1-萘基(2-萘基)甲醇 | 186407-93-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1-萘基(2-萘基)甲醇
• 英文名称: naphthalen-1-yl(naphthalen-2-yl)methanol
• 英文别名: 1-naphthyl(2-naphthyl)methanol；(+/-)-Hydroxy-(naphthyl-(1))-(naphthyl-(2))-methan；[1]Naphthyl-[2]naphthyl-methanol；α-Naphthyl-β-naphthyl-carbinol
• CAS: 186407-93-2
• 化学式: C₂₁H₁₆O
• 分子量: 284.357
• InChiKey: CFIRBWBXJDRBGQ-UHFFFAOYSA-N

物化性质

• 熔点：
  108-109 °C(Solv: benzene (71-43-2))
• 沸点：
  504.1±19.0 °C(Predicted)
• 密度：
  1.208±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-萘基(2-萘基)甲醇 在 氢碘酸 、 溶剂黄146 作用下， 生成 (1-萘基)(2-萘基)甲烷
  参考文献：
  名称：

  Tschitschibabin, Chemische Berichte, 1911, vol. 44, p. 442

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 溶剂黄146 、 锌 作用下， 生成 1-萘基(2-萘基)甲醇
  参考文献：
  名称：

  STUDIES ON MOLECULAR-REARRANGEMENTS OF α-GLYCOLS. VIII. REDUCTION OF αβ-DINAPHTHYL KETONE (AN ATTEMPT TO COMPARE THE ELECTRO NEGATIVITIES OF α- AND β- NAPHTHYL RADICALS)

  摘要：

  DOI：

  10.1246/bcsj.8.22

文献信息

• Bulky <i>N</i> ‐Heterocyclic‐Carbene‐Coordinated Palladium Catalysts for 1,2‐Addition of Arylboron Compounds to Carbonyl Compounds
  作者：Yuta Okuda、Masahiro Nagaoka、Tetsuya Yamamoto

  DOI：10.1002/cctc.202001464

  日期：2020.12.16

  primary, secondary, and tertiary alcohols by the 1,2‐addition of arylboronic acids or boronates to carbonyl compounds, including unactivated ketones, using novel bulky yet flexible N‐heterocyclic carbene (NHC)‐coordinated 2,6‐di(pentan‐3‐yl)aniline (IPent)‐based cyclometallated palladium complexes (CYPs) as catalysts is reported. The PhS‐IPent‐CYP‐catalyzed reactions are efficient at low catalyst loadings

  使用新型但又灵活的N杂环卡宾（NHC）配位的2,6-di（据报道以戊烷-3-基）苯胺（IPent）为基的环金属化钯配合物（CYPs）。PhS-IPent-CYP催化的反应在低催化剂负载量（0.02-0.3 mol％Pd）下有效，而1,2-加成的出色催化活性归因于NHC配体的空间体积。这些反应可产生各种功能化的苄醇，这些化合物很难通过经典方案使用高活性有机镁或锂试剂进行合成。
• Palladium-catalyzed arylation of aldehydes with bromo-substituted 1,3-diaryl-imidazoline carbene ligand
  作者：Tetsuya Yamamoto、Takuma Furusawa、Azamat Zhumagazin、Tetsu Yamakawa、Yohei Oe、Tetsuo Ohta

  DOI：10.1016/j.tet.2014.11.051

  日期：2015.1

  The combination of 0 valent palladium precursor and bromo-substituted 1,3-diaryl-imidazoline carbene ligand precursor such as 1-(2-bromophenyl)-3-(2,6-diisopropylphenyl)-imidazolinium chloride 1a exhibited high catalytic activity for the 1,2-addition of arylboronic acids to aldehydes including aqueous formaldehyde. (C) 2014 Elsevier Ltd. All rights reserved.
• Palladium-imidazolinium carbene-catalyzed arylation of aldehydes with arylboronic acids in water
  作者：Masami Kuriyama、Natsuki Ishiyama、Rumiko Shimazawa、Osamu Onomura

  DOI：10.1016/j.tet.2010.06.049

  日期：2010.8

  The catalytic arylation of aldehydes with arylboronic acids in only water was found to be achieved using the palladium/thioether-imidazolinium chloride system in good to excellent yields. This catalytic process showed high tolerance for a broad range of substrates, giving a variety of carbinol derivatives with 2.0-3.0 mol % of the catalyst. (C) 2010 Elsevier Ltd. All rights reserved.
• STUDIES ON MOLECULAR-REARRANGEMENTS OF α-GLYCOLS. VIII. REDUCTION OF αβ-DINAPHTHYL KETONE (AN ATTEMPT TO COMPARE THE ELECTRO NEGATIVITIES OF α- AND β- NAPHTHYL RADICALS)
  作者：Masao Migita

  DOI：10.1246/bcsj.8.22

  日期：1933.1
• POLYMER COMPOSITION HAVING PHOTOALIGNABLE GROUP, LIQUID CRYSTAL ALIGNMENT FILM FORMED OF THE POLYMER COMPOSITION, AND OPTICAL DEVICE HAVING PHASE DIFFERENCE PLATE FORMED OF THE LIQUID CRYSTAL ALIGNMENT FILM
  申请人：JNC CORPORATION

  公开号：US20150322346A1

  公开（公告）日：2015-11-12

  To provide a photoalignable material that can yield a photoalignable film having a high optical uniformity and no alignment defect, and is excellent in sensitivity to allow photoalignment even with exposure in a short period of time, and a liquid crystal alignment film having a high alignment stability of a liquid crystal compound from the photoalignable material. A photoalignable polymer composition containing a specific photoalignable polymer and a specific polymer that is reactive with the photoalignable polymer is manufactured, and the photoalignable film is manufactured by applying the polymer composition onto a base material or the like, drying the applied composition thereon, and irradiating the dried composition with light. Furthermore, the liquid crystal alignment film is manufactured by allowing alignment of molecules of the liquid crystal compound in the photoalignment film.