effect of sulfur is discussed.

  DOI：

  10.1023/a:1022512723467

文献信息

• ——
  作者：N. V. Russavskaya、V. A. Grabel'nykh、E. P. Levanova、E. N. Sukhomazova、E. N. Deryagina

  DOI：10.1023/a:1022512723467

  日期：——

  Dissolution of sulfur in the system hydrazine hydrate-alkali leads to strong activation of hydrazine, so that the latter readily reacts at room temperature with aldehydes of the aromatic and thiophene series to give the corresponding aldehyde azines in high yield. The mechanism of activating effect of sulfur is discussed.