1-octylnaphthol | 31215-05-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-octylnaphthol
• 英文别名: Octyl-2-naphthol；1-octylnaphthalen-2-ol
• CAS: 31215-05-1
• 化学式: C₁₈H₂₄O
• 分子量: 256.388
• InChiKey: AAZCPESOYPGWEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  19
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-octylnaphthol 在 四(三苯基膦)钯 potassium phosphate 、 9-borabicyclo[3.3.1]nonane dimer 、 sodium hydride 作用下， 反应 27.0h， 生成 2-<5,5-ethylidenedioxy)hexyl>-1-octylnaphthalene
  参考文献：
  名称：

  Palladium-catalyzed cross-coupling reaction of organoboron compounds with organic triflates

  摘要：

  The cross-coupling reaction of 9-alkyl-9-borabicyclo[3.3.1]nonane (9-R-9-BBN), 1-alkenyl-1,3,2-benzodioxaborole, or aryl boronic acid with 1-alkenyl or aryl triflates in the presence of K3PO4 (1.5 equiv) and a catalytic amount of Pd(PPh3)4 or Cl2Pd(dppf) resulted in high yields. The reaction conditions are sufficiently mild so that a variety of functionalized alkenes, alkadienes, and arenes are readily obtained. The utility of the present reaction was demonstrated by the cyclization of omega-alkenyl triflates leading to a benzo-fused cycloalkene and bicyclic alkene via a hydroboration-intramolecular coupling sequence.

  DOI：

  10.1021/jo00060a041
• 作为产物：
  描述：

  9-octyl-9-bora-bicyclo[3.3.1]nonane 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 盐酸 、 sodium hydroxide 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 24.0h， 生成 1-octylnaphthol
  参考文献：
  名称：

  Palladium-catalyzed cross-coupling reaction of organoboron compounds with organic triflates

  摘要：

  The cross-coupling reaction of 9-alkyl-9-borabicyclo[3.3.1]nonane (9-R-9-BBN), 1-alkenyl-1,3,2-benzodioxaborole, or aryl boronic acid with 1-alkenyl or aryl triflates in the presence of K3PO4 (1.5 equiv) and a catalytic amount of Pd(PPh3)4 or Cl2Pd(dppf) resulted in high yields. The reaction conditions are sufficiently mild so that a variety of functionalized alkenes, alkadienes, and arenes are readily obtained. The utility of the present reaction was demonstrated by the cyclization of omega-alkenyl triflates leading to a benzo-fused cycloalkene and bicyclic alkene via a hydroboration-intramolecular coupling sequence.

  DOI：

  10.1021/jo00060a041

文献信息

• Peroxidation and Skeletal Rearrangement for the Synthesis of Dioxole‐2‐Carboxamide Derivatives under Continuous‐Flow Conditions
  作者：Akash S. Ubale、Moseen A. Shaikh、Nirmala Mohanta、Boopathy Gnanaprakasam

  DOI：10.1002/adsc.202300591

  日期：2023.9.19

  Herein, we report peroxidative dearomatization of 2-naphthol and C−H peroxidation of 3-arylbenzofuran-2-ones with 66–94% yield under catalyst-free conditions using continuous flow module. Besides, an approach for the synthesis of N-substituted-2-phenylbenzo[d][1,3]dioxole-2-carboxamide has been achieved via the skeletal rearrangement of peroxybenzofuranone using amines in the absence of catalyst under

  在此，我们报道了使用连续流模块在无催化剂条件下进行 2-萘酚的过氧化脱芳构化和 3-芳基苯并呋喃-2-酮的 C−H 过氧化，产率达 66-94%。此外，在连续流动下，通过过氧苯并呋喃酮的骨架重排，在没有催化剂的情况下，实现了合成N-取代-2-苯基苯并[ d ][ 1,3 ]二氧杂环戊烯-2-甲酰胺的方法。机理研究表明，这种过氧化反应是在热解条件下通过自由基形成进行的。
• Coated minerals for filling plastics
  申请人：ENGELHARD CORPORATION

  公开号：EP0255304A2

  公开（公告）日：1988-02-03

  A filled engineering plastics is provided with improved impact strength by pretreating the filler to provide separate coating deposits of a coupling agent and an impact modifier for the plastics matrix - e.g. for nylon plastics, a kaolin filler coated with separate deposits of an amino functional silane coupling agent and a phenol or triethanolamine impact modifier has resulted in an improved strength without sacrificing tensile and elastic properties of the nylon.

  通过对填料进行预处理，为塑料基体提供偶联剂和抗冲改性剂的独立涂层，可提高填充工程塑料的抗冲击强度--例如，对于尼龙塑料，在高岭土填料上涂覆独立的氨基官能硅烷偶联剂涂层和苯酚或三乙醇胺抗冲改性剂涂层，可在不牺牲尼龙的拉伸和弹性性能的情况下提高强度。
• Process for preparing a monoazo metal complex salt compound for charge control agent and toner for developing electrostatic images
  申请人：ORIENT CHEMICAL INDUSTRIES, LTD.

  公开号：US20030187234A1

  公开（公告）日：2003-10-02

  Charge control agent comprising a metal complex salt compound of Formula (I) containing substantially no monoazo compound constituting the ligand thereof, toner containing the charge control agent, and process for manufacturing a metal complex salt compound of Formula (I), which comprises a metallizing reaction for metallizing a monoazo compound of Formula (II) with iron, nickel, aluminum, titanium or zirconium to produce a metal complex salt compound, in which metallizing reaction a monohydric or dihydric alcohol is used as a reaction-promoting solvent: 1 R: alkyl (C4 to 12); Y: halogen or alkyl (C 1 to 5); p and q: number of monoazo compounds coordinated to the metal M; p: 1, 2, 3 or 4; q: 0, 1, 2 or 3; p+q: 1 to 6; L 1 and L 2 is —O—; one of L 3 and L 4 is —O—, while the other is an —OH group or an —O − ion; M is iron, nickel, aluminum, titanium or zirconium; (M x+ )m: m number of metals of atomic valence x; m: 1 to 4; x: 2 or more; Z−: the negative charge in the parentheses; (A + )n is a hydrogen ion or an alkali metal ion, n=Z; 2

  由基本上不含构成其配体的单偶氮化合物的式(I)金属络合盐化合物组成的电荷控制剂、含有该电荷控制剂的墨粉，以及制造式(I)金属络合盐化合物的工艺，该工艺包括将式(II)单偶氮化合物与铁、镍、铝、钛或锆进行金属化反应，生成金属络合盐化合物，在该金属化反应中，使用一元醇或二元醇作为反应促进溶剂： 1 R：烷基（C4 至 12）；Y：卤素或烷基（C 1 至 5）；p 和 q：与金属 M 配位的单偶氮化合物的数目；p：1、2、3 或 4；q：0、1、2 或 3；p+q：1 至 6；L 1 和 L 2 为-O-；L 3 和 L 4 是-O-，而另一个是-OH 基团或-O - 离子；M 是铁、镍、铝、钛或锆；（M x&plus； )m：原子价为 x 的金属的 m 数；m：1 至 4；x：2 或更多；Z-：括号中的负电荷；（A &plus； )n为氢离子或碱金属离子，n&等于;Z； 2
• US4740538A
  申请人：——

  公开号：US4740538A

  公开（公告）日：1988-04-26
• US6548648B1
  申请人：——

  公开号：US6548648B1

  公开（公告）日：2003-04-15