1,8-diamino-3-nitronaphthalene | 128094-14-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,8-diamino-3-nitronaphthalene
• 英文别名: 3-nitronaphthalene-1,8-diamine
• CAS: 128094-14-4
• 化学式: C₁₀H₉N₃O₂
• 分子量: 203.2
• InChiKey: YDJQPANZJXPNFZ-UHFFFAOYSA-N

物化性质

• 沸点：
  458.6±35.0 °C(predicted)
• 密度：
  1.451±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  97.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  甲酸 、 1,8-diamino-3-nitronaphthalene 反应 0.67h， 以100%的产率得到5-nitroperimidine
  参考文献：
  名称：

  peri-naphthylenediamines

  摘要：

  meta-Substituted "proton sponges" were prepared for the first time by the direct nitration of 5,6-bis(dimethylamino)acenaphthene under strong acidic conditions and by the selective reduction of 1,3,8-tri- and 1,3,6,8-tetranitronaphthalenes and subsequent alkylation of the compounds obtained. 4,5-Bis(dimethylamino)-1,2,3,6,7,8-hexanitronaphthalene was synthesized starting from 1,3,6,8-tetranitronaphthalene.

  DOI：

  10.1007/bf02495086
• 作为产物：
  描述：

  1,3,8-三硝基萘 在 一水合肼 作用下， 反应 7.0h， 以51%的产率得到1,8-diamino-3-nitronaphthalene
  参考文献：
  名称：

  peri-naphthylenediamines

  摘要：

  meta-Substituted "proton sponges" were prepared for the first time by the direct nitration of 5,6-bis(dimethylamino)acenaphthene under strong acidic conditions and by the selective reduction of 1,3,8-tri- and 1,3,6,8-tetranitronaphthalenes and subsequent alkylation of the compounds obtained. 4,5-Bis(dimethylamino)-1,2,3,6,7,8-hexanitronaphthalene was synthesized starting from 1,3,6,8-tetranitronaphthalene.

  DOI：

  10.1007/bf02495086

文献信息

• 1,2,4,5-benzoylenebis(naphtho[1,8-de]pyrimidine) compounds and their use
  申请人：SHARP KABUSHIKI KAISHA

  公开号：EP0349219A1

  公开（公告）日：1990-01-03

  1,2,4,5-Benzoylenebis(naphto [1,8-de] pyrimidine) com­pounds of the following formula (I) or (II): wherein R and R′ are, the same or different, hydrogen atom, a halogen atom, hydroxyl group, nitro group, cyano group, an alkyl group which may be substituted, an alkoxyl group which may be substituted, an aryl group which may be substituted, an aralkyl group which may be substituted, a carboxyl group which may be esterified or a carbamoyl group which may be substituted and m and n each are an integer from 1 to 6, and photosensitive members for ele­ctrophotography having a photosensitive layer containing them.

  下式(I)或(II)的 1,2,4,5-苯甲酰基双(萘并[1,8-de]嘧啶)化合物： 其中R和R′相同或不同，为氢原子、卤素原子、羟基、硝基、氰基、可被取代的烷基、可被取代的烷氧基、可被取代的芳基、可被取代的芳烷基、可被酯化的羧基或可被取代的氨基甲酰基，且m和n均为1至6的整数。
• US5116706A
  申请人：——

  公开号：US5116706A

  公开（公告）日：1992-05-26