N-butyl-4-NHAlloc-1,8-naphthalimide | 1332830-85-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: N-butyl-4-NHAlloc-1,8-naphthalimide
• 英文别名: prop-2-enyl N-(2-butyl-1,3-dioxobenzo[de]isoquinolin-6-yl)carbamate
• CAS: 1332830-85-9
• 化学式: C₂₀H₂₀N₂O₄
• 分子量: 352.39
• InChiKey: JUWDZHZSWBTHOF-UHFFFAOYSA-N

物化性质

• 熔点：
  166.2-167.9 °C
• 沸点：
  492.9±38.0 °C(Predicted)
• 密度：
  1.282±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  75.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-butyl-4-NHAlloc-1,8-naphthalimide 在 吗啉 、 四(三苯基膦)钯 、 三苯基膦 作用下， 以 乙腈 为溶剂， 以98%的产率得到N-butyl-4-amino-1,8-naphthalimide
  参考文献：
  名称：

  A Colorimetric and Ratiometric Fluorescent Probe for Palladium

  摘要：

  A colorimetric and ratiometric fluorescent probe for the palladium species has been developed based on the Pd(0)-catalyzed cleavage of an allyoxycarbonyl group of amines under mild conditions. The probe displays a highly sensitive and selective response with significant changes in both color (from colorless to jade-green) and fluorescence (from blue to green), through the ICT process.

  DOI：

  10.1021/ol202003j
• 作为产物：
  描述：

  N-butyl-4-amino-1,8-naphthalimide 、 氯甲酸烯丙酯 在 吡啶 作用下， 以85%的产率得到N-butyl-4-NHAlloc-1,8-naphthalimide
  参考文献：
  名称：

  A Colorimetric and Ratiometric Fluorescent Probe for Palladium

  摘要：

  A colorimetric and ratiometric fluorescent probe for the palladium species has been developed based on the Pd(0)-catalyzed cleavage of an allyoxycarbonyl group of amines under mild conditions. The probe displays a highly sensitive and selective response with significant changes in both color (from colorless to jade-green) and fluorescence (from blue to green), through the ICT process.

  DOI：

  10.1021/ol202003j

文献信息

• A Colorimetric and Ratiometric Fluorescent Probe for Palladium
  作者：Jie Jiang、Huie Jiang、Wei Liu、Xiaoliang Tang、Xi Zhou、Weisheng Liu、Ruiting Liu

  DOI：10.1021/ol202003j

  日期：2011.9.16

  A colorimetric and ratiometric fluorescent probe for the palladium species has been developed based on the Pd(0)-catalyzed cleavage of an allyoxycarbonyl group of amines under mild conditions. The probe displays a highly sensitive and selective response with significant changes in both color (from colorless to jade-green) and fluorescence (from blue to green), through the ICT process.