1,2,3,4-tetrahydro-naphthalene-1,3-diol | 83731-58-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 1,2,3,4-tetrahydro-naphthalene-1,3-diol
• 英文别名: 1,2,3,4-Tetrahydro-naphthalin-1,3-diol；1.3-Dioxy-naphthalin-tetrahydrid-(1.2.3.4)；1,2,3,4-Tetrahydronaphthalene-1,3-diol
• CAS: 83731-58-2
• 化学式: C₁₀H₁₂O₂
• 分子量: 164.204
• InChiKey: HVCIHTJTCNLLNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2,3,4-tetrahydro-naphthalene-1,3-diol 、 alkaline earth salt of/the/ methylsulfuric acid 生成 萘
  参考文献：
  名称：

  Bamberger; Lodter, Chemische Berichte, 1893, vol. 26, p. 1834

  摘要：

  DOI：
• 作为产物：
  描述：

  2-hydroxy-1,2-dihydronaphthalene 在 natrium carbonate containing potassium permanganate solution 作用下， 生成 1-氧代-异苯并二氢吡喃-3-羧酸 、 1,2,3,4-tetrahydro-naphthalene-1,3-diol
  参考文献：
  名称：

  Bamberger; Lodter, Chemische Berichte, 1893, vol. 26, p. 1834

  摘要：

  DOI：

文献信息

• New metallocene catalysts for olefin or styrene polymerization and polymerization method using the metallocene catalysts
  申请人：Samsung General Chemicals Co., Ltd.

  公开号：US20040143077A1

  公开（公告）日：2004-07-22

  The new metallocene catalysts according to the present invention are prepared by reacting a metallocene compound with a compound having at least two functional groups. The metallocene compound is a transition metal compound which a transition metal is coordinated with a main ligand such as cycloalkanedienyl group and an ancillary ligand. The functional groups of the compound having at least two functional groups are selected from the group consisting of a hydroxy group, a thiol group, a primary amine group, a secondary amine group, etc. The metallocene catalysts according to the present invention have a structure which an ancillary ligand of a metallocene compound is bonded with functional groups. A structure of the metallocene catalysts can be varied according to the metallocene compounds, the compound having at least two functional groups, and the molar ratio of each reactant. The metallocene catalyst is employed with a co-catalyst for styrene and olefin polymerization. The co-catalyst is an organometallic compound and a mixture of non-coordinated Lewis acid and alkylaluminium. The organometallic compound is usually alkylaluminoxane and organoaluminium compound. The syndiotactic polystyrenes and the polyolefins having good physical properties are prepared by using the metallocene catalyst according to the present invention. A monomer for polymerization includes styrene, derivatives of styrene, and a compound having ethylenically unsaturated double bonds Those compounds are homopolymerized and copolymerized to give polystyrene and polyolefin.

  本发明的新型茂金属催化剂是通过茂金属化合物与至少具有两个官能团的化合物反应制备的。茂金属化合物是过渡金属与主配体（如环烷二烯基）和辅助配体配位的过渡金属化合物。具有至少两个官能团的化合物的官能团选自羟基、硫醇基、伯胺基、仲胺基等组成的组。根据本发明的茂金属催化剂具有茂金属化合物的辅助配体与官能团键合的结构。茂金属催化剂的结构可根据茂金属化合物、具有至少两个官能团的化合物以及各反应物的摩尔比而变化。茂金属催化剂与助催化剂一起用于苯乙烯和烯烃聚合。助催化剂是一种有机金属化合物和非配位路易斯酸与烷基铝的混合物。有机金属化合物通常是烷基铝氧烷和有机铝化合物。使用本发明的茂金属催化剂可制备具有良好物理性能的辛二聚苯乙烯和聚烯烃。用于聚合的单体包括苯乙烯、苯乙烯的衍生物和具有乙烯不饱和双键的化合物，这些化合物通过均聚和共聚得到聚苯乙烯和聚烯烃。
• Hock; Depke, Chemische Berichte, 1950, vol. 83, p. 317,325
  作者：Hock、Depke

  DOI：——

  日期：——
• DHAWAN K. L.; GOWLAND B. D.; DURST T., J., ORG., CHEM., 1980, 45, NO 5, 922-924
  作者：DHAWAN K. L.、 GOWLAND B. D.、 DURST T.

  DOI：——

  日期：——
• Amine terminated block copolymers and processes for their preparation
  申请人：THE FIRESTONE TIRE & RUBBER COMPANY

  公开号：EP0002196B1

  公开（公告）日：1984-07-04
• Cross-linked polymers
  申请人：ARCH SPECIALTY CHEMICALS, INC.

  公开号：EP0738744B1

  公开（公告）日：2002-11-27